Citation: Xian-He Huang, Meng-Meng Zhang, Xin-Wei Dou, Xuan Lu, Yu-Jun Qin, Pu Zhang, Jia-Hua Shi, Zhi-Xin Guo. Strengthened graphene oxide/diazoresin multilayer composites from layer-by-layer assembly and cross-linking[J]. Chinese Chemical Letters, ;2015, 26(9): 1155-1157. doi: 10.1016/j.cclet.2015.04.005 shu

Strengthened graphene oxide/diazoresin multilayer composites from layer-by-layer assembly and cross-linking

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1 Department of Chemistry, Renmin University of China, Beijing 100872, China;
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2 Key Laboratory of Natural Medicine and Immuno-Engineering of Henan Province, Institute of Fine Chemical and Engineering, Henan University, Kaifeng 475004, China

Corresponding author: Yu-Jun Qin, Jia-Hua Shi,
Received Date: 7 February 2015
Available Online: 26 March 2015
Fund Project:

The layer-by-layer assembly of graphene oxide and diazoresin is carried out via the electrostatic and hydrogen bond interactions on planar substrates and colloidal templates. The successful planar and spherical growth of multilayer could be investigated by UV-vis spectrophotometry and scanning electron microscopy, respectively. Subsequent UV irradiation or heating would convert the ionic bonds and hydrogen bonds to covalent bands, which significantly improves the stability of the multilayer composite against solvent etching. For the cross-linked core-shell composites, the template cores could be removed by dissolution and hollow microspheres are obtained.
- Graphene oxide,
- Diazoresin,
- Layer-by-layer assembly,
- Cross-linking
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沈阳化工大学材料科学与工程学院沈阳 110142