Citation: Tian-Jun Gong, Yuan-Ye Jiang, Yao Fu. Rh(I)-catalyzed borylation of primary alkyl chlorides[J]. Chinese Chemical Letters, ;2014, 25(3): 397-400. doi: 10.1016/j.cclet.2014.01.006 shu

Rh(I)-catalyzed borylation of primary alkyl chlorides

1.
Department of Chemistry, University of Science and Technology of China, Hefei 230026, China

Corresponding author: Yao Fu,
Received Date: 11 September 2013
Available Online: 2 December 2013
Fund Project: NSFC (No. 20972148) (No. 20972148)

Rhodium-catalyzed cross-coupling reactions of unactivated primary alkyl chlorides with diboron reagents have been developed as practical methods for the synthesis of alkylboronic esters. These reactions expand the concept and utility of Rh(I)-catalyzed cross-coupling of aliphatic electrophiles.
- Alkyl chlorides,
- Rh(I)-catalyzed,
- Cross-coupling,
- Alkylboronic esters
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沈阳化工大学材料科学与工程学院沈阳 110142