引用本文:
Heshmatollah Alinezhad, Mahmood Tajbakhsh, Neda Hamidi. Reductive animation of aldehydes and ketones using sodium borohydride in the presence of silica chloride under solvent-free conditions[J]. Chinese Chemical Letters,
2010, 21(1): 47-50.
doi:
10.1016/j.cclet.2009.07.018
Citation: Heshmatollah Alinezhad, Mahmood Tajbakhsh, Neda Hamidi. Reductive animation of aldehydes and ketones using sodium borohydride in the presence of silica chloride under solvent-free conditions[J]. Chinese Chemical Letters, 2010, 21(1): 47-50. doi: 10.1016/j.cclet.2009.07.018
Citation: Heshmatollah Alinezhad, Mahmood Tajbakhsh, Neda Hamidi. Reductive animation of aldehydes and ketones using sodium borohydride in the presence of silica chloride under solvent-free conditions[J]. Chinese Chemical Letters, 2010, 21(1): 47-50. doi: 10.1016/j.cclet.2009.07.018
Reductive animation of aldehydes and ketones using sodium borohydride in the presence of silica chloride under solvent-free conditions
摘要:
A simple and convenient procedure for the preparation of amines from aldehydes and ketones with sodium borohydride activated by silica chloride as a catalyst under solvent-free conditions is described. A variety of aliphatic and aromatic aldehydes, ketones and amines when mixed with NaBH4/silica chloride at room temperature, afforded excellent yield of the corresponding amines.
English
Reductive animation of aldehydes and ketones using sodium borohydride in the presence of silica chloride under solvent-free conditions
Abstract:
A simple and convenient procedure for the preparation of amines from aldehydes and ketones with sodium borohydride activated by silica chloride as a catalyst under solvent-free conditions is described. A variety of aliphatic and aromatic aldehydes, ketones and amines when mixed with NaBH4/silica chloride at room temperature, afforded excellent yield of the corresponding amines.
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Key words:
- Reductive animation
- / Silica chloride
- / Solvent-free conditions
- / Sodium borohydride
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