Electrochemical performance of sulfur composite cathode materials for rechargeable lithium batteries

Feng Wu Sheng Xian Wu Ren Jie Chen Shi Chen Guo Qing Wang

引用本文: Feng Wu,  Sheng Xian Wu,  Ren Jie Chen,  Shi Chen,  Guo Qing Wang. Electrochemical performance of sulfur composite cathode materials for rechargeable lithium batteries[J]. Chinese Chemical Letters, 2009, 20(10): 1255-1258. doi: 10.1016/j.cclet.2009.04.036 shu
Citation:  Feng Wu,  Sheng Xian Wu,  Ren Jie Chen,  Shi Chen,  Guo Qing Wang. Electrochemical performance of sulfur composite cathode materials for rechargeable lithium batteries[J]. Chinese Chemical Letters, 2009, 20(10): 1255-1258. doi: 10.1016/j.cclet.2009.04.036 shu

Electrochemical performance of sulfur composite cathode materials for rechargeable lithium batteries

  • 基金项目:

    This work was financially supported by the National Key Program for Basic Research of China (No.2009CB220100) and the National 863 Program (No.2007AA03Z226).

摘要: The structure and characteristic of carbon materials have a direct influence on the electrochemical performance of sulfur-carbon composite eleceof elemental sulfur and activated carbon, which is characterized as high specific surface area and microporous structure.The composite, contained 70% sulfur, as cathode in a lithium cell based on organic liquid electrolyte was tested at room temperature.It showed two reduction peaks at 2.05 V and 2.35 V, one oxidation peak at 2.4 V during cyclic voltammogram test.The initial discharge specific capacity was 1180.8 mAh g -1 and the utilization of electrochemically active sulfur was about 70.6% assuming a complete reaction to the product of Li 2S.The specific capacity still kept as high as 720.4 mAh g-1after 60 cycles retaining 61% of the initial discharge capacity.

English

  • 加载中
计量
  • PDF下载量:  1
  • 文章访问数:  1398
  • HTML全文浏览量:  48
文章相关
  • 收稿日期:  2009-01-08
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章