Citation: Qiao Feng Wang, Hui Chen, Yan Zhao, Xiao Ye Li, Sheng Yong Zhang. A new free recoverable and reusable mono-alkaloid-type ligand and its use in preparation of ethyl (2R,3S)-2,3-dihydroxy-3-phenylpropionate[J]. Chinese Chemical Letters, ;2009, 20(7): 763-766. doi: 10.1016/j.cclet.2009.02.018 shu

A new free recoverable and reusable mono-alkaloid-type ligand and its use in preparation of ethyl (2R,3S)-2,3-dihydroxy-3-phenylpropionate

Research Center of Chirotechnology, Fourth Military Medical University, Xi'an, 710032, PR China

Received Date: 13 November 2008

Fund Project: This work was supported by the National Natural Science Foundation of China (No.20572131,20842007) and Natural Science Basic Research Plan in Shaanxi Province of China (No.SJ08-ZT02) for financial support.

A new free recoverable and reusable mono-alkaloid-type ligand has been synthesized by a simple method. With highly polar groups, the ligand can be recycled and reused eight times to prepare ethyl (2R, 3S)-2, 3-dihydroxy-3-phenylpropionate with high yield and ee via asymmetric dihydroxylation (AD) reaction.
- Cinchona alkaloid,
- Recoverable and reusable ligand,
- Ethyl(2R,3S)-2,3-dihydroxy-3-phenylpropionate
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