Citation: Hai Yan Wang, Wei Dong Ji, Da Xiong Han. Layered zirconium phosphate-supported metalloporphyrin:Synthesis and catalytic application[J]. Chinese Chemical Letters, ;2008, 19(11): 1330-1332. doi: 10.1016/j.cclet.2008.07.024 shu

Layered zirconium phosphate-supported metalloporphyrin:Synthesis and catalytic application

a The Third Institute of Oceanography of State Oceanic Administration, Xiamen 361005, China;
b Department of Pharmacy, Medical College of Xiamen University, Xiamen 361005, China

Received Date: 8 April 2008

Fund Project: The work was supported by The Basic Research Foundation of China (No. HAISANKE,2008010),The National Natural Science Foundation of China (No. 40706043),The Natural Science Foundation of Fujian Province (No. 2006J0184),The Open Research of Key laboratory of Coastal Ecosystem and Environment (No. 200610) and The Youth Foundation of SOA of China (No. 2007606).

This paper reports a new route for the preparation of layered alpha-zirconium phosphate (α-ZrP)-supponed metalloporphyrin MnTMPyp.MnTMPyP was intercalated into α-ZrP using α-ZrP·BA (i.e.pre-intercalated buitylamine was arranged by a monolayer mode in α-ZrP) as a starting material.The catalytic activity of the supported material for homovanillic acid (HVA) oxidation was investigated.The results showed a promising layered material-supported catalyst in catalytic system.
- MnTMPyP,
- Intercalation,
- Layered α-ZrP,
- Catalysis,
- Supported material
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