Citation: Dong Xia Zhao, Zhen Zhen Xu, Zhong Zhi Yang. Theoretical investigation of the stereoselectivity of some Diels-Alder reactions involving cyclopentadiene[J]. Chinese Chemical Letters, ;2008, 19(9): 1135-1138. doi: 10.1016/j.cclet.2008.06.023 shu

Theoretical investigation of the stereoselectivity of some Diels-Alder reactions involving cyclopentadiene

College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, China

Received Date: 26 February 2008

Fund Project: This research has been aided by the grants from the National Natural Science Foundation of China. (No. 20633050 and 20403007)

The stereoselectivity of some Diels-Alder reactions was investigated by means of ABEEM-Óπ model. Combined with local hard-soft and acid-base (HSAB) principle, we made reasonable explanation by calculating local softness of atom and bond regions for the stereoselectivity of four Diels-Alder reactions involving cyclopentadiene.
- ABEEM-Óπ model,
- Diels-Alder reaction,
- Stereoselecfivity,
- Local softness
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