引用本文:
Hong Yao Xu, Xin Wang, Jin Cui Wu. Preparation and property of a novel soluble oxadiazole-containing functional polyacetylene[J]. Chinese Chemical Letters,
2008, 19(2): 141-145.
doi:
10.1016/j.cclet.2007.11.004
Citation: Hong Yao Xu, Xin Wang, Jin Cui Wu. Preparation and property of a novel soluble oxadiazole-containing functional polyacetylene[J]. Chinese Chemical Letters, 2008, 19(2): 141-145. doi: 10.1016/j.cclet.2007.11.004
Citation: Hong Yao Xu, Xin Wang, Jin Cui Wu. Preparation and property of a novel soluble oxadiazole-containing functional polyacetylene[J]. Chinese Chemical Letters, 2008, 19(2): 141-145. doi: 10.1016/j.cclet.2007.11.004
Preparation and property of a novel soluble oxadiazole-containing functional polyacetylene
摘要:
A novel high molecular weight functional polyacetylene bearing oxadiazole group as a pendant, poly{4-[2-(4-octoxyphenyl)-1, 3, 4-oxadiazolyl]-benzenyloxypropynylene}, was synthesized by[Rh (nbd) Cl]2-Et3N catalyst.The polymer was soluble in common organic solvents such as CHCl3 and THE The structures and properties of monomer and polymer were characterized and evaluated with FTIR, NMR, UV, TGA, GPC, and CV, respectively.The results show that the polymer possesses high thermal stability and well electron-injection property.
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关键词:
- CV
- / Oxadiazole
- / Polyacetylonc
- / Thermal stability
English
Preparation and property of a novel soluble oxadiazole-containing functional polyacetylene
Abstract:
A novel high molecular weight functional polyacetylene bearing oxadiazole group as a pendant, poly{4-[2-(4-octoxyphenyl)-1, 3, 4-oxadiazolyl]-benzenyloxypropynylene}, was synthesized by[Rh (nbd) Cl]2-Et3N catalyst.The polymer was soluble in common organic solvents such as CHCl3 and THE The structures and properties of monomer and polymer were characterized and evaluated with FTIR, NMR, UV, TGA, GPC, and CV, respectively.The results show that the polymer possesses high thermal stability and well electron-injection property.
-
Key words:
- CV
- / Oxadiazole
- / Polyacetylonc
- / Thermal stability
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