MOF封装磷/氮离子液体作为高安全性锂离子电池的多功能阻燃添加剂

引用本文: 俞华, 陈鼎都, 王璇, 杨丽君, 王戈明, 胡朴. MOF封装磷/氮离子液体作为高安全性锂离子电池的多功能阻燃添加剂[J]. 物理化学学报, 2026, 42(7): 100201. doi: 10.1016/j.actphy.2025.100201 shu

Citation: Hua Yu, Dingdu Chen, Xuan Wang, Lijun Yang, Geming Wang, Pu Hu. MOF-encapsulated phosphorus/nitrogen ionic liquid as a multifunctional flame-retardant additive for high-safety lithium-ion batteries[J]. Acta Physico-Chimica Sinica, 2026, 42(7): 100201. doi: 10.1016/j.actphy.2025.100201 shu

MOF封装磷/氮离子液体作为高安全性锂离子电池的多功能阻燃添加剂

俞华 ^1,2, ,
陈鼎都 ^3, ,
王璇 ^1, ,
杨丽君 ^2, ,
王戈明 ^{3,
,} ,
胡朴 ^{3,
,}

1.
国网山西省电力公司电力科学研究院, 山西太原 030001;
2.
重庆大学电气工程学院, 输变电装备技术全国重点实验室, 重庆 400044;
3.
武汉工程大学等离子体化学与新材料湖北省重点实验室, 湖北武汉 430073

通讯作者: 王戈明,E-mail:wanggemingwit@163.com; 胡朴,E-mail:puhu@wit.edu.cn

基金项目:
本研究得到国家自然科学基金(52377132)和国家电网公司科技项目《基于超敏材料的电力设备油中溶解气体在线监测技术研究与应用》(5500-202415130A-1-1-ZN)的资助

摘要: 种新型电解质添加剂策略，将含磷/氮离子液体(P/N-ILs)封装于金属有机框架(MOF)中。所得的P/N-ILs@MOF复合材料具有高孔隙率和结构稳定性，在有效防止P/N-ILs聚集的同时，保持了磷元素捕获自由基与氮气稀释的协同阻燃功能。添加5 wt% P/N-ILs@MOF(MIE-5)的电解液实现自熄时间缩短90%，极限氧指数提升32%。电化学测试表明，MIE-5在Li|MIE-5|LiFePPO₄电池中展现出优异的循环稳定性，300次循环后容量保持率达84.5%。此外，采用MIE-5电解液的10 Ah石墨|MIE-5|LiFePPO₄软包电池在1C倍率下循环280次后仍保留了97.7%的容量，在2C倍率下保持0.2C容量的94.9%。本研究通过MOF封装技术开创了阻燃性与电化学性能协同提升的新范式，为下一代安全耐用锂离子电池的开发提供了重要思路。

关键词:

English

MOF-encapsulated phosphorus/nitrogen ionic liquid as a multifunctional flame-retardant additive for high-safety lithium-ion batteries

Hua Yu ^1,2, ,
Dingdu Chen ^3, ,
Xuan Wang ^1, ,
Lijun Yang ^2, ,
Geming Wang ^{3,
,} ,
Pu Hu ^{3,
,}

1.
Shanxi Electric Power Research Institute, Taiyuan 030001, Shanxi Province, China;
2.
School of Electrical Engineering, State Key Laboratory of Power Transmission Equipment Technology, Chongqing University, Chongqing 400044, China;
3.
Provincial Key Laboratory of Plasma Chemistry and Advanced Materials, Wuhan Institute of Technology, Wuhan 430073, Hubei Province, China

Corresponding author: Geming Wang, ; Pu Hu,

Received Date: 08 September 2025
Accepted Date: 16 October 2025
Revised Date: 16 October 2025

Abstract: Safety concerns arising from the flammability of alkyl carbonate-based electrolytes in lithium-ion batteries highlight the urgent need for advanced flame-retardant systems. Herein, we propose a novel electrolyte additive strategy by encapsulating phosphorus/nitrogen-containing ionic liquids (P/N-ILs) within a metal-organic framework (MOF). The resulting P/N-ILs@MOF composite exhibits high porosity and structural stability, effectively preventing P/N-ILs aggregation while maintaining synergistic flame-retardant functions of phosphorus for radical scavenging and nitrogen for gas dilution. Electrolytes containing 5 wt% P/N-ILs@MOF (MIE-5) achieve a 90% reduction in self-extinguishing time and an increased limiting oxygen index of 32%. Electrochemical testing demonstrates that MIE-5 delivers excellent cycling stability, retaining 84.5% capacity after 300 cycles in Li|MIE-5|LiFePPO₄ cells. Moreover, a 10 Ah graphite|MIE-5|LiFePPO₄ pouch cell with MIE-5 maintains 97.7% capacity after 280 cycles at 1C and retains 94.9% of its 0.2C capacity at 2C. This study introduces a new paradigm for integrating flame retardancy with electrochemical performance via MOF-encapsulation, offering significant potential for next-generation safe and durable lithium-ion batteries.

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沈阳化工大学材料科学与工程学院沈阳 110142

MOF封装磷/氮离子液体作为高安全性锂离子电池的多功能阻燃添加剂

通讯作者: 王戈明,E-mail:wanggemingwit@163.com; 胡朴,E-mail:puhu@wit.edu.cn

English

MOF-encapsulated phosphorus/nitrogen ionic liquid as a multifunctional flame-retardant additive for high-safety lithium-ion batteries

Corresponding author: Geming Wang, ; Pu Hu,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

MOF封装磷/氮离子液体作为高安全性锂离子电池的多功能阻燃添加剂

通讯作者: 王戈明,E-mail:wanggemingwit@163.com; 胡朴,E-mail:puhu@wit.edu.cn

English

MOF-encapsulated phosphorus/nitrogen ionic liquid as a multifunctional flame-retardant additive for high-safety lithium-ion batteries

Corresponding author: Geming Wang, ; Pu Hu,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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