Citation: Zi-Bo Wei, Yang Zhao, Chao Wang, Shigenori Kuga, Yong Huang, Min Wu. Antistatic PVC-graphene Composite through Plasticizer-mediated Exfoliation of Graphite[J]. Chinese Journal of Polymer Science, ;2018, 36(12): 1361-1367. doi: 10.1007/s10118-018-2160-5 shu

Antistatic PVC-graphene Composite through Plasticizer-mediated Exfoliation of Graphite

Zi-Bo Wei ^1,2 ,
Yang Zhao ^1,, ,
Chao Wang ¹ ,
Shigenori Kuga ¹ ,
Yong Huang ¹ ,
Min Wu ^1,,

a.
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Yang Zhao, yzhao@mail.ipc.ac.cn Min Wu, wumin@mail.ipc.ac.cn
Received Date: 23 March 2018
Revised Date: 2 May 2018
Accepted Date: 19 May 2018
Available Online: 14 June 2018

Multilayer graphene was prepared by mechanical exfoliation of natural graphite with dioctyl phthalate (DOP) as milling medium without solvent. The obtained mixture could be directly mixed with poly(vinyl chloride) (PVC) for melt-forming, with DOP acting as plasticizer and graphene acting as conductive filler for antistatic performance. The composite showed surface resistance of 2.5 × 10⁶ Ω/□ at 1 wt% carbon additive, significantly lower than approx. 7 wt% of raw graphite required for achieving the same level. This value is low enough for practical antistatic criterion of 3 × 10⁸ Ω/□. The effect of filler addition on mechanical performance was minimal, or even beneficial for the milled carbon in contrast to the case of raw graphite.
- Antistatic composite,
- Poly(vinyl chloride),
- Graphene,
- Mechanical exfoliation,
- Electrical property
References
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  Murthy, K.; Ramkumar, K.; Satyam, M. Electrical properties of PVC-graphite thick films. J. Mater. Sci. Lett. 1984, 3(9), 813−816 doi: 10.1007/BF00727982
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  Hansora, D. P.; Shimpi, N. G.; Mishra, S. Graphite to graphene via graphene oxide: an overview on synthesis, properties, and applications. JOM 2015, 67(12), 2855−2868 doi: 10.1007/s11837-015-1522-5
24. [24]
  Vadukumpully, S.; Paul, J.; Valiyaveettil, S. Cationic surfactant mediated exfoliation of graphite into graphene flakes. Carbon 2009, 47(14), 3288−3294 doi: 10.1016/j.carbon.2009.07.049
25. [25]
  Vidano, R. P.; Fischbach, D. B.; Willis, L. J.; Loehr, T. M. Observation of raman band shifting with excitation wavelength for carbons and graphites. Solid State Commun. 1981, 39(2), 341−344 doi: 10.1016/0038-1098(81)90686-4
26. [26]
  Graf, D.; Molitor, F.; Ensslin, K.; Stampfer, C.; Jungen, A.; Hierold, C. Spatially resolved raman spectroscopy of single- and few-layer graphene. Nano Lett. 2007, 7(2), 238−242 doi: 10.1021/nl061702a
27. [27]
  Castiglioni, C.; Negri, F.; Rigolio, M.; Zerbi, G. Raman activation in disordered graphites of the A1' symmetry forbidden k≠0 phonon: The origin of the D line. J. Chem. Phys. 2001, 115(8), 3769−3778 doi: 10.1063/1.1381529
28. [28]
  Nemanich, R. J.; Solin, S. A. 1st-order and 2nd-order Raman-scattering from finite-size crystals of graphite. Phys. Rev. B 1979, 20(2), 392−401 doi: 10.1103/PhysRevB.20.392
29. [29]
  Ferrari, A. C. Raman spectroscopy of graphene and graphite: Disorder, electron-phonon coupling, doping and nonadiabatic effects. Solid State Commun. 2007, 143(1-2), 47−57 doi: 10.1016/j.ssc.2007.03.052
30. [30]
  Ferrari, A. C.; Meyer, J. C.; Scardaci, V.; Casiraghi, C.; Lazzeri, M.; Mauri, F. Raman spectrum of graphene and graphene layers. Phys. Rev. Lett. 2006, 97(18), 187401 doi: 10.1103/PhysRevLett.97.187401
31. [31]
  Gupta, A.; Chen, G.; Joshi, P.; Tadigadapa, S.; Eklund, P. C. Raman scattering from high-frequency phonons in supported n-graphene layer films. Nano Lett. 2006, 6(12), 2667−2673 doi: 10.1021/nl061420a
32. [32]
  Menges, G. Werkstoffkunde Kunststoffe, Carl Hanser Ver-lag München Wien, 3, Auflage, 1990, p 217-218.
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Antistatic PVC-graphene Composite through Plasticizer-mediated Exfoliation of Graphite

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通讯作者: 陈斌, bchen63@163.com