4D Printing: History and Recent Progress
- Corresponding author: Tao Xie, taoxie@zju.edu.cn †These authors contributed equally to this work
Citation:
Jing-Jun Wu, Li-Mei Huang, Qian Zhao, Tao Xie. 4D Printing: History and Recent Progress[J]. Chinese Journal of Polymer Science,
;2018, 36(5): 563-575.
doi:
10.1007/s10118-018-2089-8
Hull, C. W., 1986, U.S. Pat., 5, 556, 590.
Bower, C., Meitl, M., Gomez, D., Bonafede, S. and Kneeburg, D., 2016, U.S. Pat., 9358775.
Tofail, S. A. M. ; Koumoulos, E. P. ; Bandyopadhyay, A. ; Bose, S. ; O'Donoghue, L. ; Charitidis, C. Additive manufacturing: scientific and technological challenges, market uptake and opportunities. Materialstoday, in press.
Shirazi S. F. S., Gharehkhani S., Mehrali M., Yarmand H., Metselaar H. S. C., Kadri N. A., Osman N. A. A.. A review on powder-based additive manufacturing for tissue engineering:selective laser sintering and inkjet 3D printing[J]. Sci. Technol. Adv. Mat., 2015,16(3)033502. doi: 10.1088/1468-6996/16/3/033502
Tumbleston J. R., Shirvanyants D., Ermoshkin N., Janusziewicz R., Johnson A. R., Kelly D., Chen K., Pinschmidt R., Rolland J. P., Ermoshkin A.. Additive manufacturing[J]. Continuous liquid interface production of 3D objects. Science, 2015,347(6228):1349-1352.
Geier, B., Local Motors shows Strati, the world's first 3D-printed car. http://fortune.com/2015/01/13/local-motors-shows-strati-the-worlds-first-3d-printed-car/.
Simmons, D., Airbus had 1, 000 parts 3D printed to meet deadline. http://www.bbc.com/news/technology-32597809.
Tibbits, S., The emergence of "4D printing". http://www.ted.com/talks/skylar_tibbits_the_emergence_of_4d_printing.
Campbell T., Tibbits S., Garrett B.. The next wave:4D printing-programming the material world[J]. Frame, 2014.
Xie T.. Tunable polymer multi-shape memory effect[J]. Nature, 2010,464(7286):267-270. doi: 10.1038/nature08863
Zhao Q., Qi H. J., Xie T.. Recent progress in shape memory polymer:new behavior, enabling materials, and mechanistic understanding[J]. Prog. Polym. Sci., 2015:49-120.
Zhao Q., Zou W., Luo Y., Xie T.. Shape memory polymer network with thermally distinct elasticity and plasticity[J]. Sci. Adv., 2016,2(1). doi: 10.1126/sciadv.1501297
Zheng N., Fang Z., Zou W., Zhao Q., Xie T.. Thermoset shape-memory polyurethane with intrinsic plasticity enabled by transcarbamoylation[J]. Angew. Chem. Int. Ed., 2016,55(38):11421-11425. doi: 10.1002/anie.201602847
Hj V. D. L., Herber S., Olthuis W., Bergveld P.. Stimulus-sensitive hydrogels and their applications in chemical (micro)analysis[J]. Analyst, 2003,128(4):325-331. doi: 10.1039/b210140h
Prabaharan M., Mano J. F.. Stimuli-responsive hydrogels based on polysaccharides incorporated with thermo-responsive polymers as novel biomaterials[J]. Macromol. Biosci., 2006,6(12):991-1008. doi: 10.1002/(ISSN)1616-5195
Tokarev I., Minko S.. Stimuli-responsive hydrogel thin films[J]. Soft matter, 2009,5(3):511-524. doi: 10.1039/B813827C
Qiu Y., Park K.. Environment-sensitive hydrogels for drug delivery[J]. Adv. Drug. Deliv. Rev., 2012,64(3):49-60.
Shankar R., Ghosh T. K., Spontak R. J.. Dielectric elastomers as next-generation polymeric actuators[J]. Soft matter, 2007,3(9):1116-1129. doi: 10.1039/b705737g
Yang Z., Herd G. A., Clarke S. M., Tajbakhsh A. R., Terentjev E. M., Huck W. T.. Thermal and UV shape shifting of surface topography[J]. J. Am. Chem. Soc., 2006,128(4):1074-1075. doi: 10.1021/ja056866s
Naficy S., Gately R., Gorkin R., Xin H., Spinks G. M.. 4D printing of reversible shape morphing hydrogel structures[J]. Macromol. Mater. Eng., 2017,302(1). doi: 10.1002/mame.201600212
Raviv D., Zhao W., McKnelly C., Papadopoulou A., Kadambi A., Shi B., Hirsch S., Dikovsky D., Zyracki M., Olguin C., Raskar R., Tibbits S.. Active printed materials for complex self-evolving deformations[J]. Sci. Rep., 2014,4. doi: 10.1038/srep07422
Tibbits S., McKnelly C., Olguin C., Dikovsky D., Hirsch S.. 4D printing and universal transformation[J]. Proceedings of the 34th Annual Conference of the Association for Computer Aided Design in Architecture, 2014:539-548.
Zhao Z., Wu J., Mu X., Chen H., Qi H. J., Fang D.. Desolvation induced origami of photocurable polymers by digit light processing[J]. Macromol. Rapid. Commun., 2017,38(13). doi: 10.1002/marc.201600625
3D SYSTEMS, https://cn.3dsystems.com/3d-printers/projet-mjp-3600-dental.
Stratasy, http://www.stratasys.com/3d-printers/technologies/polyjet-technology.
Lewis J. A., Smay J. E., Stuecker J., Cesarano J.. Direct ink writing of three-dimensional ceramic structures[J]. J. Am. Ceram. Soc., 2010,89(12):3599-3609.
Ionov L.. 3D microfabrication using stimuli-responsive self-folding polymer films[J]. Polym. Rev., 2013,53(1):92-107. doi: 10.1080/15583724.2012.751923
Ma C., Li T., Zhao Q., Yang X., Wu J., Luo Y., Xie T.. Supramolecular lego assembly towards three-dimensional multi-responsive hydrogels[J]. Adv. Mater., 2014,26(32):5665-5669. doi: 10.1002/adma.201402026
Zhao Q., Sun J., Ling Q., Zhou Q.. Synthesis of macroporous thermosensitive hydrogels:A novel method of controlling pore size[J]. Langmuir, 2009,25(5):3249-3254. doi: 10.1021/la8038939
Gong J. P., Katsuyama Y., Kurokawa T., Osada Y.. Double-Network hydrogels with extremely high mechanical strength[J]. Adv. Mater., 2003,15(14):1155-1158. doi: 10.1002/adma.200304907
Ge Q., Qi H. J., Dunn M. L.. Active materials by four-dimension printing[J]. Appl. Phys. Lett., 2013,103(13). doi: 10.1063/1.4819837
Ge Q., Dunn C. K., Qi H. J., Dunn M. L.. Active origami by 4D printing[J]. Smart Mater. Struct., 2014,23(9). doi: 10.1088/0964-1726/23/9/094007
Genzer, J. ; Liu, Y. ; Shaw, B. ; Dickey, M. In Light-induced sequential self-folding of pre-strained polymer sheets, APS Meeting 2014.
Ying L., Shaw B., Dickey M. D., Genzer J.. Sequential self-folding of polymer sheets[J]. Sci. Adv., 2017,3(3). doi: 10.1126/sciadv.1602417
Mao Y., Yu K., Isakov M. S., Wu J., Dunn M. L., Qi H. J.. Sequential self-folding structures by 3D printed digital shape memory polymers[J]. Sci. Rep., 2015,5. doi: 10.1038/srep13616
Ding Z., Yuan C., Peng X., Wang T., Qi H. J., Dunn M. L.. Direct 4D printing via active composite materials[J]. Sci. Adv., 2017,3(4). doi: 10.1126/sciadv.1602890
Mao Y., Ding Z., Yuan C., Ai S., Isakov M., Wu J., Wang T., Dunn M. L., Qi H. J.. 3D printed reversible shape changing components with stimuli responsive materials[J]. Sci. Rep., 2016,6. doi: 10.1038/srep24761
Zarek M., Layani M., Cooperstein I., Sachyani E., Cohn D., Magdassi S.. 3D printing of shape memory polymers for flexible electronic devices[J]. Adv. Mater., 2016,28(22):4449-4454. doi: 10.1002/adma.v28.22
Zarek M., Mansour N., Shapira S., Cohn D.. 4D printing of shape memory-based personalized endoluminal medical devices[J]. Macromol. Rapid Commun., 2017,38(2). doi: 10.1002/marc.201600628
Zarek M., Layani M., Eliazar S., Mansour N., Cooperstein I., Shukrun E., Szlar A., Cohn D., Magdassi S.. 4D printing shape memory polymers for dynamic jewellery and fashionwear[J]. Virtual. Phys. Prototyp., 2016,11(4):263-270. doi: 10.1080/17452759.2016.1244085
Miao S., Zhu W., Castro N. J., Nowicki M., Zhou X., Cui H., Fisher J. P., Zhang L. G.. 4D printing smart biomedical scaffolds with novel soybean oil epoxidized acrylate[J]. Sci. Rep., 2016,6. doi: 10.1038/srep27226
Yu K., Dunn M. L., Qi H. J.. Digital manufacture of shape changing components[J]. Extreme. Mech. Lett., 2015,4:9-17. doi: 10.1016/j.eml.2015.07.005
Huang L. M., Jiang R. Q., Wu J. J., Song J. Z., Bai H., Li B. G., Zhao Q., Xie T.. Ultrafast digital printing toward 4D shape changing materials[J]. Adv. Mater., 2017,29(7). doi: 10.1002/adma.201605390
Yang H., Leow W. R., Wang T., Wang J., Yu J., He K., Qi D., Wan C., Chen X.. 3D printed photoresponsive devices based on shape memory composites[J]. Adv. Mater., 2017. doi: 10.1002/adma.201701627
Yang K., Grant J. C., Lamey P., Joshi-Imre A., Lund B. R., Smaldone R. A., Voit W.. Diels-alder reversible thermoset 3D printing:isotropic thermoset polymers via fused filament fabrication[J]. Adv. Funct. Mater., 2017. doi: 10.1002/adfm.201700318
Wei H., Zhang Q., Yao Y., Liu L., Liu Y., Leng J.. Direct-write fabrication of 4D active shape-changing structures based on a shape memory polymer and its nanocomposite[J]. ACS Appl. Mater. Interfaces, 2017,9(1):876-883. doi: 10.1021/acsami.6b12824
Gladman A. S., Matsumoto E. A., Nuzzo R. G., Mahadevan L., Lewis J. A.. Biomimetic 4D printing[J]. Nat. Mater., 2016,15(4):413-418. doi: 10.1038/nmat4544
Zhang Q., Yan D., Zhang K., Hu G.. Pattern transformation of heat-shrinkable polymer by three-dimensional (3D) printing technique[J]. Sci. Rep., 2015,5. doi: 10.1038/srep08936
Zhang Q., Zhang K., Hu G.. Smart three-dimensional lightweight structure triggered from a thin composite sheet via 3D printing technique[J]. Sci. Rep., 2016,6. doi: 10.1038/srep22431
Zhao Z., Wu J., Mu X., Chen H., Qi H. J., Fang D.. Origami by frontal photopolymerization[J]. Sci. Adv., 2017,3(4). doi: 10.1126/sciadv.1602326
Sokol, Z., The U. S. Army is investing in 4D printing, expect craziness like self-altering camo. https://creators.vice.com/en_us/article/yp5m8x/the-us-army-is-investing-in-4d-printing-expect-crazy-results.
Kuribayashi K., Tsuchiya K., You Z., Tomus D., Umemoto M., Ito T., Sasaki M.. Self-deployable origami stent grafts as a biomedical application of Ni-rich TiNi shape memory alloy foil[J]. Sci. Eng. A Struct. Mater., 2006,419(1-2):131-137. doi: 10.1016/j.msea.2005.12.016
Wache H. M., Tartakowska D. J., Hentrich A., Wagner M. H.. Development of a polymer stent with shape memory effect as a drug delivery system[J]. J. Mater. Sci. Mater. Med., 2003,14(2):109-112. doi: 10.1023/A:1022007510352
Mengchen Liu , Yufei Zhang , Yi Xiao , Yang Wei , Meichen Bi , Huaide Jiang , Yan Yu , Shenghong Zhong . High stretchability and toughness of liquid metal reinforced conductive biocompatible hydrogels for flexible strain sensors. Chinese Journal of Structural Chemistry, 2025, 44(3): 100518-100518. doi: 10.1016/j.cjsc.2025.100518
Xi Chen , Xue Zhang , Shuai Yang , Jie Wang , Tian Tang , Maling Gou . An adhesive hydrogel for the treatment of oral ulcers. Chinese Chemical Letters, 2025, 36(3): 110021-. doi: 10.1016/j.cclet.2024.110021
Ningyue Xu , Jun Wang , Lei Liu , Changyang Gong . Injectable hydrogel-based drug delivery systems for enhancing the efficacy of radiation therapy: A review of recent advances. Chinese Chemical Letters, 2024, 35(8): 109225-. doi: 10.1016/j.cclet.2023.109225
Tong Zhang , Xiaojing Liang , Licheng Wang , Shuai Wang , Xiaoxiao Liu , Yong Guo . An ionic liquid assisted hydrogel functionalized silica stationary phase for mixed-mode liquid chromatography. Chinese Chemical Letters, 2025, 36(1): 109889-. doi: 10.1016/j.cclet.2024.109889
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