Citation: Ying-jie Xu, Yi-hu Song, Qiang Zheng. Effects of Nanosilica on Crystallization and Thermal Ageing Behaviors of Polyethylene Terephthalate[J]. Chinese Journal of Polymer Science, ;2015, 33(5): 697-708. doi: 10.1007/s10118-015-1619-x shu

Effects of Nanosilica on Crystallization and Thermal Ageing Behaviors of Polyethylene Terephthalate

1.
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China

Received Date: 19 August 2014
Revised Date: 15 November 2014

Fund Project: This work was financially supported by the Jiangsu Yuxing Film Technology Co. Ltd., China.

The effects of nanosilica (SiO2) on crystallization and thermal aging behaviors of polyethylene terephthalate (PET) have been studied using differential scanning calorimetry (DSC) and polarized optical microscopy (POM), viscometry, tensile testing and scanning electron microscopy (SEM). For non-isothermal and isothermal crystallizations, the crystallization rate of PET increases considerably with increasing content of SiO2 providing a large number of nucleation sites, but the relative crystallinity of the nanocomposites has little differences with that of neat PET. According to POM observation, the nucleation of PET becomes faster and the nucleation density increases significantly with increasing SiO2 content. For PET and its nanocomposites thermally aged at 190 ℃, the results of intrinsic viscosity, carboxyl content and tensile test show that the degradation rate of PET is reduced with the addition of a small content of SiO2, but the degradation rate increases with further addition of SiO2, owing to the dual effect of SiO2 on PET degradation.
- Polyethylene terephthalate,
- Nanosilica,
- Crystallization,
- Thermal ageing
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
44. [44]
45. [45]
1. [1]
  Yarui Li , Huangjie Lu , Yingzhe Du , Jie Qiu , Peng Lin , Jian Lin . Highly efficient separation of high-valent actinide ions from lanthanides via fractional crystallization. Chinese Journal of Structural Chemistry, 2025, 44(4): 100562-100562. doi: 10.1016/j.cjsc.2025.100562
2. [2]
  Jaeheon Lee , Jung Hyeun Kim . Effect of thermal annealing on cold crystallization ability of thermoset polyurethane elastomer synthesized from fully bio-derived polyol. Chinese Journal of Structural Chemistry, 2025, 44(5): 100568-100568. doi: 10.1016/j.cjsc.2025.100568
3. [3]
  Tinghui Hu , Junwen Long , Yi Long , Xuanhe Liu . Plastic Disillusionment. University Chemistry, 2025, 40(7): 249-254. doi: 10.12461/PKU.DXHX202409004
4. [4]
  Lanjun Cheng , Xinyuan Wang , Jie An , Xiang Wu , Chengfeng Zhu , Yanming Fu , Yougui Li . Improvement of the Resolution Experiment of Racemic Tartaric Acid. University Chemistry, 2025, 40(7): 277-285. doi: 10.12461/PKU.DXHX202408010
5. [5]
  Xiuqiong Zeng , Jiqing Cai , Chen Chen , Yanping Ren , Wan Li , Yongxian Fan , Faqiong Zhao , Wenwei Zhang , Mei Shi , Min Hu , Kai Hu , Xiuyun Wang , Weihong Li , Yong Fan , Xiaohang Qiu , Juanjuan Song , Dongcheng Liu , Jianrong Zhang , Shuyong Zhang . Suggestions on Dissolution, Crystallization and Crystal Cultivation. University Chemistry, 2026, 41(3): 191-199. doi: 10.12461/PKU.DXHX202507045
6. [6]
  Jun Lu , Jinrui Yan , Yaohao Guo , Junjie Qiu , Shuangliang Zhao , Bo Bao . Controlling solid form and crystal habit of triphenylmethanol by antisolvent crystallization in a microfluidic device. Chinese Chemical Letters, 2024, 35(4): 108876-. doi: 10.1016/j.cclet.2023.108876
7. [7]
  Xia-Lin Dai , Yu-Hang Yao , Jian-Feng Zhen , Wei Gao , Jia-Mei Chen , Tong-Bu Lu . Reaction crystallization method based on deep eutectic solvents: A novel, green and efficient cocrystal synthesis approach. Chinese Chemical Letters, 2025, 36(11): 110413-. doi: 10.1016/j.cclet.2024.110413
8. [8]
  Shuang Li , Penghui Yuan , Xinyi Zhang , Meiru Liu , Dezhi Yang , Linglei Kong , Li Zhang , Yang Lu , Guanhua Du . Revolutionizing sepsis therapy: Machine learning-driven co-crystallization reveals emodin's therapeutic potential. Chinese Chemical Letters, 2026, 37(2): 111289-. doi: 10.1016/j.cclet.2025.111289
9. [9]
  Haibo Ye , Qianyu Li , Juan Li , Didi Li , Zhimin Ao . Review on the abiotic degradation of biodegradable plastic poly(butylene adipate-terephthalate): Mechanisms and main factors of the degradation. Chinese Chemical Letters, 2025, 36(1): 109861-. doi: 10.1016/j.cclet.2024.109861
10. [10]
  Qiang Cao , Xue-Feng Cheng , Jia Wang , Chang Zhou , Liu-Jun Yang , Guan Wang , Dong-Yun Chen , Jing-Hui He , Jian-Mei Lu . Graphene from microwave-initiated upcycling of waste polyethylene for electrocatalytic reduction of chloramphenicol. Chinese Chemical Letters, 2024, 35(4): 108759-. doi: 10.1016/j.cclet.2023.108759
11. [11]
  Min Chen , Boyu Peng , Xuyun Guo , Ye Zhu , Hanying Li . Polyethylene interfacial dielectric layer for organic semiconductor single crystal based field-effect transistors. Chinese Chemical Letters, 2024, 35(4): 109051-. doi: 10.1016/j.cclet.2023.109051
12. [12]
  Xiaxia Xing , Xiaoyu Chen , Zhenxu Li , Xinhua Zhao , Yingying Tian , Xiaoyan Lang , Dachi Yang . Polyethylene imine functionalized porous carbon framework for selective nitrogen dioxide sensing with smartphone communication. Chinese Chemical Letters, 2024, 35(9): 109230-. doi: 10.1016/j.cclet.2023.109230
13. [13]
  Yue Ren , Kang Li , Yi-Zi Wang , Shao-Peng Zhao , Shu-Min Pan , Haojie Fu , Mengfan Jing , Yaming Wang , Fengyuan Yang , Chuntai Liu . Swelling and erosion assisted sustained release of tea polyphenol from antibacterial ultrahigh molecular weight polyethylene for joint replacement. Chinese Chemical Letters, 2025, 36(2): 110468-. doi: 10.1016/j.cclet.2024.110468
14. [14]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957
15. [15]
  Zihe SONG , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Crystal structure, thermal analysis, and luminescence properties of six heterocyclic lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 181-192. doi: 10.11862/CJIC.20250126
16. [16]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
17. [17]
  Ruizhi Yang , Xia Li , Weiping Guo , Zixuan Chen , Hongwei Ming , Zhong-Zhen Luo , Zhigang Zou . New thermoelectric semiconductors Pb5Sb12+xBi6-xSe32 with ultralow thermal conductivity. Chinese Journal of Structural Chemistry, 2024, 43(3): 100268-100268. doi: 10.1016/j.cjsc.2024.100268
18. [18]
  Chaozheng He , Pei Shi , Donglin Pang , Zhanying Zhang , Long Lin , Yingchun Ding . First-principles study of the relationship between the formation of single atom catalysts and lattice thermal conductivity. Chinese Chemical Letters, 2024, 35(6): 109116-. doi: 10.1016/j.cclet.2023.109116
19. [19]
  Zhiqing Ge , Zuxiong Pan , Shuo Yan , Baoying Zhang , Xiangyu Shen , Mozhen Wang , Xuewu Ge . Novel high-temperature thermochromic polydiacetylene material and its application as thermal indicator. Chinese Chemical Letters, 2024, 35(11): 109850-. doi: 10.1016/j.cclet.2024.109850
20. [20]
  Guizhi Zhu , Junrui Tan , Longfei Tan , Qiong Wu , Xiangling Ren , Changhui Fu , Zhihui Chen , Xianwei Meng . Growth of CeCo-MOF in dendritic mesoporous organosilica as highly efficient antioxidant for enhanced thermal stability of silicone rubber. Chinese Chemical Letters, 2025, 36(1): 109669-. doi: 10.1016/j.cclet.2024.109669

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1660)
HTML views(65)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142