Citation: Yan Xin, Hong Wang, Bo-wen Liu, Jin-ying Yuan. Synthesis and MALDI-TOF Characterization of -CD Core ATRP Initiators and RAFT Chain Transfers with Different Degrees of Substitution[J]. Chinese Journal of Polymer Science, ;2015, 33(1): 36-48. doi: 10.1007/s10118-015-1572-8 shu

Synthesis and MALDI-TOF Characterization of -CD Core ATRP Initiators and RAFT Chain Transfers with Different Degrees of Substitution

Yan Xin ¹ ,
Hong Wang ¹ ,
Bo-wen Liu ¹ ,
Jin-ying Yuan ^1,,

1.
Key Lab of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China

Corresponding author: Jin-ying Yuan,
Received Date: 17 March 2014
Revised Date: 4 May 2014

Fund Project: This work was financially supported by the National Natural Science Foundation of China (Nos. 21174076 and 21374053).

In this paper, three different kinds of -CD derivatives were synthesized as atom transfer radical polymerization (ATRP) initiator or reversible addition-fragmentation chain transfer polymerization (RAFT) chain transfers. The degree of substitution for each derivative was carefully characterized through 1H-NMR, 13C-NMR spectroscopy and matrix-assisted laser desorption/ionization time of flight mass spectrometry (MALDI-TOF-MS). The factors influencing the degree of substitution were discussed. Moreover, the comparison between ATRP and RAFT was shown in the polymerization of N-isopropyl acrylamide (NIPAM).
- -CD core star polymers,
- MALDI-TOF,
- ATRP initiators,
- RAFT chain transfers,
- GPC
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
44. [44]
45. [45]
46. [46]
47. [47]
48. [48]
49. [49]
50. [50]
51. [51]
52. [52]
53. [53]
54. [54]
55. [55]
56. [56]
57. [57]
58. [58]
59. [59]
60. [60]
61. [61]
62. [62]
63. [63]
64. [64]
65. [65]
66. [66]
67. [67]
68. [68]
69. [69]
70. [70]
71. [71]
72. [72]
73. [73]
74. [74]
75. [75]
76. [76]
77. [77]
78. [78]
79. [79]
80. [80]
81. [81]
82. [82]
83. [83]
84. [84]
1. [1]
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