Citation: Dan-dan Wu, Wu Li, Hong-yu Liang, San-rong Liu, Jian-yong Fang, Hui-liang Zhang, Hui-xuan Zhang, Li-song Dong. Thermal, Mechanical and Rheological Properties of Eco-friendly Poly(propylene carbonate)/Poly(1, 2-propylene succinate) Blends[J]. Chinese Journal of Polymer Science, ;2014, 32(7): 914-922. doi: 10.1007/s10118-014-1466-1 shu

Thermal, Mechanical and Rheological Properties of Eco-friendly Poly(propylene carbonate)/Poly(1, 2-propylene succinate) Blends

Dan-dan Wu ^1,2,3 ,
Wu Li ^1,2,3 ,
Hong-yu Liang ^1,2,3 ,
San-rong Liu ⁴ ,
Jian-yong Fang ⁴ ,
Hui-liang Zhang ^4,, ,
Hui-xuan Zhang ⁵ ,
Li-song Dong ⁴

1.
1. Changchun University of Technology, Changchun 130012, China
2.
2. Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry, Changchun 130022, China
3.
4.
Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry, Changchun 130022, China
5.
Changchun University of Technology, Changchun 130012, China

Corresponding author: Hui-liang Zhang,
Received Date: 29 October 2013
Revised Date: 11 December 2013

Fund Project: This work was financially supported by the Science Technology Bureau of Jilin Province of China (No. 20126023), the National High Technology Research and Development Program of China (863 Program) (No. 2012AA062904) and the National Natural Science Foundation of China (No. 51021003).

In order to improve the flexibility of poly(propylene carbonate) (PPC), poly(1,2-propylene succinate) (PPSu) was used to plasticize PPC in a batch mixer. The effects of PPSu on the miscibility, thermal stability, mechanical and rheological properties of the blends were investigated. PPC was partially miscible with PPSu. It was demonstrated that PPSu decreased the glass transition temperature and melt viscosity of PPC, as shown in the DSC and rheological curves. With the increase in PPSu content, the PPC/PPSu blends showed decreased tensile strength, however, the elongation at break was increased to 1100% for the 70/30 PPC/PPSu blend. The introduction of PPSu provided an efficient and novel plasticization method to extend the application area of PPC.
- Biodegradable,
- Poly(propylene carbonate),
- Poly(1,2-propylene succinate),
- Miscibility,
- Blends
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