Citation:
L. Guru Prasad. Azo Dye Doped Polymer Films for Nonlinear Optical Applications[J]. Chinese Journal of Polymer Science,
;2014, 32(5): 650-657.
doi:
10.1007/s10118-014-1441-x
-
Azo dye doped polymer films were prepared on glass substrates using spin-coating technique. FTIR, UV-Vis spectra and PL measurements were recorded to characterize the structure of the metanil yellow doped PVA films. Surface morphology and thickness of the films were studied using AFM and FESEM. The magnitude of both real and imaginary parts of third-order nonlinear susceptibility 3 of metanil yellow were determined by the Z-scan technique. The nonlinear refractive index n2 and the nonlinear absorption coefficient of the azo dye doped polymer films were calculated respectively. The real part of the third-order susceptibility 3 is much larger than its imaginary part indicating that the third-order optical response of the metanil yellow doped PVA films is dominated by the optical nonlinear refractive behavior.
-
Keywords:
- Azo dye,
- PVA,
- Nonlinear optical materials
-
-
-
[1]
-
[2]
-
[3]
-
[4]
-
[5]
-
[6]
-
[7]
-
[8]
-
[9]
-
[10]
-
[11]
-
[12]
-
[13]
-
[14]
-
[15]
-
[16]
-
[17]
-
[18]
-
[19]
-
[20]
-
[21]
-
[1]
-
-
-
[1]
Hongshan Wang , Zhenglong Li , Ran An , Zhenyou Wang , Juanjuan Lu , Guansong Zheng , Zhihua Yang , Yu Chu , Junjie Li . NaAg3Ga8S14: A new diamond-like framework infrared nonlinear optical material derived from AgGaS2. Chinese Journal of Structural Chemistry, 2025, 44(12): 100757-100757. doi: 10.1016/j.cjsc.2025.100757
-
[2]
Xiaodong Zhang , Bohui Xu , Deshuai Xiao , Xinyuan Zhang , Pifu Gong , Zheshuai Lin . From centrosymmetric CN3H6C6H5SO3 to non-centrosymmetric CN3H6C6H4SO3(OH): Hydroxyl introduced hydrogen bond reconstruction to realize strong second harmonic generation. Chinese Journal of Structural Chemistry, 2025, 44(10): 100707-100707. doi: 10.1016/j.cjsc.2025.100707
-
[3]
Xing Cao , Xinyu Tian , Yuanyuan Huang , Liping Zhang , Yanpeng Ni , Yu-Zhong Wang . H3PO3-protonated chitosan enabling flame-retardant and antibacterial PVA composite films with high strength and toughness through multiple H-bonds and interlocking interfaces. Chinese Chemical Letters, 2025, 36(11): 111382-. doi: 10.1016/j.cclet.2025.111382
-
[4]
Jiajing Wu , Ru-Ling Tang , Sheng-Ping Guo . Three types of promising functional building units for designing metal halide nonlinear optical crystals. Chinese Journal of Structural Chemistry, 2024, 43(6): 100291-100291. doi: 10.1016/j.cjsc.2024.100291
-
[5]
Lihua Gao , Yinglei Han , Chensheng Lin , Huikang Jiang , Guang Peng , Guangsai Yang , Jindong Chen , Ning Ye . Halogen-assisted octet binding electrons construction of pnictogens towards wide-bandgap nonlinear optical pnictides. Chinese Chemical Letters, 2024, 35(12): 109529-. doi: 10.1016/j.cclet.2024.109529
-
[6]
Hongyuan Sha , Dongling Yang , Yanran Shang , Zujian Wang , Rongbing Su , Chao He , Xiaoming Yang , Xifa Long . Trithionic guanidine: A novel semi-organic short-wave ultraviolet nonlinear optical sulfate with dimeric heteroleptic tetrahedra. Chinese Chemical Letters, 2025, 36(4): 109730-. doi: 10.1016/j.cclet.2024.109730
-
[7]
Yangfeifei Ou , Xiao-Liang Zhou , You-Zhao Lan , Jian-Wen Cheng . Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions. Chinese Journal of Structural Chemistry, 2025, 44(9): 100708-100708. doi: 10.1016/j.cjsc.2025.100708
-
[8]
Yijia Chen , Wendan Luo , Ke Liu , Taihong Liu , Liping Ding , Yu Fang . Diverse roles of indacenodithiophene in push-pull chromophores for enhanced two-photon absorption and efficient nonlinear optical limiting. Chinese Journal of Structural Chemistry, 2025, 44(10): 100704-100704. doi: 10.1016/j.cjsc.2025.100704
-
[9]
Ying Xu , Yan Pu , Qiong Zhang , Xi Kang , Manzhou Zhu . Order-by-order control over the nonlinear optical properties of atomically precise nanoclusters. Chinese Journal of Structural Chemistry, 2025, 44(10): 100735-100735. doi: 10.1016/j.cjsc.2025.100735
-
[10]
Li Zhou , Fengyu Li , Zhou Lu , Yingwei Wang , Jun He . Two-dimensional atomic crystals for third-order nonlinear optical modulation. Chinese Journal of Structural Chemistry, 2026, 45(2): 100772-100772. doi: 10.1016/j.cjsc.2025.100772
-
[11]
Le Ye , Zi-Luo Fang , Ming-Yu Guo , Wei-Xiong Zhang . Hot-pressing boosted nonlinear optical properties in a new ferroelectric plastic crystalline material. Chinese Chemical Letters, 2026, 37(4): 110826-. doi: 10.1016/j.cclet.2025.110826
-
[12]
Ruiyan CHEN , Yanping HE , Jian ZHANG . Synthesis and third-order nonlinear optical property of Ti4L6 cage-based metal-organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2149-2156. doi: 10.11862/CJIC.20250177
-
[13]
Yuwei Kang , Can Yang , Jun Zhang , Qi Wu . Synergistic triple-site engineering in ABX3-type hybrid halides for high-performance nonlinear optical crystals. Chinese Chemical Letters, 2026, 37(1): 111385-. doi: 10.1016/j.cclet.2025.111385
-
[14]
Tianyang Dong , Xingyuan Wen , Xingzhi Wu , Ying Jiang , Chong Wang , Ruizhi Liu , Junyi Li , Wenfa Zhou , Yinglin Song , Xiaofeng Shi , Rui Wen , Chunru Wang , Li Jiang , Chunli Bai . Ionic covalent organic frameworks enable laser-pulse-duration-dependent high third-order nonlinear optical responses. Chinese Journal of Structural Chemistry, 2025, 44(10): 100733-100733. doi: 10.1016/j.cjsc.2025.100733
-
[15]
Fan Liu , Pifu Gong , Zheshuai Lin , Lei Kang . REXCO3 (RE = La, Ce, Y; X = OH, F) with circular alignment of anionic motifs induced extraordinary nonlinear optical effects. Chinese Journal of Structural Chemistry, 2026, 45(3): 100844-100844. doi: 10.1016/j.cjsc.2025.100844
-
[16]
Yinghao Zhang , Ke Shao , Yihang Zhu , Haokun Zhang , Yinuo Zhuo , Huihui Bao , Yeye Ai , Yongguang Li . Unanticipated optical properties of π-conjugated cyclometalated Pt(Ⅱ) complexes for advanced information storage and anti-counterfeiting materials. Chinese Chemical Letters, 2025, 36(9): 110735-. doi: 10.1016/j.cclet.2024.110735
-
[17]
Lei ZHANG , Cheng HE , Yang JIAO . An azo-based fluorescent probe for the detection of hypoxic tumor cells. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1162-1172. doi: 10.11862/CJIC.20250081
-
[18]
Pu Zhang , Xiang Mao , Xuehua Dong , Ling Huang , Liling Cao , Daojiang Gao , Guohong Zou . Two UV organic-inorganic hybrid antimony-based materials with superior optical performance derived from cation-anion synergetic interactions. Chinese Chemical Letters, 2024, 35(9): 109235-. doi: 10.1016/j.cclet.2023.109235
-
[19]
Yu-Hang Miao , Zheng-Xu Zhang , Xu-Yi Huang , Yuan-Zhao Hua , Shi-Kun Jia , Xiao Xiao , Min-Can Wang , Li-Ping Xu , Guang-Jian Mei . Catalytic asymmetric dearomative azo-Diels–Alder reaction of 2-vinlyindoles. Chinese Chemical Letters, 2024, 35(4): 108830-. doi: 10.1016/j.cclet.2023.108830
-
[20]
Baoqi Wu , Rongzhi Tang , Zhi-Wei Li , Feng Lin , Zongyu Sun , Huanyu Xia , Lin Jiang , Yu Tan . Selective encapsulation of azo compounds by tetracationic cyclophane in water and photo-controlled reversible release. Chinese Chemical Letters, 2025, 36(9): 110896-. doi: 10.1016/j.cclet.2025.110896
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(1794)
- HTML views(28)
Login In
DownLoad: