Synthesis and Optical Properties of Hyperbranched PAEKs Containing Porphyrin and Its Metal Derivatives

Citation: Xu Jiang, Yin-long Du, Chuan Liu, Peng-fei Huo, Zhi Geng, Shu-ling Zhang, Gui-bin Wang. Synthesis and Optical Properties of Hyperbranched PAEKs Containing Porphyrin and Its Metal Derivatives[J]. Chinese Journal of Polymer Science, 2014, 32(1): 73-83. doi: 10.1007/s10118-014-1375-3 shu

Synthesis and Optical Properties of Hyperbranched PAEKs Containing Porphyrin and Its Metal Derivatives

1.
College of Chemistry, Engineering Research Center of High Performance Plastics, Ministry of Education, Jilin University, Changchun 130012, China
基金项目:
This work was financially supported by the grants from Ph.D. Program Foundation of Ministry of Education of China (No. 20120061110017).

摘要: Novel functional hyperbranched poly(aryl ether ketone)s (HPAEKs) bonded with nonlinear optical chromophores (meso-tetrakis(4-hydroxyphenyl) porphyrin, THPP and its metal derivatives) were synthesized and characterized by 1H-NMR and UV-Vis absorption spectra. The incorporation of chromophores into HPAEKs endowed HPAEKs novel NLO and OL properties. Indeed, dendritic architecture allowed for maximum dispersion of the chromophores, avoided aggregation, more optical limiting property was obtained. Simultaneously, they retained the excellent properties of the materials, particularly in thermal stability. Their optical properties were evaluated by nonlinear optical analyses and optical limiting. The results showed that these polymers possessed good optical limiting (OL) property and large nonlinear optical (NLO) susceptibilities (ca. 10-12 esu). All polymers containing chromophores presented excellent thermal stability (DT5 524.17 ℃).

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English

Synthesis and Optical Properties of Hyperbranched PAEKs Containing Porphyrin and Its Metal Derivatives

1.
College of Chemistry, Engineering Research Center of High Performance Plastics, Ministry of Education, Jilin University, Changchun 130012, China
Received Date: 18 February 2013
Revised Date: 06 May 2013
Available Online: 05 January 2014
Fund Project:
This work was financially supported by the grants from Ph.D. Program Foundation of Ministry of Education of China (No. 20120061110017).

Abstract: Novel functional hyperbranched poly(aryl ether ketone)s (HPAEKs) bonded with nonlinear optical chromophores (meso-tetrakis(4-hydroxyphenyl) porphyrin, THPP and its metal derivatives) were synthesized and characterized by 1H-NMR and UV-Vis absorption spectra. The incorporation of chromophores into HPAEKs endowed HPAEKs novel NLO and OL properties. Indeed, dendritic architecture allowed for maximum dispersion of the chromophores, avoided aggregation, more optical limiting property was obtained. Simultaneously, they retained the excellent properties of the materials, particularly in thermal stability. Their optical properties were evaluated by nonlinear optical analyses and optical limiting. The results showed that these polymers possessed good optical limiting (OL) property and large nonlinear optical (NLO) susceptibilities (ca. 10-12 esu). All polymers containing chromophores presented excellent thermal stability (DT5 524.17 ℃).

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Optical Properties of Hyperbranched PAEKs Containing Porphyrin and Its Metal Derivatives

English

Synthesis and Optical Properties of Hyperbranched PAEKs Containing Porphyrin and Its Metal Derivatives

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Synthesis and Optical Properties of Hyperbranched PAEKs Containing Porphyrin and Its Metal Derivatives

English

Synthesis and Optical Properties of Hyperbranched PAEKs Containing Porphyrin and Its Metal Derivatives

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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