Citation: Qiang Liu a, You-ke Huang a, Xiang-dong Zhou b, You-liang Zhao a. SYNTHESIS OF HETEROARM STAR POLYMERS COMPRISING POLY(4-METHYLPHENYL VINYL SULFOXIDE) SEGMENT BY LIVING ANIONIC POLYMERIZATION[J]. Chinese Journal of Polymer Science, ;2010, 28(5): 819-828. doi: 10.1007/s10118-010-9166-y shu

SYNTHESIS OF HETEROARM STAR POLYMERS COMPRISING POLY(4-METHYLPHENYL VINYL SULFOXIDE) SEGMENT BY LIVING ANIONIC POLYMERIZATION

Received Date: 9 November 2009
Revised Date: 21 December 2009

A series of 3-arm ABC and AA'B and 4-arm ABCD, AA'BC and AA'A"B heteroarm star polymers comprising one poly(4-methylphenyl vinyl sulfoxide) segment and other segments such as polystyrene, poly(α-methylstyrene), poly(4-methoxystyrene) and poly(4-trimethylsilylstyrene) were synthesized by living anionic polymerization based on diphenylethylene (DPE) chemistry. The DPE-functionalized polymers were synthesized by iterative methodology, and the objective star polymers were prepared by two distinct methodologies based on anionic polymerization using DPE-functionalized polymers. The first methodology involves an addition reaction of living anionic polymer with excess DPE-functionalized polymer and a subsequent living anionic polymerization of 4-methylphenyl vinyl sulfoxide (MePVSO) initiated from the in situ formed polymer anion with two or three polymer segments. The second methodology comprises an addition reaction of DPE-functionalized polymer with excess sec-BuLi and a following anionic polymerization of MePVSO initiated from the in situ formed polymer anion and 3-methyl-1,1-diphenylpentyl anion as well. Both approaches could afford the target heteroarm star polymers with predetermined molecular weight, narrow molecular weight distribution (Mw/Mn 1.03) and desired composition, evidenced by SEC, 1H-NMR and SLS analyses. These polymers can be used as model polymers to investigate structure-property relationships in heteroarm star polymers.
1. [1]
  Cong-Bin Ji , Ding-Xiong Xie , Mei Chen , Ye-Ying Lan , Bao-Hua Zhang , Ji-Ying Yang , Zheng-Hui Kang , Shu-Jie Chen , Yu-Wei Zhang , Yun-Lin Liu . Green synthesis of 2-trifluoromethylquinoline skeletons via organocatalytic N-[(α-trifluoromethyl)vinyl]isatins CN bond activation. Chinese Chemical Letters, 2025, 36(7): 110598-. doi: 10.1016/j.cclet.2024.110598
2. [2]
  Wenyi Mei , Lijuan Xie , Xiaodong Zhang , Cunjian Shi , Fengzhi Wang , Qiqi Fu , Zhenjiang Zhao , Honglin Li , Yufang Xu , Zhuo Chen . Design, synthesis and biological evaluation of fluorescent derivatives of ursolic acid in living cells. Chinese Chemical Letters, 2024, 35(5): 108825-. doi: 10.1016/j.cclet.2023.108825
3. [3]
  Man Xu , Qianyi Li , Jingyao Ma , Hao Li , Yunfei Zhu , Fan Yu , Kuande Wang , Tao Zhou , Quanyou Feng , Linghai Xie , Jinyi Lin . Wide bandgap steric carbazole-fluorene-nanogrid polymers via metal-free CN polymerization for deep-blue polymer light-emitting diodes. Chinese Chemical Letters, 2026, 37(1): 111551-. doi: 10.1016/j.cclet.2025.111551
4. [4]
  Chen Lian , Si-Han Zhao , Hai-Lou Li , Xinhua Cao . A giant Ce-containing poly(tungstobismuthate): Synthesis, structure and catalytic performance for the decontamination of a sulfur mustard simulant. Chinese Chemical Letters, 2024, 35(10): 109343-. doi: 10.1016/j.cclet.2023.109343
5. [5]
  Xiao Liu , Hangqi Liu , Qian Wang , Dandan Zheng , Sibo Wang , Masakazu Anpo , Guigang Zhang . Rational synthesis of poly(heptazine imides) nanorod in ternary LiCl/NaCl/KCl for visible light hydrogen production. Chinese Chemical Letters, 2025, 36(12): 111621-. doi: 10.1016/j.cclet.2025.111621
6. [6]
  Zhenzhu Wang , Chenglong Liu , Yunpeng Ge , Wencan Li , Chenyang Zhang , Bing Yang , Shizhong Mao , Zeyuan Dong . Differentiated self-assembly through orthogonal noncovalent interactions towards the synthesis of two-dimensional woven supramolecular polymers. Chinese Chemical Letters, 2024, 35(5): 109127-. doi: 10.1016/j.cclet.2023.109127
7. [7]
  Peipei CUI , Xin LI , Yilin CHEN , Zhilin CHENG , Feiyan GAO , Xu GUO , Wenning YAN , Yuchen DENG . Transition metal coordination polymers with flexible dicarboxylate ligand: Synthesis, characterization, and photoluminescence property. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2221-2231. doi: 10.11862/CJIC.20240234
8. [8]
  Dongdong YANG , Jianhua XUE , Yuanyu YANG , Meixia WU , Yujia BAI , Zongxuan WANG , Qi MA . Design and synthesis of two coordination polymers for the rapid detection of ciprofloxacin based on triphenylpolycarboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2466-2474. doi: 10.11862/CJIC.20240266
9. [9]
  Yuetong Gao , Tong Mu , Xinyue Hu , Yang Pang , Chengji Zhao . Facile synthesis of all-carbon fluorinated backbone polymers containing sulfide linkage as proton exchange membranes for fuel cells. Chinese Chemical Letters, 2025, 36(6): 110763-. doi: 10.1016/j.cclet.2024.110763
10. [10]
  Yinxia SUN , Liping LIU , Xue BAI , Yu SUN , Wanhong SUN , Zhepeng DENG , Jianghai CHEN , Jianjun WANG , Li XU , Shuzhen ZHANG . Synthesis and crystal structures of Co(Ⅱ)/Cu(Ⅱ) coordination polymers based on solvent and ligand concentration regulation strategy. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 340-354. doi: 10.11862/CJIC.20250226
11. [11]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
12. [12]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
13. [13]
  Haojie Song , Laiyu Luo , Siyu Wang , Guo Zhang , Baojiang Jiang . Advances in poly(heptazine imide)/poly(triazine imide) photocatalyst. Chinese Chemical Letters, 2024, 35(10): 109347-. doi: 10.1016/j.cclet.2023.109347
14. [14]
  Gaofeng WANG , Shuwen SUN , Lixin Meng , Dequn PENG . Syntheses and fluorescent sensing properties of two coordination polymers based on 9, 9′-dihexyl-2, 7-di(pyridin-4-yl)fluorene. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 331-339. doi: 10.11862/CJIC.20250260
15. [15]
  Weixia Wang , Yongji Zhang , Fei Zhao , Libo Wang , Fanpeng Meng , Shuchao Qin , Jinsheng Zhao . Engineering π-delocalized network in fused-thiophene based polymers/g-C3N4 S-scheme heterojunctions for photocatalytic H2 evolution. Chinese Journal of Structural Chemistry, 2026, 45(3): 100833-100833. doi: 10.1016/j.cjsc.2025.100833
16. [16]
  Jingfeng Yue , Zhenxin Tang , Yuxing Zhang , Zhongbao Jian . Oligomeric α-diimine nickel catalysts for enhanced ethylene polymerization. Chinese Chemical Letters, 2026, 37(1): 111930-. doi: 10.1016/j.cclet.2025.111930
17. [17]
  Wang CHEN , Guixian WU , Yingying XIONG , Ming CHENG , Mingming ZHOU , Hui ZHANG , Zhengyun LIANG , Dejin HUANG , Minghua CHEN . Crystal structures of complexes of cyclobutanocucurbit[5]uril with Na⁺/K⁺: Coordination state in different anionic environments. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 161-169. doi: 10.11862/CJIC.20250195
18. [18]
  Yunfei Fu , Hui Li , Chengfei Liu , Wei Tian . Chemical reactions in living cells for enhanced biological treatment. Chinese Chemical Letters, 2026, 37(4): 112220-. doi: 10.1016/j.cclet.2025.112220
19. [19]
  Yuhao Ma , Yufei Zhou , Mingchuan Yu , Cheng Fang , Shaoxia Yang , Junfeng Niu . Covalently bonded ternary photocatalyst comprising MoSe₂/black phosphorus nanosheet/graphitic carbon nitride for efficient moxifloxacin degradation. Chinese Chemical Letters, 2024, 35(9): 109453-. doi: 10.1016/j.cclet.2023.109453
20. [20]
  Tianzhu Qin , Weiwei Zi . Palladium-catalyzed enantioselective [2σ + 2π] cycloadditions of vinyl-carbonyl-bicyclo[1.1.0]butanes with arylidenemalononitriles. Chinese Chemical Letters, 2026, 37(1): 111072-. doi: 10.1016/j.cclet.2025.111072

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1814)
HTML views(17)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return