引用本文:
Yi LI, Tao ZHANG, Yu Lin LI. First Total Synthesis of 6-Oxodendrolasinolide[J]. Chinese Chemical Letters,
2006, 17(2): 147-149.
Citation: Yi LI, Tao ZHANG, Yu Lin LI. First Total Synthesis of 6-Oxodendrolasinolide[J]. Chinese Chemical Letters, 2006, 17(2): 147-149.
Citation: Yi LI, Tao ZHANG, Yu Lin LI. First Total Synthesis of 6-Oxodendrolasinolide[J]. Chinese Chemical Letters, 2006, 17(2): 147-149.
First Total Synthesis of 6-Oxodendrolasinolide
摘要:
An efficient total synthesis of 6-oxodendrolasinolide 1, a new farnesane-based homosesquiterpene lactone, starting from geraniol 2 through twelve steps is described. Our work involved two key steps: (1) regioselective alkylation of the anion of vinyldithian 5 with allylic chloride 31, (2) Corey's oxidative lactionization method2.
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关键词:
- Total synthesis
- / butenolide
- / homosesquiterpene
English
First Total Synthesis of 6-Oxodendrolasinolide
Abstract:
An efficient total synthesis of 6-oxodendrolasinolide 1, a new farnesane-based homosesquiterpene lactone, starting from geraniol 2 through twelve steps is described. Our work involved two key steps: (1) regioselective alkylation of the anion of vinyldithian 5 with allylic chloride 31, (2) Corey's oxidative lactionization method2.
-
Key words:
- Total synthesis
- / butenolide
- / homosesquiterpene
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