引用本文:
Mao Xia HE, Feng ZHU, Da Cheng FENG, Zheng Ting CAI. The Study of Alcoholysis of 1, 2-Thiazetidine-1, 1-dioxide with Quantum Chemical Method[J]. Chinese Chemical Letters,
2004, 15(6): 745-748.
Citation: Mao Xia HE, Feng ZHU, Da Cheng FENG, Zheng Ting CAI. The Study of Alcoholysis of 1, 2-Thiazetidine-1, 1-dioxide with Quantum Chemical Method[J]. Chinese Chemical Letters, 2004, 15(6): 745-748.
Citation: Mao Xia HE, Feng ZHU, Da Cheng FENG, Zheng Ting CAI. The Study of Alcoholysis of 1, 2-Thiazetidine-1, 1-dioxide with Quantum Chemical Method[J]. Chinese Chemical Letters, 2004, 15(6): 745-748.
The Study of Alcoholysis of 1, 2-Thiazetidine-1, 1-dioxide with Quantum Chemical Method
摘要:
The alcoholysis mechanism of 1, 2-thiazetidine-1, 1-dioxide with methanol, in which the relatively stable product is sulfonate ester, has been investigated by quantum chemical method. Our calculations indicate the reaction for alcoholysis of 1, 2-thiazetidine-1, 1-dioxide proceeds via two possible mechanisms:concerted and stepwise. In the stepwise mechanism, two possible reaction pathways can be followed while only one possible reaction pathway can be followed in the concerted mechanism.
English
The Study of Alcoholysis of 1, 2-Thiazetidine-1, 1-dioxide with Quantum Chemical Method
Abstract:
The alcoholysis mechanism of 1, 2-thiazetidine-1, 1-dioxide with methanol, in which the relatively stable product is sulfonate ester, has been investigated by quantum chemical method. Our calculations indicate the reaction for alcoholysis of 1, 2-thiazetidine-1, 1-dioxide proceeds via two possible mechanisms:concerted and stepwise. In the stepwise mechanism, two possible reaction pathways can be followed while only one possible reaction pathway can be followed in the concerted mechanism.
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Key words:
- 1, 2-Thiazetidine-1, 1-dioxide
- / alcoholysis
- / quantum chemical method
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