{"研究论文":[{"abstractInfo":"采用浊度法研究了Pb-Ti复合醇盐的水解聚结过程。发现该过程随水量和醇盐浓度的增大而加快,碱(NH<sub>4<\/sub>OH)能够大大促进水解聚结反应,酸(HOAc)则在低浓度时起促进作用高浓度时起抑制作用。根据醇盐水解聚结的反应机理对以上结果作了解释。","abstractInfoCn":"采用浊度法研究了Pb-Ti复合醇盐的水解聚结过程。发现该过程随水量和醇盐浓度的增大而加快,碱(NH<sub>4<\/sub>OH)能够大大促进水解聚结反应,酸(HOAc)则在低浓度时起促进作用高浓度时起抑制作用。根据醇盐水解聚结的反应机理对以上结果作了解释。","abstractInfoEn":"The hydrolysis-condensation process of Pb-Ti complex alkoxide has been studied by turbidimetry. It was found that increase in both the amount of water and alkoxide concen-tration accelerated the hydrolysis-condensation reaction. NH<sub>4<\/sub>OH greatly promoted the hy-drolysis-condensation reaction,while HOAc showed a promotion effect at lower acid concen-tration,but a suppression effect at higher acid concentration. The results have been ex-plained in terms of hydrolysis-condensation reaction of alkoxide.","articleNo":"19950201","authorCnList":["齐利民","  马季铭","  程虎民","  赵振国"],"authorEnList":["Qi Limin","  Ma Jiming","  Cheng Humin","  Zhao Zhenguo"],"authorList":["齐利民","  马季铭","  程虎民","  赵振国"],"authors":"齐利民,  马季铭,  程虎民,  赵振国","authorsCn":"齐利民,  马季铭,  程虎民,  赵振国","authorsEn":"Qi Limin,  Ma Jiming,  Cheng Humin,  Zhao Zhenguo","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"齐利民,  马季铭,  程虎民,  赵振国. Pb-Ti复合醇盐的水解聚结过程. 应用化学, 1995, 12(2): 1-4.","citationCn":"齐利民,  马季铭,  程虎民,  赵振国. Pb-Ti复合醇盐的水解聚结过程. 应用化学, 1995, 12(2): 1-4.","citationEn":"齐利民,  马季铭,  程虎民,  赵振国. Hydrolysis-Condensation of Pb-Ti Complex Alkoxide. Chinese Journal of Applied Chemistry, 1995, 12(2): 1-4.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"1","highCitedState":"","htmlCount":56,"htmlFile":"","id":"e28fde0a-5058-426c-8c6a-3c7e924b64b7","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"复合醇盐, PbTiO<sub>3<\/sub>, 水解聚结, 浊度法","keywordCn":"复合醇盐, PbTiO<sub>3<\/sub>, 水解聚结, 浊度法","keywordCnList":["复合醇盐"," PbTiO<sub>3<\/sub>"," 水解聚结"," 浊度法"],"keywordEn":"complex alkoxide, PbTiO<sub>3<\/sub>, hydrolysis-condensation reaction, turbidimetry","keywordEnList":["complex alkoxide"," PbTiO<sub>3<\/sub>"," hydrolysis-condensation reaction"," turbidimetry"],"keywordList":["复合醇盐"," PbTiO<sub>3<\/sub>"," 水解聚结"," 浊度法"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"4","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":304.12,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"Pb-Ti复合醇盐的水解聚结过程","titleCn":"Pb-Ti复合醇盐的水解聚结过程","titleEn":"Hydrolysis-Condensation of Pb-Ti Complex Alkoxide","viewCount":449,"volume":"12","year":1995},{"abstractInfo":"采用FTIR、XPS和AES研究了金属铜表面M-S(M=Mo,W)簇合物膜。结果表明,Mo(W)S<sub>4<\/sub><sup>2-<\/sup>与铜表面的Cu<sub>2<\/sub>O反应,形成了Mo(W)-S-Cu键;簇合物膜由Mo(W)、S、Cu、O元素组成,分别呈+6、-2、+1、-2价,膜为多分子层结构并保持MoS<sub>4<\/sub>,或WS<sub>2<\/sub>单元,膜表面只有Cu、O而不存在Mo(W)、S.膜层厚度与反应时间有关,时间越长,膜越厚。膜为多组分的复杂体系,其颜色是各组分统计分布的结果。","abstractInfoCn":"采用FTIR、XPS和AES研究了金属铜表面M-S(M=Mo,W)簇合物膜。结果表明,Mo(W)S<sub>4<\/sub><sup>2-<\/sup>与铜表面的Cu<sub>2<\/sub>O反应,形成了Mo(W)-S-Cu键;簇合物膜由Mo(W)、S、Cu、O元素组成,分别呈+6、-2、+1、-2价,膜为多分子层结构并保持MoS<sub>4<\/sub>,或WS<sub>2<\/sub>单元,膜表面只有Cu、O而不存在Mo(W)、S.膜层厚度与反应时间有关,时间越长,膜越厚。膜为多组分的复杂体系,其颜色是各组分统计分布的结果。","abstractInfoEn":"The M-S (M=Mo,W) cluster compound films on copper surfaces have been in-vestigated by FTIR, XPS and AES. The results show that Mo(W)-S-Cu bonds were formed by the reaction of Mo(W)S<sub>4<\/sub><sup>2-<\/sup> with Cu<sub>2<\/sub>O layer on copper surface. The films are com-posed of Mo(W),S,Cu and O,each with the valence of +6,-2,+1 and -2,respective-ly. A multimolecular layer structure of the films was verified. Only Cu and O were found on the film surface, MoS<sub>4<\/sub> or WS<sub>2<\/sub> units remain in the inner layers of the films. The thickness of the film was found to depend on the reaction time: the longer the time,the thicker the film. The color of the films is probably caused by a statistical distribution of various layers and the film is a complicated multicomponent and multilayer system.","articleNo":"19950202","authorCnList":["叶向荣","  侯红卫","  忻新泉"],"authorEnList":["Ye Xiangrong","  Hou Hongwei","  Xin Xinquan"],"authorList":["叶向荣","  侯红卫","  忻新泉"],"authors":"叶向荣,  侯红卫,  忻新泉","authorsCn":"叶向荣,  侯红卫,  忻新泉","authorsEn":"Ye Xiangrong,  Hou Hongwei,  Xin Xinquan","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"叶向荣,  侯红卫,  忻新泉. 固相配位化学反应研究LXVII.金属铜表面M-S(M=Mo,W)簇合物膜的组成. 应用化学, 1995, 12(2): 5-8.","citationCn":"叶向荣,  侯红卫,  忻新泉. 固相配位化学反应研究LXVII.金属铜表面M-S(M=Mo,W)簇合物膜的组成. 应用化学, 1995, 12(2): 5-8.","citationEn":"叶向荣,  侯红卫,  忻新泉. Studies on Solid State Reactions of Coordination Compounds LXVII. Constitution of M-S(M=Mo,W) Cluster Compound Films on the Copper Surface. Chinese Journal of Applied Chemistry, 1995, 12(2): 5-8.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"5","highCitedState":"","htmlCount":55,"htmlFile":"","id":"a83a3b87-51ed-45b4-bafe-66b4968770d2","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"铜表面, 铝, 钨, 族合物膜","keywordCn":"铜表面, 铝, 钨, 族合物膜","keywordCnList":["铜表面"," 铝"," 钨"," 族合物膜"],"keywordEn":"copper surface, molybdenum, tungsten, cluster compound film","keywordEnList":["copper surface"," molybdenum"," tungsten"," cluster compound film"],"keywordList":["铜表面"," 铝"," 钨"," 族合物膜"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"8","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":2,"pdfSize":294.95,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"固相配位化学反应研究LXVII.金属铜表面M-S(M=Mo,W)簇合物膜的组成","titleCn":"固相配位化学反应研究LXVII.金属铜表面M-S(M=Mo,W)簇合物膜的组成","titleEn":"Studies on Solid State Reactions of Coordination Compounds LXVII. Constitution of M-S(M=Mo,W) Cluster Compound Films on the Copper Surface","viewCount":450,"volume":"12","year":1995},{"abstractInfo":"在氢离子浓度均为3mol/L的硫酸,盐酸,磷酸,醋酸水溶液中和冰醋酸中研究了具有Keggin结构的硅钨杂多酸(SiW<sub>12<\/sub>)在不同来源活性炭上的吸附作用.各活性炭对SiW<sub>12<\/sub>吸附等温线的形式是不相同的,吸附剂载体的微孔结构以及杂多酸的溶剂化起着重要的作用.并且在无机酸介质中,杂多酸的吸附量比在水溶液中成规律性地增加,且与酸强度成正比关系。在有机酸介质中,吸附作用比较复杂。根据所得结果,提出了在酸性介质中杂多酸在活性炭表面的吸附模型.","abstractInfoCn":"在氢离子浓度均为3mol/L的硫酸,盐酸,磷酸,醋酸水溶液中和冰醋酸中研究了具有Keggin结构的硅钨杂多酸(SiW<sub>12<\/sub>)在不同来源活性炭上的吸附作用.各活性炭对SiW<sub>12<\/sub>吸附等温线的形式是不相同的,吸附剂载体的微孔结构以及杂多酸的溶剂化起着重要的作用.并且在无机酸介质中,杂多酸的吸附量比在水溶液中成规律性地增加,且与酸强度成正比关系。在有机酸介质中,吸附作用比较复杂。根据所得结果,提出了在酸性介质中杂多酸在活性炭表面的吸附模型.","abstractInfoEn":"The adsorption of heteropoly acid (HPA) SiW<sub>12<\/sub> of Keggin structure on the acti-vated carbons of different sources has been studied in aqueous solutions of H<sub>2<\/sub>SO<sub>4<\/sub>, HCl, H<sub>3<\/sub>PO<sub>4<\/sub> with H<sup>+<\/sup> concentration of 3mol/L,aq. HAc solution and pure acetic acid. It is found that the forms of the adsorption isotherms of SiW<sub>12<\/sub> were different and the micropore struc-ture of the adsorbent and solvation of HPA have an important effect on HPA adsorption. In inorganic acid medium the amount of the adsorbed HPA was higher than it was in water, and there appeared a proportional relation between adsorptive capacity and acid strength of the medium. In organic acid medium the adsorption was more complex. An adsorption model of HPA in acid medium is proposed.","articleNo":"19950203","authorCnList":["楚文玲","  叶兴凯","  吴越"],"authorEnList":["Chu Wenling","  Ye Xingkai","  Wu Yue"],"authorList":["楚文玲","  叶兴凯","  吴越"],"authors":"楚文玲,  叶兴凯,  吴越","authorsCn":"楚文玲,  叶兴凯,  吴越","authorsEn":"Chu Wenling,  Ye Xingkai,  Wu Yue","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"楚文玲,  叶兴凯,  吴越. 杂多酸在活性炭上的固载化Ⅲ.活性炭在酸性介质中对钨硅杂多酸(SiW<sub>12<\/sub>)的吸附. 应用化学, 1995, 12(2): 9-12.","citationCn":"楚文玲,  叶兴凯,  吴越. 杂多酸在活性炭上的固载化Ⅲ.活性炭在酸性介质中对钨硅杂多酸(SiW<sub>12<\/sub>)的吸附. 应用化学, 1995, 12(2): 9-12.","citationEn":"楚文玲,  叶兴凯,  吴越. Heterogenization of Heteropoly Acids on the Activated Carbon Ⅲ. Adsorption of Dodecatungstosilicic Acid (SiW<sub>12<\/sub>) on Adivated Carbons in Acid Medium. Chinese Journal of Applied Chemistry, 1995, 12(2): 9-12.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"9","highCitedState":"","htmlCount":46,"htmlFile":"","id":"ae4a7f40-d366-48ea-acde-5f4765c949cb","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"钨硅酸, 吸附, 活性炭, 固载","keywordCn":"钨硅酸, 吸附, 活性炭, 固载","keywordCnList":["钨硅酸"," 吸附"," 活性炭"," 固载"],"keywordEn":"dodecatungstosilicic acid, adsorption, activated carbon, heterogenization","keywordEnList":["dodecatungstosilicic acid"," adsorption"," activated carbon"," heterogenization"],"keywordList":["钨硅酸"," 吸附"," 活性炭"," 固载"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"12","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":312.54,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"杂多酸在活性炭上的固载化Ⅲ.活性炭在酸性介质中对钨硅杂多酸(SiW<sub>12<\/sub>)的吸附","titleCn":"杂多酸在活性炭上的固载化Ⅲ.活性炭在酸性介质中对钨硅杂多酸(SiW<sub>12<\/sub>)的吸附","titleEn":"Heterogenization of Heteropoly Acids on the Activated Carbon Ⅲ. Adsorption of Dodecatungstosilicic Acid (SiW<sub>12<\/sub>) on Adivated Carbons in Acid Medium","viewCount":400,"volume":"12","year":1995},{"abstractInfo":"报道-类新的Schiff碱和咪唑的混合型金属配合物,即水杨醛缩甘氨酸、咪唑金属配合物和2,4-二羟基苯甲醛缩丙氨酸、咪唑金属配合物的合成.用溴化乙锭荧光分析法研究了这类配合物与DNA的相互作用,其中镍配合物与DNA的作用明显.","abstractInfoCn":"报道-类新的Schiff碱和咪唑的混合型金属配合物,即水杨醛缩甘氨酸、咪唑金属配合物和2,4-二羟基苯甲醛缩丙氨酸、咪唑金属配合物的合成.用溴化乙锭荧光分析法研究了这类配合物与DNA的相互作用,其中镍配合物与DNA的作用明显.","abstractInfoEn":"A series of Schiff base coordination compounds containing Cu,Ni,Zn,and Co has been synthesized from salicylaldehyde,2,4-dihydroxy benzaldehyde, glycine and <i>L<\/i>-ala-nine. The order of the antitumor activity of the conlpounds is Ni>Cu>Zn>Co,by ethidium fluorescence spectroscopy.","articleNo":"19950204","authorCnList":["杨高文","  夏小平","  涂欢","  赵成学"],"authorEnList":["Yang Gaowen","  Xia Xiaoping","  Tu Huan","  Zhao Chenxue"],"authorList":["杨高文","  夏小平","  涂欢","  赵成学"],"authors":"杨高文,  夏小平,  涂欢,  赵成学","authorsCn":"杨高文,  夏小平,  涂欢,  赵成学","authorsEn":"Yang Gaowen,  Xia Xiaoping,  Tu Huan,  Zhao Chenxue","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"杨高文,  夏小平,  涂欢,  赵成学. Schiff碱、咪唑金属配合物的合成与抗癌活性. 应用化学, 1995, 12(2): 13-15.","citationCn":"杨高文,  夏小平,  涂欢,  赵成学. Schiff碱、咪唑金属配合物的合成与抗癌活性. 应用化学, 1995, 12(2): 13-15.","citationEn":"杨高文,  夏小平,  涂欢,  赵成学. Synthesis and Antitumor Activity of Schiff Base Coordination Compounds. Chinese Journal of Applied Chemistry, 1995, 12(2): 13-15.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"13","highCitedState":"","htmlCount":47,"htmlFile":"","id":"78a5e783-14e1-462a-bbc0-dfc5da9921af","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"Schiff碱, 咪唑, 金属配合物, 抗癌活性","keywordCn":"Schiff碱, 咪唑, 金属配合物, 抗癌活性","keywordCnList":["Schiff碱"," 咪唑"," 金属配合物"," 抗癌活性"],"keywordEn":"Schiff base, imidazole, metal coordination compound, antitumor activity","keywordEnList":["Schiff base"," imidazole"," metal coordination compound"," antitumor activity"],"keywordList":["Schiff碱"," 咪唑"," 金属配合物"," 抗癌活性"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"15","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":232.41,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"Schiff碱、咪唑金属配合物的合成与抗癌活性","titleCn":"Schiff碱、咪唑金属配合物的合成与抗癌活性","titleEn":"Synthesis and Antitumor Activity of Schiff Base Coordination Compounds","viewCount":463,"volume":"12","year":1995},{"abstractInfo":"用<sup>1<\/sup>HNMR法研究了钯(Ⅱ)混配物分子内芳环配体间的堆积作用,结果表明堆积度和参与堆积的芳环大小-致。","abstractInfoCn":"用<sup>1<\/sup>H NMR法研究了钯(Ⅱ)混配物分子内芳环配体间的堆积作用,结果表明堆积度和参与堆积的芳环大小-致。","abstractInfoEn":"The stacking interaction of aromatic rings in the mixed ligand complexes Pd(A) (ATP)<sup><i>n<\/i>-<\/sup> (A=1,10-phenanthroline,2,2'-bipyridyl,and typtophane,<i>n<\/i>=2,3) has been studied by <sup>1<\/sup>H NMR. The results showed that the stacking degree was in accordance with the size of the aromatic rings.","articleNo":"19950205","authorCnList":["孙洪良","  龚钰秋"],"authorEnList":["Sun Hongliang","  Gong Yuqiu"],"authorList":["孙洪良","  龚钰秋"],"authors":"孙洪良,  龚钰秋","authorsCn":"孙洪良,  龚钰秋","authorsEn":"Sun Hongliang,  Gong Yuqiu","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"孙洪良,  龚钰秋. 钯(Ⅱ)混配物分子内的芳环堆积作用. 应用化学, 1995, 12(2): 16-19.","citationCn":"孙洪良,  龚钰秋. 钯(Ⅱ)混配物分子内的芳环堆积作用. 应用化学, 1995, 12(2): 16-19.","citationEn":"孙洪良,  龚钰秋. Stacking Interaction of Aromatic Rings in Pd(Ⅱ) Mixed-Ligand Complexes. Chinese Journal of Applied Chemistry, 1995, 12(2): 16-19.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"16","highCitedState":"","htmlCount":99,"htmlFile":"","id":"6ab1edd0-4837-46f5-b6e1-d7aa3be4525c","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"钯, 混配物, 邻菲咯啉, 联吡啶, 色氨酸, 三磷酸腺苷, 堆积作用","keywordCn":"钯, 混配物, 邻菲咯啉, 联吡啶, 色氨酸, 三磷酸腺苷, 堆积作用","keywordCnList":["钯"," 混配物"," 邻菲咯啉"," 联吡啶"," 色氨酸"," 三磷酸腺苷"," 堆积作用"],"keywordEn":"palladium, mixed complex, phenanthroline, bipyridyl, typtophane, ATP, stacking interaction","keywordEnList":["palladium"," mixed complex"," phenanthroline"," bipyridyl"," typtophane"," ATP"," stacking interaction"],"keywordList":["钯"," 混配物"," 邻菲咯啉"," 联吡啶"," 色氨酸"," 三磷酸腺苷"," 堆积作用"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"19","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":270.86,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"钯(Ⅱ)混配物分子内的芳环堆积作用","titleCn":"钯(Ⅱ)混配物分子内的芳环堆积作用","titleEn":"Stacking Interaction of Aromatic Rings in Pd(Ⅱ) Mixed-Ligand Complexes","viewCount":756,"volume":"12","year":1995},{"abstractInfo":"制得了二丁胺甲基膦酸-亚酸氢锆Zr(HPO<sub>3<\/sub>)<sub>2-<i>x<\/i><\/sub>&#183;(O<sub>3<\/sub>PCH<sub>2<\/sub>NBu<sub>2<\/sub>)<sub><i>x<\/i><\/sub>&#183;H<sub>2<\/sub>O(<i>x<\/i>=0.8,0.6,0.5,0.4,0.35),用溴化苄季铵化,得部分季铵化产物:溴化节基二丁铵甲基膦酸-二丁胺甲基膦酸-亚磷酸氢锆Zr(HPO<sub>3<\/sub>)<sub>2-<i>x<\/i><\/sub>&#183;(O<sub>3<\/sub>PCH<sub>2<\/sub>NBu<sub>2<\/sub>)<sub><i>x-y<\/i><\/sub>&#183;(O<sub>3<\/sub>PCH<sub>2<\/sub>N<sup>+<\/sup>Bu<sub>2<\/sub>&#183;CH<sub>2<\/sub>Ph&#183;Br<sup>-<\/sup>)<sub><i>y<\/i><\/sub>&#183;H<sub>2<\/sub>O(<i>y<\/i><<i>x<\/i>),用作相转移催化剂,对液/固/液或固/固/液相转移催化的取代、成醚、合成酯及二氯卡宾加成反应均具良好的催化活性。催化剂易回收,回收率为70%~100%,重复使用10次以上无明显失活。","abstractInfoCn":"制得了二丁胺甲基膦酸-亚酸氢锆Zr(HPO<sub>3<\/sub>)<sub>2-<i>x<\/i><\/sub>&#183;(O<sub>3<\/sub>PCH<sub>2<\/sub>NBu<sub>2<\/sub>)<sub><i>x<\/i><\/sub>&#183;H<sub>2<\/sub>O(<i>x<\/i>=0.8,0.6,0.5,0.4,0.35),用溴化苄季铵化,得部分季铵化产物:溴化节基二丁铵甲基膦酸-二丁胺甲基膦酸-亚磷酸氢锆Zr(HPO<sub>3<\/sub>)<sub>2-<i>x<\/i><\/sub>&#183;(O<sub>3<\/sub>PCH<sub>2<\/sub>NBu<sub>2<\/sub>)<sub><i>x-y<\/i><\/sub>&#183;(O<sub>3<\/sub>PCH<sub>2<\/sub>N<sup>+<\/sup>Bu<sub>2<\/sub>&#183;CH<sub>2<\/sub>Ph&#183;Br<sup>-<\/sup>)<sub><i>y<\/i><\/sub>&#183;H<sub>2<\/sub>O(<i>y<\/i> < <i>x<\/i>),用作相转移催化剂,对液/固/液或固/固/液相转移催化的取代、成醚、合成酯及二氯卡宾加成反应均具良好的催化活性。催化剂易回收,回收率为70%~100%,重复使用10次以上无明显失活。","abstractInfoEn":"Zirconium dibutylaminomethylphosphonate-phosphites Zr(HPO<sub>3<\/sub>)<sub>2-<i>x<\/i><\/sub>&#183;(O<sub>3<\/sub>PCH<sub>2<\/sub>N-Bu<sub>2<\/sub>)<sub><i>x<\/i><\/sub>&#183;H<sub>2<\/sub>O (ZPDBN-ZP,<i>x<\/i>=0.8,0.6,0.5,0.4,0.35) have been prepared for the first time. Partly quaternized ZPDBN-ZP with benzylbromide, zirconium (benzyldibutylammo-niomethylphosphonate bromide-dibutylammoniomethylphosphonate-phosphite) Zr(HPO<sub>3<\/sub>)<sub>2-<i>x<\/i><\/sub>&#183;(O<sub>3<\/sub>PCH<sub>2<\/sub>NBu<sub>2<\/sub>)<sub><i>x-y<\/i><\/sub>&#183;(O<sub>3<\/sub>PCH<sub>2<\/sub>N<sup>+<\/sup>Bu<sub>2<\/sub>PhCH<sub>2<\/sub>Br<sup>-<\/sup>)<i>y<\/i>&#183;H<sub>2<\/sub>O (ZPBBDB-ZPDBN-ZP, <i>y<\/i>< <i>x<\/i>) have been obtained. Heterogeneous PTC reactions of nucleophilic substitution, etherifica-tion,esterification, and addition of dichlorocarbene by using ZPBBDB-ZPDBN-ZP have been carried out successfully. The catalysts can easily be recovered with recovery of 70%~100%. No obvious loss of the catalytic activity was found after more than ten times repeated use.","articleNo":"19950206","authorCnList":["傅相锴","  温淑英","  亢为"],"authorEnList":["Fu Xiangkai","  Wen Shuying","  Kang Wei"],"authorList":["傅相锴","  温淑英","  亢为"],"authors":"傅相锴,  温淑英,  亢为","authorsCn":"傅相锴,  温淑英,  亢为","authorsEn":"Fu Xiangkai,  Wen Shuying,  Kang Wei","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"傅相锴,  温淑英,  亢为. 二丁胺甲基膦酸锆的苄基季胺化合物及其相转移催化作用. 应用化学, 1995, 12(2): 20-23.","citationCn":"傅相锴,  温淑英,  亢为. 二丁胺甲基膦酸锆的苄基季胺化合物及其相转移催化作用. 应用化学, 1995, 12(2): 20-23.","citationEn":"傅相锴,  温淑英,  亢为. Quaternary Compounds of Zirconium Dibutylamino-methylphosphonate and Thier PTC Activities. Chinese Journal of Applied Chemistry, 1995, 12(2): 20-23.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"20","highCitedState":"","htmlCount":37,"htmlFile":"","id":"da4252dd-4aca-4eda-9808-6faa0d7e07d1","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"二丁胺甲基膦酸锆, 亚磷酸氢锆, 相转移催化反应, 季铵化, 亲核取代反应, 醚化反应, 酯化反应, 卡宾加成反应","keywordCn":"二丁胺甲基膦酸锆, 亚磷酸氢锆, 相转移催化反应, 季铵化, 亲核取代反应, 醚化反应, 酯化反应, 卡宾加成反应","keywordCnList":["二丁胺甲基膦酸锆"," 亚磷酸氢锆"," 相转移催化反应"," 季铵化"," 亲核取代反应"," 醚化反应"," 酯化反应"," 卡宾加成反应"],"keywordEn":"zirconium dibutylaminomethylphosphonate, zirconium phosphite, PTC reaction, quaternization, nucleophilic substitution, etherification, esterification, carbene addition","keywordEnList":["zirconium dibutylaminomethylphosphonate"," zirconium phosphite"," PTC reaction"," quaternization"," nucleophilic substitution"," etherification"," esterification"," carbene addition"],"keywordList":["二丁胺甲基膦酸锆"," 亚磷酸氢锆"," 相转移催化反应"," 季铵化"," 亲核取代反应"," 醚化反应"," 酯化反应"," 卡宾加成反应"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"23","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":311.33,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"二丁胺甲基膦酸锆的苄基季胺化合物及其相转移催化作用","titleCn":"二丁胺甲基膦酸锆的苄基季胺化合物及其相转移催化作用","titleEn":"Quaternary Compounds of Zirconium Dibutylamino-methylphosphonate and Thier PTC Activities","viewCount":437,"volume":"12","year":1995},{"abstractInfo":"研究了沸石作为常温非水锂电池阴极材料的放电性能和循环特性。通过库仑滴定,三角波电位扫描,<i>X<\/i>-射线分析和红外光谱研究了锂/沸石电池的阴极反应机理,发现在<i>x<\/i><3、4mol时,阴极上发生的是锂的嵌入反应。测得锂嵌入NaA型沸石生成LiNaA的嵌入自由能为-231kJ/mol(25℃)。用电化学方法测得,常温下锂在Li<sub><i>x<\/i><\/sub>NaA(<i>x<\/i>=0.17~0.69)中的化学扩散系数为1&#215;10<sup>-9<\/sup>~1&#215;10<sup>-10<\/sup>cm<sup>2<\/sup>/s数量级。","abstractInfoCn":"研究了沸石作为常温非水锂电池阴极材料的放电性能和循环特性。通过库仑滴定,三角波电位扫描,<i>X<\/i>-射线分析和红外光谱研究了锂/沸石电池的阴极反应机理,发现在<i>x<\/i><3、4mol时,阴极上发生的是锂的嵌入反应。测得锂嵌入NaA型沸石生成LiNaA的嵌入自由能为-231kJ/mol(25℃)。用电化学方法测得,常温下锂在Li<sub><i>x<\/i><\/sub>NaA(<i>x<\/i>=0.17~0.69)中的化学扩散系数为1&#215;10<sup>-9<\/sup>~1&#215;10<sup>-10<\/sup>cm<sup>2<\/sup>/s数量级。","abstractInfoEn":"The discharge and cyclic voltammetry behavior of a variety of zeolites as cathode of lithium secondary cell have been studied by coulometric titration,infrared absorption spectrosoepy and <i>X<\/i>-ray diffractometry. It was found that in the course of discharge lithium is electrochemically intercalated into compound at discharge depth <i>x<\/i> < 3.4mol. The intercala-tion free energy of Li into NaA zeolite was found to be -231kJ/mol (25℃). The chemical diffusion coefficient of lithium in Li<i>x<\/i>NaA (<i>x<\/i>=0.17~0.69) was determined to be about 1&#215;10<sup>-9<\/sup>~1&#215;10<sup>-10<\/sup>cm<sup>2<\/sup>/s at room temperature.","articleNo":"19950207","authorCnList":["房艳"],"authorEnList":["Fang Yan"],"authorList":["房艳"],"authors":"房艳","authorsCn":"房艳","authorsEn":"Fang Yan","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"房艳. 锂/沸石电池的电化学行为. 应用化学, 1995, 12(2): 24-28.","citationCn":"房艳. 锂/沸石电池的电化学行为. 应用化学, 1995, 12(2): 24-28.","citationEn":"房艳. Electrochemical Behavior of Li/Zeolotes Cells. Chinese Journal of Applied Chemistry, 1995, 12(2): 24-28.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"24","highCitedState":"","htmlCount":36,"htmlFile":"","id":"7cfec574-7799-484c-a565-923a323ded3d","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"锂/沸石电池, 插入, 电化学行为","keywordCn":"锂/沸石电池, 插入, 电化学行为","keywordCnList":["锂/沸石电池"," 插入"," 电化学行为"],"keywordEn":"lithium-zeolite cell, intercalation, electrochemical behavior","keywordEnList":["lithium-zeolite cell"," intercalation"," electrochemical behavior"],"keywordList":["锂/沸石电池"," 插入"," 电化学行为"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"28","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":356.78,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"锂/沸石电池的电化学行为","titleCn":"锂/沸石电池的电化学行为","titleEn":"Electrochemical Behavior of Li/Zeolotes Cells","viewCount":436,"volume":"12","year":1995},{"abstractInfo":"合成了10种甲基二环己基锡-<i>O<\/i>,<i>O<\/i>-二烃基二硫代酸酸酯。利用IR、NMR,MS及元素分析确证了化合物的结构.生物活性测试结果表明,这类化合物具有较高的杀螨和除草活性。","abstractInfoCn":"合成了10种甲基二环己基锡-<i>O<\/i>,<i>O<\/i>-二烃基二硫代酸酸酯。利用IR、NMR,MS及元素分析确证了化合物的结构.生物活性测试结果表明,这类化合物具有较高的杀螨和除草活性。","abstractInfoEn":"Ten dicyclohexylmethyltin-<i>O<\/i>,<i>O<\/i>-dialkyl(aryl)dithiophosphates have been prepared and characterized by IR,NMR (<sup>1<\/sup>H, <sup>13<\/sup>C),MS and elemental analysis. The bioassay tests showed the high acaricidal activities and herbicidal activities of the compounds.","articleNo":"19950208","authorCnList":["杨志强","  谢庆兰","  周秀中"],"authorEnList":["Yang Zhiqiang","  Xie Qinglan","  Zhou Xiouzhong"],"authorList":["杨志强","  谢庆兰","  周秀中"],"authors":"杨志强,  谢庆兰,  周秀中","authorsCn":"杨志强,  谢庆兰,  周秀中","authorsEn":"Yang Zhiqiang,  Xie Qinglan,  Zhou Xiouzhong","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"杨志强,  谢庆兰,  周秀中. 混合三烃基锡衍生物的研究Ⅹ.甲基二环己基锡二硫代磷酸酯的合成及生物活性. 应用化学, 1995, 12(2): 29-32.","citationCn":"杨志强,  谢庆兰,  周秀中. 混合三烃基锡衍生物的研究Ⅹ.甲基二环己基锡二硫代磷酸酯的合成及生物活性. 应用化学, 1995, 12(2): 29-32.","citationEn":"杨志强,  谢庆兰,  周秀中. Studies on Mixed Trialkyltin Derivatives Ⅹ. Preparation and Biological Activities of Dicyclohexyl-Methyltin Dithiophosphates. Chinese Journal of Applied Chemistry, 1995, 12(2): 29-32.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"29","highCitedState":"","htmlCount":37,"htmlFile":"","id":"841ed976-e399-44bf-9e2b-de5a002e44e0","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"甲基二环己基锡, 二硫代灰酸酯, 合成, 杀螨活性, 除草活性","keywordCn":"甲基二环己基锡, 二硫代灰酸酯, 合成, 杀螨活性, 除草活性","keywordCnList":["甲基二环己基锡"," 二硫代灰酸酯"," 合成"," 杀螨活性"," 除草活性"],"keywordEn":"dicyclohexylmethyltin dithiophosphate, synthesis, acaricidal activity, herbicidal activity","keywordEnList":["dicyclohexylmethyltin dithiophosphate"," synthesis"," acaricidal activity"," herbicidal activity"],"keywordList":["甲基二环己基锡"," 二硫代灰酸酯"," 合成"," 杀螨活性"," 除草活性"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"32","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":273.94,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"混合三烃基锡衍生物的研究Ⅹ.甲基二环己基锡二硫代磷酸酯的合成及生物活性","titleCn":"混合三烃基锡衍生物的研究Ⅹ.甲基二环己基锡二硫代磷酸酯的合成及生物活性","titleEn":"Studies on Mixed Trialkyltin Derivatives Ⅹ. Preparation and Biological Activities of Dicyclohexyl-Methyltin Dithiophosphates","viewCount":416,"volume":"12","year":1995},{"abstractInfo":"在Nafion膜表层引入全氟表面活性剂可改善膜表面的亲水性,其中全氟磺酸型表面活性剂FC-99效果最好。经后者处理的Nafion膜几乎不溶胀,而能使水溶液在膜上的接触角显著减小,并改善\"气泡效应(零间距效应)\"。","abstractInfoCn":"在Nafion膜表层引入全氟表面活性剂可改善膜表面的亲水性,其中全氟磺酸型表面活性剂FC-99效果最好。经后者处理的Nafion膜几乎不溶胀,而能使水溶液在膜上的接触角显著减小,并改善\"气泡效应(零间距效应)\"。","abstractInfoEn":"The surface of Nafion membrane can be rendered more hydrophilic by modification with perfluorinated surfactants. A surfactant of sulfonic acid type (FC-99) was found to be most suitable for membrane modification. The swelling of the membrane is not serious after treatment, while the advancing contact angle between water and the membrane can be signi-ficantly reduced. Bubble effect (\"zero-gap\" effect) was diminished markedly in experimental membrane electrolysis cell using modified Nafion membrane.","articleNo":"19950209","authorCnList":["祖延兵","  查全性"],"authorEnList":["Zu Yanbing","  Cha Chuansin"],"authorList":["祖延兵","  查全性"],"authors":"祖延兵,  查全性","authorsCn":"祖延兵,  查全性","authorsEn":"Zu Yanbing,  Cha Chuansin","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"祖延兵,  查全性. 用全氟表面活性剂改善Nafion膜表面的亲水性. 应用化学, 1995, 12(2): 33-36.","citationCn":"祖延兵,  查全性. 用全氟表面活性剂改善Nafion膜表面的亲水性. 应用化学, 1995, 12(2): 33-36.","citationEn":"祖延兵,  查全性. Improvement of Hydtophilicity of Nafion Membrane Surface by Modification with Perfluorinated Sutfactants. Chinese Journal of Applied Chemistry, 1995, 12(2): 33-36.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"33","highCitedState":"","htmlCount":181,"htmlFile":"","id":"1f9982e6-b096-4f36-bb49-2fbd9e4a62e1","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"Nafion膜, 全氟表面活性剂, 接触角, 气泡效应","keywordCn":"Nafion膜, 全氟表面活性剂, 接触角, 气泡效应","keywordCnList":["Nafion膜"," 全氟表面活性剂"," 接触角"," 气泡效应"],"keywordEn":"Nafion membrane, perfluorinated surfactant, contact angle, bubble effect","keywordEnList":["Nafion membrane"," perfluorinated surfactant"," contact angle"," bubble effect"],"keywordList":["Nafion膜"," 全氟表面活性剂"," 接触角"," 气泡效应"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"36","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":5,"pdfSize":288.23,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"用全氟表面活性剂改善Nafion膜表面的亲水性","titleCn":"用全氟表面活性剂改善Nafion膜表面的亲水性","titleEn":"Improvement of Hydtophilicity of Nafion Membrane Surface by Modification with Perfluorinated Sutfactants","viewCount":743,"volume":"12","year":1995},{"abstractInfo":"乙二胺与二茂铁甲醛或双二茂铁甲基氟硼酸盐反应,合成了1,6-二(二茂铁基)-2,5-二氮杂已烷和1,1,6,6-四(二茂铁基)-2,5-二氮杂已烷。它们与过渡金属(Fe<sup>2+<\/sup>、Co<sup>2+<\/sup>、Ni<sup>2+<\/sup>、Cu<sup>2+<\/sup>、Zn<sup>2+<\/sup>)盐在乙醇或乙醇-二氯甲烷中反应,制得14种过渡金属配合物。对这些化合物进行了表征。二种配体及其铜配合物用作复合固体推进剂的燃速调节剂时,基本不迁移,而燃速催化效率均超过辛基二茂铁。","abstractInfoCn":"乙二胺与二茂铁甲醛或双二茂铁甲基氟硼酸盐反应,合成了1,6-二(二茂铁基)-2,5-二氮杂已烷和1,1,6,6-四(二茂铁基)-2,5-二氮杂已烷。它们与过渡金属(Fe<sup>2+<\/sup>、Co<sup>2+<\/sup>、Ni<sup>2+<\/sup>、Cu<sup>2+<\/sup>、Zn<sup>2+<\/sup>)盐在乙醇或乙醇-二氯甲烷中反应,制得14种过渡金属配合物。对这些化合物进行了表征。二种配体及其铜配合物用作复合固体推进剂的燃速调节剂时,基本不迁移,而燃速催化效率均超过辛基二茂铁。","abstractInfoEn":"Two ligands 1,6-diferrocenyl-2,5-diazahexane and 1,1,6,6-tetraferrocenyl-2,5-diazahexane,were synthesized by reacting ethylene diamine with ferrocenyl formaldehyde and biferrocenylmethyl flouroborate respectively. Fourteen complexes of the ligands with Fe<sup>2+<\/sup>,Co<sup>2+<\/sup>,Ni<sup>2+<\/sup>,Cu<sup>2+<\/sup> and Zn<sup>2+<\/sup> were prepared. All the compounds have been characterized by elemental analysis, DTA and IR,<sup>1<\/sup>H NMR measurements. The ligands and their cuprous complex have been used as burning-rate modifiers for composite solid propellants. No migra-tion was found in composite propellants. The catalytic efficiency of burning-rate was over that of octylferrocene.","articleNo":"19950210","authorCnList":["边占喜","  王健春","  李逢泽"],"authorEnList":["Bian Zhanxi","  Wang Jianchun","  Li Fengze"],"authorList":["边占喜","  王健春","  李逢泽"],"authors":"边占喜,  王健春,  李逢泽","authorsCn":"边占喜,  王健春,  李逢泽","authorsEn":"Bian Zhanxi,  Wang Jianchun,  Li Fengze","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"边占喜,  王健春,  李逢泽. 多二茂铁基二氮杂己烷及其过渡金属配合物的合成. 应用化学, 1995, 12(2): 37-41.","citationCn":"边占喜,  王健春,  李逢泽. 多二茂铁基二氮杂己烷及其过渡金属配合物的合成. 应用化学, 1995, 12(2): 37-41.","citationEn":"边占喜,  王健春,  李逢泽. Synthesis of Multiferrocenyl Diazahexanes and Transition Metal Complexes. Chinese Journal of Applied Chemistry, 1995, 12(2): 37-41.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"37","highCitedState":"","htmlCount":98,"htmlFile":"","id":"a2d2afd4-c581-4e66-a1c7-8df95c67fcc8","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"二(二茂铁基)-二氮杂己烷, 四(二茂铁基)-二氮杂己烷, 过渡金属配合物, 燃速调节剂","keywordCn":"二(二茂铁基)-二氮杂己烷, 四(二茂铁基)-二氮杂己烷, 过渡金属配合物, 燃速调节剂","keywordCnList":["二(二茂铁基)-二氮杂己烷"," 四(二茂铁基)-二氮杂己烷"," 过渡金属配合物"," 燃速调节剂"],"keywordEn":"diferrocenyl diazahexane, tetraferrocenyl diazahexane, transition metal complex, burning-rate modifier","keywordEnList":["diferrocenyl diazahexane"," tetraferrocenyl diazahexane"," transition metal complex"," burning-rate modifier"],"keywordList":["二(二茂铁基)-二氮杂己烷"," 四(二茂铁基)-二氮杂己烷"," 过渡金属配合物"," 燃速调节剂"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"41","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":348.75,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"多二茂铁基二氮杂己烷及其过渡金属配合物的合成","titleCn":"多二茂铁基二氮杂己烷及其过渡金属配合物的合成","titleEn":"Synthesis of Multiferrocenyl Diazahexanes and Transition Metal Complexes","viewCount":623,"volume":"12","year":1995},{"abstractInfo":"在乙醇-水溶液中合成了14种2,6-双(1'-苯基-3'-甲基-5'-氧代-4'-甲酰吡唑)吡啶稀土配合物。元素分析确定其化学组成为RE<sub>2<\/sub>L<sub>3<\/sub>&#183;<i>n<\/i>H<sub>2<\/sub>O,并用紫外可见光谱、红外光谱、核磁共振谱、热分析、荧光光谱、摩尔电导等进行了表征。","abstractInfoCn":"在乙醇-水溶液中合成了14种2,6-双(1'-苯基-3'-甲基-5'-氧代-4'-甲酰吡唑)吡啶稀土配合物。元素分析确定其化学组成为RE<sub>2<\/sub>L<sub>3<\/sub>&#183;<i>n<\/i>H<sub>2<\/sub>O,并用紫外可见光谱、红外光谱、核磁共振谱、热分析、荧光光谱、摩尔电导等进行了表征。","abstractInfoEn":"A novel ligand 2,6-bis (1'-phenyl-3'-methyl-5'-oxo-4'-formylpyrazol) pyridine (H<sub>2<\/sub>L) and its complexes have been prepared by reacting H<sub>2<\/sub>L with rare earth nitrate in ethyl alcohol solution. The complexes have been characterized by elemental analysis, thermoanal-ysis,molar conductivity,IR,UV,<sup>1<\/sup>H NMR and fluorescence spectra measurements.","articleNo":"19950211","authorCnList":["刘易人","  杨汝栋","  刘建民"],"authorEnList":["Liu Yiren","  Yang Rudong","  Liu Jianmin"],"authorList":["刘易人","  杨汝栋","  刘建民"],"authors":"刘易人,  杨汝栋,  刘建民","authorsCn":"刘易人,  杨汝栋,  刘建民","authorsEn":"Liu Yiren,  Yang Rudong,  Liu Jianmin","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"刘易人,  杨汝栋,  刘建民. 2,6-双(1'-苯基-3'-甲基-5'-氧代-4'-甲酰吡唑)吡啶稀土配合物的合成与表征. 应用化学, 1995, 12(2): 42-46.","citationCn":"刘易人,  杨汝栋,  刘建民. 2,6-双(1'-苯基-3'-甲基-5'-氧代-4'-甲酰吡唑)吡啶稀土配合物的合成与表征. 应用化学, 1995, 12(2): 42-46.","citationEn":"刘易人,  杨汝栋,  刘建民. Synthesis and Characterization of 2,6-Bis-(1'-Phenyl-3'-Methyl-5'-Oxo-4'-Formylpyrazol) Pyridine and Its Rare Earth Complexes. Chinese Journal of Applied Chemistry, 1995, 12(2): 42-46.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"42","highCitedState":"","htmlCount":59,"htmlFile":"","id":"c1ca5c97-5d5d-4a7d-9771-591c9b8594bd","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"稀土, 配合物, 双(苯基甲基氧代甲酰吡唑)吡啶, 合成","keywordCn":"稀土, 配合物, 双(苯基甲基氧代甲酰吡唑)吡啶, 合成","keywordCnList":["稀土"," 配合物"," 双(苯基甲基氧代甲酰吡唑)吡啶"," 合成"],"keywordEn":"rare earth, complex, bis(phenyl-methyl-oxo-formylpyrazol)diformyl pyridine, synthesis","keywordEnList":["rare earth"," complex"," bis(phenyl-methyl-oxo-formylpyrazol)diformyl pyridine"," synthesis"],"keywordList":["稀土"," 配合物"," 双(苯基甲基氧代甲酰吡唑)吡啶"," 合成"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"46","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":352.71,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"2,6-双(1'-苯基-3'-甲基-5'-氧代-4'-甲酰吡唑)吡啶稀土配合物的合成与表征","titleCn":"2,6-双(1'-苯基-3'-甲基-5'-氧代-4'-甲酰吡唑)吡啶稀土配合物的合成与表征","titleEn":"Synthesis and Characterization of 2,6-Bis-(1'-Phenyl-3'-Methyl-5'-Oxo-4'-Formylpyrazol) Pyridine and Its Rare Earth Complexes","viewCount":457,"volume":"12","year":1995},{"abstractInfo":"合成了<i>β<\/i>-芳氧基丙酸芳酯及<i>β<\/i>-芳氧基丙酰芳胺等17种化合物,经IR、UV、<sup>1<\/sup>HNMR和元素分析确定了它们的结构,并对它们的生物活性进行了初步考察。","abstractInfoCn":"合成了<i>β<\/i>-芳氧基丙酸芳酯及<i>β<\/i>-芳氧基丙酰芳胺等17种化合物,经IR、UV、<sup>1<\/sup>H NMR和元素分析确定了它们的结构,并对它们的生物活性进行了初步考察。","abstractInfoEn":"Nine aryl <i>β<\/i>-aryloxypropionates and eight ary <i>β<\/i>-aryloxypropionamides have been synthesized and confirmed by elemental analysis,UV,IR, and <sup>1<\/sup>H NMR spectrometry mea-surements. The promoting effects of these compounds on the wheat growth were tested pre-liminary.","articleNo":"19950212","authorCnList":["李英俊","  付兴吉","  许永廷","  金郁","  杨开海"],"authorEnList":["Li Yingjun","  Fu Xingji","  Xu Yongting","  Jin Yu","  Yang Kaihai"],"authorList":["李英俊","  付兴吉","  许永廷","  金郁","  杨开海"],"authors":"李英俊,  付兴吉,  许永廷,  金郁,  杨开海","authorsCn":"李英俊,  付兴吉,  许永廷,  金郁,  杨开海","authorsEn":"Li Yingjun,  Fu Xingji,  Xu Yongting,  Jin Yu,  Yang Kaihai","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"李英俊,  付兴吉,  许永廷,  金郁,  杨开海. <i>β<\/i>-芳氧基丙酸衍生物的合成及生物活性. 应用化学, 1995, 12(2): 47-50.","citationCn":"李英俊,  付兴吉,  许永廷,  金郁,  杨开海. <i>β<\/i>-芳氧基丙酸衍生物的合成及生物活性. 应用化学, 1995, 12(2): 47-50.","citationEn":"李英俊,  付兴吉,  许永廷,  金郁,  杨开海. Synthesis and Biological Activity of <i>β<\/i>-Aryloxypropionic Acid Derivatives. Chinese Journal of Applied Chemistry, 1995, 12(2): 47-50.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"47","highCitedState":"","htmlCount":67,"htmlFile":"","id":"e0190d64-2acf-49ba-be51-d39d5aadd9e5","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"芳氧基丙酸芳酯, 芳氧基丙酰芳胺, 合成, 生物活性","keywordCn":"芳氧基丙酸芳酯, 芳氧基丙酰芳胺, 合成, 生物活性","keywordCnList":["芳氧基丙酸芳酯"," 芳氧基丙酰芳胺"," 合成"," 生物活性"],"keywordEn":"aryl <i>β<\/i>-aryloxypropionate, aryl <i>β<\/i>-aryloxypropionamide, synthesis, biological activ-ity","keywordEnList":["aryl <i>β<\/i>-aryloxypropionate"," aryl <i>β<\/i>-aryloxypropionamide"," synthesis"," biological activ-ity"],"keywordList":["芳氧基丙酸芳酯"," 芳氧基丙酰芳胺"," 合成"," 生物活性"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"50","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":260.92,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"<i>β<\/i>-芳氧基丙酸衍生物的合成及生物活性","titleCn":"<i>β<\/i>-芳氧基丙酸衍生物的合成及生物活性","titleEn":"Synthesis and Biological Activity of <i>β<\/i>-Aryloxypropionic Acid Derivatives","viewCount":606,"volume":"12","year":1995},{"abstractInfo":"探索了微粉化过程对各种纤维素材料超分子结构的影响。结果表明,稀盐酸水解制得的微粉(和微晶)纤维素,在结晶状态(如聚合度、结晶度、晶粒尺寸等)及晶粒聚集体的形态结构上,均随纤维素晶型的不同而变,并与硫酸水解和机械微粉化不同。<i>X<\/i>-射线衍射分析显示:微粉化产物仍保持其纤维素材料原来的晶型和两相(晶区与非晶区)共存的微细结构。","abstractInfoCn":"探索了微粉化过程对各种纤维素材料超分子结构的影响。结果表明,稀盐酸水解制得的微粉(和微晶)纤维素,在结晶状态(如聚合度、结晶度、晶粒尺寸等)及晶粒聚集体的形态结构上,均随纤维素晶型的不同而变,并与硫酸水解和机械微粉化不同。<i>X<\/i>-射线衍射分析显示:微粉化产物仍保持其纤维素材料原来的晶型和两相(晶区与非晶区)共存的微细结构。","abstractInfoEn":"The production of micronized cellulose by acid hydrolysis induced the changes in main structural characteristics,such as degree of polymerization,crystallinity,size of crys-tallites and morphological structure,which depend greatly on the original crystalline types and means of the treatment. The results from <i>X<\/i>-ray diffraction showed that the biphase sys-tem still remains in the micronized celluloses,so their original crystalline type.","articleNo":"19950213","authorCnList":["朱玉琴","  汤烈贵","  潘松汉","  王真智"],"authorEnList":["Zhu Yuqin","  Tang Liegui","  Pan Songhan","  Wang Zhenzhi"],"authorList":["朱玉琴","  汤烈贵","  潘松汉","  王真智"],"authors":"朱玉琴,  汤烈贵,  潘松汉,  王真智","authorsCn":"朱玉琴,  汤烈贵,  潘松汉,  王真智","authorsEn":"Zhu Yuqin,  Tang Liegui,  Pan Songhan,  Wang Zhenzhi","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"朱玉琴,  汤烈贵,  潘松汉,  王真智. 微粉(和微晶)纤维素的微细结构. 应用化学, 1995, 12(2): 51-54.","citationCn":"朱玉琴,  汤烈贵,  潘松汉,  王真智. 微粉(和微晶)纤维素的微细结构. 应用化学, 1995, 12(2): 51-54.","citationEn":"朱玉琴,  汤烈贵,  潘松汉,  王真智. Microstructure of Micronizcd (and Microcrystalline) Cellulose. Chinese Journal of Applied Chemistry, 1995, 12(2): 51-54.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"51","highCitedState":"","htmlCount":87,"htmlFile":"","id":"d134db7f-0fc8-4e65-b6d4-a1601c0cd287","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"微粉纤维素, 微晶纤维素, 聚合度, 结晶度, 晶型, 结构形态","keywordCn":"微粉纤维素, 微晶纤维素, 聚合度, 结晶度, 晶型, 结构形态","keywordCnList":["微粉纤维素"," 微晶纤维素"," 聚合度"," 结晶度"," 晶型"," 结构形态"],"keywordEn":"micronized cellulose, microcrystalline cellulose, polymerization degree, crystallini-ty, crystalline type, structural morphology","keywordEnList":["micronized cellulose"," microcrystalline cellulose"," polymerization degree"," crystallini-ty"," crystalline type"," structural morphology"],"keywordList":["微粉纤维素"," 微晶纤维素"," 聚合度"," 结晶度"," 晶型"," 结构形态"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"54","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":257.22,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"微粉(和微晶)纤维素的微细结构","titleCn":"微粉(和微晶)纤维素的微细结构","titleEn":"Microstructure of Micronizcd (and Microcrystalline) Cellulose","viewCount":700,"volume":"12","year":1995},{"abstractInfo":"制取了4-二氰基亚甲基-2-甲基-6-对二甲胺基苯乙烯基-4H-吡喃(DCM)和1,2-双(5-甲基苯并噁唑)基乙烯(DT)两种荧光分子的LB膜以及两者的混合膜。以吸收光谱和荧光光谱探讨了膜中分子的构型、微环境、发光性能等特征。发现在LB膜的缀密排布环境中DCM顺式构型的含量较之在溶液中大为增加。","abstractInfoCn":"制取了4-二氰基亚甲基-2-甲基-6-对二甲胺基苯乙烯基-4H-吡喃(DCM)和1,2-双(5-甲基苯并噁唑)基乙烯(DT)两种荧光分子的LB膜以及两者的混合膜。以吸收光谱和荧光光谱探讨了膜中分子的构型、微环境、发光性能等特征。发现在LB膜的缀密排布环境中DCM顺式构型的含量较之在溶液中大为增加。","abstractInfoEn":"The LB films of two fluorescent molectiles,4-dicyanomethylene-2-methyl-6-<i>p<\/i>-dimethylaminostyryl-4H-pyran (DCM) and 1,2-bis(5-methylbenzoxazol-2-yl) ethylene (DT) and their mixture were prepared. The configtiration, micro environment and luminescence properties of these molecules in films have been investigated by absorption and fluorcscence spectroscopy. The content of <i>cis<\/i>-form DCM in LB film was found to be greatly increascd in comparison with that in solution.","articleNo":"19950214","authorCnList":["王文韵","  崔海宁","  王新平"],"authorEnList":["Wang Wenyun","  Cui Haining","  Wang Xinping"],"authorList":["王文韵","  崔海宁","  王新平"],"authors":"王文韵,  崔海宁,  王新平","authorsCn":"王文韵,  崔海宁,  王新平","authorsEn":"Wang Wenyun,  Cui Haining,  Wang Xinping","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"王文韵,  崔海宁,  王新平. 两种荧光LB膜的制备和光谱性能. 应用化学, 1995, 12(2): 55-58.","citationCn":"王文韵,  崔海宁,  王新平. 两种荧光LB膜的制备和光谱性能. 应用化学, 1995, 12(2): 55-58.","citationEn":"王文韵,  崔海宁,  王新平. Preparation and Spectral Properties of Two Fluorescent LB Films. Chinese Journal of Applied Chemistry, 1995, 12(2): 55-58.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"55","highCitedState":"","htmlCount":56,"htmlFile":"","id":"fe6b6557-d866-4cc9-9254-77691e219e45","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"LB膜, 二氰基亚甲基-甲基-对二申胺基苯乙烯基-吡喃, 双(甲基苯并噁唑)基乙烯","keywordCn":"LB膜, 二氰基亚甲基-甲基-对二申胺基苯乙烯基-吡喃, 双(甲基苯并噁唑)基乙烯","keywordCnList":["LB膜"," 二氰基亚甲基-甲基-对二申胺基苯乙烯基-吡喃"," 双(甲基苯并噁唑)基乙烯"],"keywordEn":"fluorescent LB film, dicyanomethylene-methyl-<i>p<\/i>-dimethylaminostyryl-4H-py-ran, bis(methylbenzoxazolyl)ethylene","keywordEnList":["fluorescent LB film"," dicyanomethylene-methyl-<i>p<\/i>-dimethylaminostyryl-4H-py-ran"," bis(methylbenzoxazolyl)ethylene"],"keywordList":["LB膜"," 二氰基亚甲基-甲基-对二申胺基苯乙烯基-吡喃"," 双(甲基苯并噁唑)基乙烯"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"58","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":294.79,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"两种荧光LB膜的制备和光谱性能","titleCn":"两种荧光LB膜的制备和光谱性能","titleEn":"Preparation and Spectral Properties of Two Fluorescent LB Films","viewCount":446,"volume":"12","year":1995},{"abstractInfo":"测定了VOSO<sub>4<\/sub>与谷氨酸及VOSO<sub>4<\/sub>与谷氨酸、1,10-邻菲咯啉在乙二醇/水(1:1)溶液中的低温ESR波谱。利用Johnson加和规则并结合IR,推测了在不同pH下生成的配合物的可能结构。利用电子光谱数据计算了配合物的晶体场参数,讨论了成配规律。","abstractInfoCn":"测定了VOSO<sub>4<\/sub>与谷氨酸及VOSO<sub>4<\/sub>与谷氨酸、1,10-邻菲咯啉在乙二醇/水(1:1)溶液中的低温ESR波谱。利用Johnson加和规则并结合IR,推测了在不同pH下生成的配合物的可能结构。利用电子光谱数据计算了配合物的晶体场参数,讨论了成配规律。","abstractInfoEn":"The ESR spectra of VO-Glu and VO-Glu-phen systems in glycol/water(1:1) mixture with various acidity have been recorded at 173K. It is found that the constitution of the complexes is in dependence on the pH values of the solution. Their possible structures were suggested according to Johnson's rule and IR values. By using electronic spectral data the crystal field parameters were calculated.","articleNo":"19950215","authorCnList":["陈德余","  张仕勇","  周玉成","  何玲"],"authorEnList":["Chen Deyu","  Zhang Shiyong","  Zhou Yucheng","  He Ling"],"authorList":["陈德余","  张仕勇","  周玉成","  何玲"],"authors":"陈德余,  张仕勇,  周玉成,  何玲","authorsCn":"陈德余,  张仕勇,  周玉成,  何玲","authorsEn":"Chen Deyu,  Zhang Shiyong,  Zhou Yucheng,  He Ling","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"陈德余,  张仕勇,  周玉成,  何玲. VO<sup>2+<\/sup>-谷氨酸-1,10-邻菲咯啉配合物的结构. 应用化学, 1995, 12(2): 59-62.","citationCn":"陈德余,  张仕勇,  周玉成,  何玲. VO<sup>2+<\/sup>-谷氨酸-1,10-邻菲咯啉配合物的结构. 应用化学, 1995, 12(2): 59-62.","citationEn":"陈德余,  张仕勇,  周玉成,  何玲. Study on Structures and Spectra of Oxovanadium Complexes with Glu and Phen Ligands. Chinese Journal of Applied Chemistry, 1995, 12(2): 59-62.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"59","highCitedState":"","htmlCount":68,"htmlFile":"","id":"f187a0a2-1a4f-46f6-8f71-16c40933027f","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"谷氨酸, 邻菲咯啉, VO<sup>2+<\/sup>配合物, ESR谱, 晶体场参数","keywordCn":"谷氨酸, 邻菲咯啉, VO<sup>2+<\/sup>配合物, ESR谱, 晶体场参数","keywordCnList":["谷氨酸"," 邻菲咯啉"," VO<sup>2+<\/sup>配合物"," ESR谱"," 晶体场参数"],"keywordEn":"glutamic acid, phenanthroline, VO<sup>2+<\/sup> complex, ESR spectrum, crystal field pa-rameter","keywordEnList":["glutamic acid"," phenanthroline"," VO<sup>2+<\/sup> complex"," ESR spectrum"," crystal field pa-rameter"],"keywordList":["谷氨酸"," 邻菲咯啉"," VO<sup>2+<\/sup>配合物"," ESR谱"," 晶体场参数"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"62","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":291.36,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"VO<sup>2+<\/sup>-谷氨酸-1,10-邻菲咯啉配合物的结构","titleCn":"VO<sup>2+<\/sup>-谷氨酸-1,10-邻菲咯啉配合物的结构","titleEn":"Study on Structures and Spectra of Oxovanadium Complexes with Glu and Phen Ligands","viewCount":636,"volume":"12","year":1995},{"abstractInfo":"通过硫代磷酰-氯酯与<i>N<\/i>,<i>N<\/i>-二丙基-<i>α<\/i>-乙氨基乙酰胺反应合成了21种-<i>α<\/i>-硫代磷酰基胺基乙酰胺衍生物。所合成的化合物用元素分析、<sup>1<\/sup>HNMR和<sup>31<\/sup>PNMR进行了表征,并进行了杀虫和杀螨活性的试验。","abstractInfoCn":"通过硫代磷酰-氯酯与<i>N<\/i>,<i>N<\/i>-二丙基-<i>α<\/i>-乙氨基乙酰胺反应合成了21种-<i>α<\/i>-硫代磷酰基胺基乙酰胺衍生物。所合成的化合物用元素分析、<sup>1<\/sup>H NMR和<sup>31<\/sup>P NMR进行了表征,并进行了杀虫和杀螨活性的试验。","abstractInfoEn":"Twenty one <i>α<\/i>-thiophosphorylamidocetamidcs with general formula [RO(R<sup>1<\/sup>O)P (S)N(Et)CH<sub>2<\/sub>CON(C<sub>3<\/sub>H<sub>7<\/sub>)<sub>2<\/sub>] have been synthesized by reacting RO(R<sup>1<\/sup>O)P(S)Cl with EtNHCH<sub>2<\/sub>CON(C<sub>3<\/sub>H<sub>7<\/sub>)<sub>2<\/sub> and characterized by elemental analysis,<sup>1<\/sup>H NMR and <sup>31<\/sup> P NMR mea-surements. They showed a better acaricidal and insecticidal activity.","articleNo":"19950216","authorCnList":["刘钊杰","  贺红武","  李志荣","  万树青"],"authorEnList":["Liu Zhaojie","  He Hongwu","  Li Zhirong","  Wan Shuqing"],"authorList":["刘钊杰","  贺红武","  李志荣","  万树青"],"authors":"刘钊杰,  贺红武,  李志荣,  万树青","authorsCn":"刘钊杰,  贺红武,  李志荣,  万树青","authorsEn":"Liu Zhaojie,  He Hongwu,  Li Zhirong,  Wan Shuqing","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"刘钊杰,  贺红武,  李志荣,  万树青. 具有生物活性的有机磷化合物研究Ⅸ.甘氨酰胺的硫代磷酰化衍生物的合成与生物活性. 应用化学, 1995, 12(2): 63-66.","citationCn":"刘钊杰,  贺红武,  李志荣,  万树青. 具有生物活性的有机磷化合物研究Ⅸ.甘氨酰胺的硫代磷酰化衍生物的合成与生物活性. 应用化学, 1995, 12(2): 63-66.","citationEn":"刘钊杰,  贺红武,  李志荣,  万树青. Studies on Biologically Active Organophosphorus Compounds Ⅸ. Synthesis and Biological Activities of Glycinamide Containing Phosphorus Derivatives. Chinese Journal of Applied Chemistry, 1995, 12(2): 63-66.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"63","highCitedState":"","htmlCount":58,"htmlFile":"","id":"73efe5be-d22e-4ad5-a36c-91ad920b119e","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"<i>α<\/i>-硫代磷酰胺基乙酰胺, 合成, 杀虫活性, 杀螨活性","keywordCn":"<i>α<\/i>-硫代磷酰胺基乙酰胺, 合成, 杀虫活性, 杀螨活性","keywordCnList":["<i>α<\/i>-硫代磷酰胺基乙酰胺"," 合成"," 杀虫活性"," 杀螨活性"],"keywordEn":"<i>α<\/i>-thiophosphorylamidoacetamide, synthesis, acaricdal activity, insecticidal activi-ty","keywordEnList":["<i>α<\/i>-thiophosphorylamidoacetamide"," synthesis"," acaricdal activity"," insecticidal activi-ty"],"keywordList":["<i>α<\/i>-硫代磷酰胺基乙酰胺"," 合成"," 杀虫活性"," 杀螨活性"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"66","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":284.71,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"具有生物活性的有机磷化合物研究Ⅸ.甘氨酰胺的硫代磷酰化衍生物的合成与生物活性","titleCn":"具有生物活性的有机磷化合物研究Ⅸ.甘氨酰胺的硫代磷酰化衍生物的合成与生物活性","titleEn":"Studies on Biologically Active Organophosphorus Compounds Ⅸ. Synthesis and Biological Activities of Glycinamide Containing Phosphorus Derivatives","viewCount":432,"volume":"12","year":1995},{"abstractInfo":"采用溶胶-凝胶法制得了二氧化锡干凝胶粉体,并在不同温度下热处理后得到不同粒径的二氧化锡纳米级超微粉,采用热重法和差热分析、<i>X<\/i>-射线粉末衍射、透射电镜等方法观察了不同温度热处理后纳米粉体的粒径、形貌、聚集状态等的变化。","abstractInfoCn":"采用溶胶-凝胶法制得了二氧化锡干凝胶粉体,并在不同温度下热处理后得到不同粒径的二氧化锡纳米级超微粉,采用热重法和差热分析、<i>X<\/i>-射线粉末衍射、透射电镜等方法观察了不同温度热处理后纳米粉体的粒径、形貌、聚集状态等的变化。","abstractInfoEn":"Nanosized stannic oxide powders were prepared by sol-gel method. The mi-crostructure change of the ultrafine particles after heat-treatment at 300~800℃ has been in-vestigated by XRD,TEM,TG-DTA,and FT-IR techniques. It is found that the intensity of the transverse optical mode of Sn-O streching vibration increased with the calcining tempcr-ature and the bonding vibration of O-Sn-O showed a blue shift. The changes are strongly affected by the size, shape, and the state of aggregation of the ultrafine particles.","articleNo":"19950217","authorCnList":["李泉","  曾广赋","  席时权"],"authorEnList":["Li Quan","  Zeng Guangfu","  Xi Shiquan"],"authorList":["李泉","  曾广赋","  席时权"],"authors":"李泉,  曾广赋,  席时权","authorsCn":"李泉,  曾广赋,  席时权","authorsEn":"Li Quan,  Zeng Guangfu,  Xi Shiquan","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"李泉,  曾广赋,  席时权. 二氧化锡纳米粉末的热处理与微结构. 应用化学, 1995, 12(2): 67-71.","citationCn":"李泉,  曾广赋,  席时权. 二氧化锡纳米粉末的热处理与微结构. 应用化学, 1995, 12(2): 67-71.","citationEn":"李泉,  曾广赋,  席时权. Heat Treatment and Microstructure of Nanosized Stannic Oxide Powders. Chinese Journal of Applied Chemistry, 1995, 12(2): 67-71.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"67","highCitedState":"","htmlCount":91,"htmlFile":"","id":"8ba6ec5a-b203-40a6-a0a4-053afefee9d9","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"二氧化锡, 溶胶-凝胶法, 纳米粉体, 微结构, 红外光谱","keywordCn":"二氧化锡, 溶胶-凝胶法, 纳米粉体, 微结构, 红外光谱","keywordCnList":["二氧化锡"," 溶胶-凝胶法"," 纳米粉体"," 微结构"," 红外光谱"],"keywordEn":"stannic oxide, nanosized particle, heat-treatment, microstructure, IR","keywordEnList":["stannic oxide"," nanosized particle"," heat-treatment"," microstructure"," IR"],"keywordList":["二氧化锡"," 溶胶-凝胶法"," 纳米粉体"," 微结构"," 红外光谱"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"71","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":2,"pdfSize":366.72,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"二氧化锡纳米粉末的热处理与微结构","titleCn":"二氧化锡纳米粉末的热处理与微结构","titleEn":"Heat Treatment and Microstructure of Nanosized Stannic Oxide Powders","viewCount":602,"volume":"12","year":1995},{"abstractInfo":"以醋酸酐封端的不饱和聚酯(FUPR)与交联聚氨酯预聚物制备了具有互穿聚合物网络(IPN)的不饱和聚酯/聚氨酯,通过红外,DSC和扫描电镜等分析了FUPR/PUIPN网络形成的动力学,微相分离行为及力学性能。结果表明,当FUPR/PU达到其-比值时,产生网络互穿效应,可改善聚氨酯的刚性,提高不饱和聚酯的抗冲性。","abstractInfoCn":"以醋酸酐封端的不饱和聚酯(FUPR)与交联聚氨酯预聚物制备了具有互穿聚合物网络(IPN)的不饱和聚酯/聚氨酯,通过红外,DSC和扫描电镜等分析了FUPR/PUIPN网络形成的动力学,微相分离行为及力学性能。结果表明,当FUPR/PU达到其-比值时,产生网络互穿效应,可改善聚氨酯的刚性,提高不饱和聚酯的抗冲性。","abstractInfoEn":"A polyester/polyurethane interpenetrating polymer network (IPN) was prepared from acetoxy terminated unsaturated polyester(FUPR) and crosslinked polyurethaiie pre-polymer. The kinetics of network formation, behavior of rnicrophase separation and mecha-nical properties of the IPNs were examined by IR,DSC,and SEM. The results showed that the IPN was formed at a certain ratio of FUPR/PU. The products showed an improved ri-gidity to polyutrethane and increased impact strength to unsaturated polyester.","articleNo":"19950218","authorCnList":["许美萱","  管云林","  刘文广","  姚康德","  肖景松","  薛普兴"],"authorEnList":["Xu Meixuan","  Guan Yunlin","  Liu Wenguang","  Yao Kangde","  Xiao Jingsong","  Xue Puxing"],"authorList":["许美萱","  管云林","  刘文广","  姚康德","  肖景松","  薛普兴"],"authors":"许美萱,  管云林,  刘文广,  姚康德,  肖景松,  薛普兴","authorsCn":"许美萱,  管云林,  刘文广,  姚康德,  肖景松,  薛普兴","authorsEn":"Xu Meixuan,  Guan Yunlin,  Liu Wenguang,  Yao Kangde,  Xiao Jingsong,  Xue Puxing","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"许美萱,  管云林,  刘文广,  姚康德,  肖景松,  薛普兴. 不饱和聚酯/聚氨酯互穿网络聚合物的合成. 应用化学, 1995, 12(2): 72-75.","citationCn":"许美萱,  管云林,  刘文广,  姚康德,  肖景松,  薛普兴. 不饱和聚酯/聚氨酯互穿网络聚合物的合成. 应用化学, 1995, 12(2): 72-75.","citationEn":"许美萱,  管云林,  刘文广,  姚康德,  肖景松,  薛普兴. Synthesis of Unsaturated Polyester/Polyurethane Interpenetrating Polymer Networks. Chinese Journal of Applied Chemistry, 1995, 12(2): 72-75.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"72","highCitedState":"","htmlCount":85,"htmlFile":"","id":"900ad1a4-547f-4891-ad2e-e463fe766752","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"互穿聚合物网络, 不饱和聚酯, 聚氨酯, 合成","keywordCn":"互穿聚合物网络, 不饱和聚酯, 聚氨酯, 合成","keywordCnList":["互穿聚合物网络"," 不饱和聚酯"," 聚氨酯"," 合成"],"keywordEn":"interpenetrating polymer network, unsaturated polyester, polyurethane, synthesis","keywordEnList":["interpenetrating polymer network"," unsaturated polyester"," polyurethane"," synthesis"],"keywordList":["互穿聚合物网络"," 不饱和聚酯"," 聚氨酯"," 合成"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"75","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":121.2,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"不饱和聚酯/聚氨酯互穿网络聚合物的合成","titleCn":"不饱和聚酯/聚氨酯互穿网络聚合物的合成","titleEn":"Synthesis of Unsaturated Polyester/Polyurethane Interpenetrating Polymer Networks","viewCount":582,"volume":"12","year":1995},{"abstractInfo":"用DSC法研究了La<sub>2<\/sub>O<sub>3<\/sub>和Y<sub>2<\/sub>O<sub>3<\/sub>对浇铸尼龙-6(MC尼龙-6)结晶与熔融的影响。二者都使MC尼龙-6熔体等速降温的结晶温度<i>T<\/i><sub>c<\/sub>升高、等速升温的溶点<i>T<\/i><sub>m<\/sub>降低、结晶度<i>X<\/i><sub>c<\/sub>降低,拉伸过程的断裂能密度及断裂伸长率提高。La<sub>2<\/sub>O<sub>3<\/sub>使MC尼龙-6平衡熔点<i>T<\/i><sub>m<\/sub><sup>o<\/sup>降低,结晶速率增加,结晶完善程度变差。Y<sub>2<\/sub>O<sub>3<\/sub>使MC尼龙-6的<i>T<\/i><sub>m<\/sub><sup>o<\/sup>升高,它可显著改善MC尼龙-6的耐热性。","abstractInfoCn":"用DSC法研究了La<sub>2<\/sub>O<sub>3<\/sub>和Y<sub>2<\/sub>O<sub>3<\/sub>对浇铸尼龙-6(MC尼龙-6)结晶与熔融的影响。二者都使MC尼龙-6熔体等速降温的结晶温度<i>T<\/i><sub>c<\/sub>升高、等速升温的溶点<i>T<\/i><sub>m<\/sub>降低、结晶度<i>X<\/i><sub>c<\/sub>降低,拉伸过程的断裂能密度及断裂伸长率提高。La<sub>2<\/sub>O<sub>3<\/sub>使MC尼龙-6平衡熔点<i>T<\/i><sub>m<\/sub><sup>o<\/sup>降低,结晶速率增加,结晶完善程度变差。Y<sub>2<\/sub>O<sub>3<\/sub>使MC尼龙-6的<i>T<\/i><sub>m<\/sub><sup>o<\/sup>升高,它可显著改善MC尼龙-6的耐热性。","abstractInfoEn":"The influences of addition of La<sub>2<\/sub>O<sub>3<\/sub> and Y<sub>2<\/sub>O<sub>3<\/sub> on the crystallization and melting be-havior of MC nvlon-6 have been studied by DSC technique at a rate of 10℃/min. Both rare earth oxides increased the crvstallization temperattire <i>T<\/i><sub>c<\/sub> and decreascd the melting tempera-ture <i>T<\/i><sub>m<\/sub> of MC nylon-6,decreased the crystallinity <i>X<\/i><sub>c<\/sub>. Addition of La<sub>2<\/sub>O<sub>3<\/sub> decreased the equi-librlum melting temperature <i>T<\/i><sub>m<\/sub><sup>o<\/sup>,leading to the increased crystallization rate and imperfect-ness of the crvstallization. Adtlition of Y<sub>2<\/sub>O<sub>3<\/sub> increased the <i>T<\/i><sub>m<\/sub><sup>o<\/sup>, remarkedly improving the thermal stability of MC nylon-6.","articleNo":"19950219","authorCnList":["曲桂杰","  唐功本","  杨玉华","  刘景江"],"authorEnList":["Qu Guijie","  Tang Gongben","  Yang Yuhua","  Liu Jingjiang"],"authorList":["曲桂杰","  唐功本","  杨玉华","  刘景江"],"authors":"曲桂杰,  唐功本,  杨玉华,  刘景江","authorsCn":"曲桂杰,  唐功本,  杨玉华,  刘景江","authorsEn":"Qu Guijie,  Tang Gongben,  Yang Yuhua,  Liu Jingjiang","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"曲桂杰,  唐功本,  杨玉华,  刘景江. 浇铸尼龙-6的结晶与熔融. 应用化学, 1995, 12(2): 76-79.","citationCn":"曲桂杰,  唐功本,  杨玉华,  刘景江. 浇铸尼龙-6的结晶与熔融. 应用化学, 1995, 12(2): 76-79.","citationEn":"曲桂杰,  唐功本,  杨玉华,  刘景江. Melting and Crystallization of MC Nylon-6. Chinese Journal of Applied Chemistry, 1995, 12(2): 76-79.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"76","highCitedState":"","htmlCount":69,"htmlFile":"","id":"845dac71-2e7e-4886-b6d0-cf68235843b7","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"MC尼龙, 结晶, 熔融, 尼龙改性剂, 平衡熔点","keywordCn":"MC尼龙, 结晶, 熔融, 尼龙改性剂, 平衡熔点","keywordCnList":["MC尼龙"," 结晶"," 熔融"," 尼龙改性剂"," 平衡熔点"],"keywordEn":"MC nylon, crystallization, melting, La<sub>2<\/sub>O<sub>3<\/sub>, Y<sub>2<\/sub>O<sub>3<\/sub>","keywordEnList":["MC nylon"," crystallization"," melting"," La<sub>2<\/sub>O<sub>3<\/sub>"," Y<sub>2<\/sub>O<sub>3<\/sub>"],"keywordList":["MC尼龙"," 结晶"," 熔融"," 尼龙改性剂"," 平衡熔点"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"79","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":287.94,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"浇铸尼龙-6的结晶与熔融","titleCn":"浇铸尼龙-6的结晶与熔融","titleEn":"Melting and Crystallization of MC Nylon-6","viewCount":645,"volume":"12","year":1995},{"abstractInfo":"用超声波和离心方法将3种来源不同的粘土样品按粒径分级,测定各级分粒径比表面积和结构,并制各相应级分的粘土胶进行物理力学性能测试。结果表明,在-定范围内,粘土粒径的变化仅对粘土胶的某些力学性能产生明显的影响,而粘土粒子以其独特的形态结构对粘土胶产生显著的补强作用。","abstractInfoCn":"用超声波和离心方法将3种来源不同的粘土样品按粒径分级,测定各级分粒径比表面积和结构,并制各相应级分的粘土胶进行物理力学性能测试。结果表明,在-定范围内,粘土粒径的变化仅对粘土胶的某些力学性能产生明显的影响,而粘土粒子以其独特的形态结构对粘土胶产生显著的补强作用。","abstractInfoEn":"Three kinds of clay were fractionated according to the particle size using ultrasonic and centrifugal method. The mechanical properties of the clay-rubber masterbatch with vari-ous clay fractions were determined. The results show that within a certain range,the clay particle size only affects some of the mechanical properties of clay-rubber masterbatch. The characteristic morphological structure of the clay provides a significant reinforcing action on clay-rubber masterbatch.","articleNo":"19950220","authorCnList":["敖宁建","  王少雄","  黎志平","  王爱玲","  周刚","  周慧玲"],"authorEnList":["Ao Ningjian","  Wang Shaoxiong","  Li Zhiping","  Wang Ailing","  Zhou Gang","  Zhou Huiling"],"authorList":["敖宁建","  王少雄","  黎志平","  王爱玲","  周刚","  周慧玲"],"authors":"敖宁建,  王少雄,  黎志平,  王爱玲,  周刚,  周慧玲","authorsCn":"敖宁建,  王少雄,  黎志平,  王爱玲,  周刚,  周慧玲","authorsEn":"Ao Ningjian,  Wang Shaoxiong,  Li Zhiping,  Wang Ailing,  Zhou Gang,  Zhou Huiling","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"敖宁建,  王少雄,  黎志平,  王爱玲,  周刚,  周慧玲. 粘土粒径及形态结构对粘土胶性能的影响. 应用化学, 1995, 12(2): 80-83.","citationCn":"敖宁建,  王少雄,  黎志平,  王爱玲,  周刚,  周慧玲. 粘土粒径及形态结构对粘土胶性能的影响. 应用化学, 1995, 12(2): 80-83.","citationEn":"敖宁建,  王少雄,  黎志平,  王爱玲,  周刚,  周慧玲. Effect of Clay Particle on Mechanical Properties of Clay-Rubber Masterbatch. Chinese Journal of Applied Chemistry, 1995, 12(2): 80-83.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"80","highCitedState":"","htmlCount":176,"htmlFile":"","id":"f6c2e41b-41a5-4df6-a37b-5bb6765e7393","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"粘土, 粘土胶, 补强作用","keywordCn":"粘土, 粘土胶, 补强作用","keywordCnList":["粘土"," 粘土胶"," 补强作用"],"keywordEn":"clay, clay-rubber masterbatch, reinforcing action","keywordEnList":["clay"," clay-rubber masterbatch"," reinforcing action"],"keywordList":["粘土"," 粘土胶"," 补强作用"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"83","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":1,"pdfSize":105.86,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"粘土粒径及形态结构对粘土胶性能的影响","titleCn":"粘土粒径及形态结构对粘土胶性能的影响","titleEn":"Effect of Clay Particle on Mechanical Properties of Clay-Rubber Masterbatch","viewCount":767,"volume":"12","year":1995},{"abstractInfo":"酞侧基聚芳醚砜(PES-C)与聚苯硫醚(PPS)具有部分相容性,虽然PPS的强度和韧性均低于PES-C,但PPS含量为2%~10%的PES-C/PPS共混物在保持PES-C原有强度、断裂伸长率的同时,模量略增,冲击强度有很大幅度提高,熔融指数亦有增加。","abstractInfoCn":"酞侧基聚芳醚砜(PES-C)与聚苯硫醚(PPS)具有部分相容性,虽然PPS的强度和韧性均低于PES-C,但PPS含量为2%~10%的PES-C/PPS共混物在保持PES-C原有强度、断裂伸长率的同时,模量略增,冲击强度有很大幅度提高,熔融指数亦有增加。","abstractInfoEn":"The morphology and mechanical properties of PES-C/PPS blends have been stud-ied by means of DSC,DMA,SEM and mechanical characterization. The blends are partly compatible. It is interested that, though the strength and ductility of PPS is lower than that of PES-C, at low content of PPS the impact strength of PES-C can be improved markedly without changing its tensile strength and elongation at break. The melt index of the blends also increases with increasing PPS content.","articleNo":"19950221","authorCnList":["杨宇明","  李滨耀","  张英俊","  张延","  庄国庆"],"authorEnList":["Yang Yuming","  Li Binyao","  Zhang Yingjun","  Zhang Yan","  Zhuang Guoqing"],"authorList":["杨宇明","  李滨耀","  张英俊","  张延","  庄国庆"],"authors":"杨宇明,  李滨耀,  张英俊,  张延,  庄国庆","authorsCn":"杨宇明,  李滨耀,  张英俊,  张延,  庄国庆","authorsEn":"Yang Yuming,  Li Binyao,  Zhang Yingjun,  Zhang Yan,  Zhuang Guoqing","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"杨宇明,  李滨耀,  张英俊,  张延,  庄国庆. 酞侧基聚芳醚砜/聚苯硫醚共混物的形态与力学性能. 应用化学, 1995, 12(2): 84-87.","citationCn":"杨宇明,  李滨耀,  张英俊,  张延,  庄国庆. 酞侧基聚芳醚砜/聚苯硫醚共混物的形态与力学性能. 应用化学, 1995, 12(2): 84-87.","citationEn":"杨宇明,  李滨耀,  张英俊,  张延,  庄国庆. Morphology and Mechanical Properties of Phenolphthalein Polyethersulfone-Polyphenylene Sulfide Blends. Chinese Journal of Applied Chemistry, 1995, 12(2): 84-87.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"84","highCitedState":"","htmlCount":67,"htmlFile":"","id":"52c6d13b-5787-45c6-a77e-6cc2611dbb9b","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"酞侧基聚芳醚砜, 聚苯硫醚, 相容性, 形态, 力学性能","keywordCn":"酞侧基聚芳醚砜, 聚苯硫醚, 相容性, 形态, 力学性能","keywordCnList":["酞侧基聚芳醚砜"," 聚苯硫醚"," 相容性"," 形态"," 力学性能"],"keywordEn":"phenolphthalein polyethersulfone, polyphenylene sulfide, compatibility, morpho-logy, mechanical property","keywordEnList":["phenolphthalein polyethersulfone"," polyphenylene sulfide"," compatibility"," morpho-logy"," mechanical property"],"keywordList":["酞侧基聚芳醚砜"," 聚苯硫醚"," 相容性"," 形态"," 力学性能"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"87","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":254.45,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"酞侧基聚芳醚砜/聚苯硫醚共混物的形态与力学性能","titleCn":"酞侧基聚芳醚砜/聚苯硫醚共混物的形态与力学性能","titleEn":"Morphology and Mechanical Properties of Phenolphthalein Polyethersulfone-Polyphenylene Sulfide Blends","viewCount":600,"volume":"12","year":1995},{"abstractInfo":"通过DSC和WAXD研究了高密度聚乙烯/低密度聚乙烯/乙烯-醋酸乙烯共聚物(HDPE/LDPE/EVA)三元共混体系的热行为和结晶性能.发现当HDPE含量小于40%时,EVA对LDPE起稀释剂作用,促进HDPE、LDPE的晶相分离,使HDPE、LDPE单独结晶.当HDPE含量高于40%时,LDPE片晶进入HDPE晶相.形成与LDPE在片晶水平上的共晶.","abstractInfoCn":"通过DSC和WAXD研究了高密度聚乙烯/低密度聚乙烯/乙烯-醋酸乙烯共聚物(HDPE/LDPE/EVA)三元共混体系的热行为和结晶性能.发现当HDPE含量小于40%时,EVA对LDPE起稀释剂作用,促进HDPE、LDPE的晶相分离,使HDPE、LDPE单独结晶.当HDPE含量高于40%时,LDPE片晶进入HDPE晶相.形成与LDPE在片晶水平上的共晶.","abstractInfoEn":"The thermal and crystallization behaviour of HDPE/LDPE/EVA blends have been studied by DSC and WAXD technigues. The results showed that when HDPE content was less than 40%, the EVA as a diluent for the LDPE,promotes crystal phase separation of HDPE and LDPE: when the content of HDPE was more than 40%,LDPE may enter into HDPE crystalline regions,forming cocrystallite in the lamellar regian.","articleNo":"19950222","authorCnList":["于旻","  杨连军","  李三喜","  古利新"],"authorEnList":["Yu Min","  Yang Lianjun","  Li Sanxi","  Gu Lixin"],"authorList":["于旻","  杨连军","  李三喜","  古利新"],"authors":"于旻,  杨连军,  李三喜,  古利新","authorsCn":"于旻,  杨连军,  李三喜,  古利新","authorsEn":"Yu Min,  Yang Lianjun,  Li Sanxi,  Gu Lixin","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"于旻,  杨连军,  李三喜,  古利新. 高密度聚乙烯/低密度聚乙烯/乙烯-醋酸乙烯共聚物共混体系的结晶行为. 应用化学, 1995, 12(2): 88-91.","citationCn":"于旻,  杨连军,  李三喜,  古利新. 高密度聚乙烯/低密度聚乙烯/乙烯-醋酸乙烯共聚物共混体系的结晶行为. 应用化学, 1995, 12(2): 88-91.","citationEn":"于旻,  杨连军,  李三喜,  古利新. Crystallization fo HDPE/LDPE/EVA Blends. Chinese Journal of Applied Chemistry, 1995, 12(2): 88-91.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"88","highCitedState":"","htmlCount":84,"htmlFile":"","id":"3e2a63ef-3be4-4c78-9ee2-f2e27ee8cd19","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"HDPE, LDPE, EVA, 共混物, 共晶","keywordCn":"HDPE, LDPE, EVA, 共混物, 共晶","keywordCnList":["HDPE"," LDPE"," EVA"," 共混物"," 共晶"],"keywordEn":"HDPE, LDPE, EVA, blend, cocrystallization","keywordEnList":["HDPE"," LDPE"," EVA"," blend"," cocrystallization"],"keywordList":["HDPE"," LDPE"," EVA"," 共混物"," 共晶"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"91","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":96.68,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"高密度聚乙烯/低密度聚乙烯/乙烯-醋酸乙烯共聚物共混体系的结晶行为","titleCn":"高密度聚乙烯/低密度聚乙烯/乙烯-醋酸乙烯共聚物共混体系的结晶行为","titleEn":"Crystallization fo HDPE/LDPE/EVA Blends","viewCount":532,"volume":"12","year":1995},{"abstractInfo":"具有冠醚基团的线型聚硅氧烷是-类用作毛细管色谱固定相<sup>[1]<\/sup>、高选择性液体萃取剂<sup>[2]<\/sup>、液膜<sup>[3]<\/sup>、支撑液膜载体<sup>[4]<\/sup>等的新材料,具有良好的应用前景。","abstractInfoCn":"具有冠醚基团的线型聚硅氧烷是-类用作毛细管色谱固定相<sup>[1]<\/sup>、高选择性液体萃取剂<sup>[2]<\/sup>、液膜<sup>[3]<\/sup>、支撑液膜载体<sup>[4]<\/sup>等的新材料,具有良好的应用前景。","abstractInfoEn":"3'-Allyldibenzo-18-crown-6,prepared from 3-allylcatechol and 1,2-bis(<i>β<\/i>-(<i>β<\/i>'-chloroethoxy)-ethoxy) benzene,was subjected to hydrosilylation by methyldichlorosiloxane,followed by polycondensation with hydroxy-terminated polydimethylsiloxane to give a linear polysiloxane with pendant crown ether moieties. The transport properties of sodium,potas-sium,and ammonium salts throtigh a bulk liquid membrane system using this polysiloxane as a carrier have been investigated.","articleNo":"19950223","authorCnList":["龚淑玲","  卢雪然","  卢光明","  陈远荫"],"authorEnList":["Gong Shuling","  Lu Xueran","  Lu Xianming","  Chen Yuanyin"],"authorList":["龚淑玲","  卢雪然","  卢光明","  陈远荫"],"authors":"龚淑玲,  卢雪然,  卢光明,  陈远荫","authorsCn":"龚淑玲,  卢雪然,  卢光明,  陈远荫","authorsEn":"Gong Shuling,  Lu Xueran,  Lu Xianming,  Chen Yuanyin","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"龚淑玲,  卢雪然,  卢光明,  陈远荫. 具有二苯并18-冠-6侧基的线型聚硅氧烷的合成及其促进离子传输性能. 应用化学, 1995, 12(2): 92-94.","citationCn":"龚淑玲,  卢雪然,  卢光明,  陈远荫. 具有二苯并18-冠-6侧基的线型聚硅氧烷的合成及其促进离子传输性能. 应用化学, 1995, 12(2): 92-94.","citationEn":"龚淑玲,  卢雪然,  卢光明,  陈远荫. Linear Polysiloxane with Pendant DB-18-C-6: Synthesis and Property of Ion Transport Improvement. Chinese Journal of Applied Chemistry, 1995, 12(2): 92-94.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"92","highCitedState":"","htmlCount":45,"htmlFile":"","id":"7d57ddcd-5cc0-4568-af18-f03d1cccf36b","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"冠醚, 聚硅氧烷, 离子载体, 液膜","keywordCn":"冠醚, 聚硅氧烷, 离子载体, 液膜","keywordCnList":["冠醚"," 聚硅氧烷"," 离子载体"," 液膜"],"keywordEn":"rown ether, polysiloxaiie, ionophore, liquid membrane","keywordEnList":["rown ether"," polysiloxaiie"," ionophore"," liquid membrane"],"keywordList":["冠醚"," 聚硅氧烷"," 离子载体"," 液膜"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"94","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":1,"pdfSize":212.83,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"具有二苯并18-冠-6侧基的线型聚硅氧烷的合成及其促进离子传输性能","titleCn":"具有二苯并18-冠-6侧基的线型聚硅氧烷的合成及其促进离子传输性能","titleEn":"Linear Polysiloxane with Pendant DB-18-C-6: Synthesis and Property of Ion Transport Improvement","viewCount":486,"volume":"12","year":1995},{"abstractInfo":"高氧化态Mo<sup>6+<\/sup>与稀土的复合氧化物研究得较多<sup>[1~4]<\/sup>,而低氧化态钼与稀土的复合氧化物研究的还不够深入<sup>[5~7]<\/sup>。","abstractInfoCn":"高氧化态Mo<sup>6+<\/sup>与稀土的复合氧化物研究得较多<sup>[1~4]<\/sup>,而低氧化态钼与稀土的复合氧化物研究的还不够深入<sup>[5~7]<\/sup>。","abstractInfoEn":"The molybdenum(Ⅳ) oxides of formula Ln<sub>2<\/sub>Mo<sub>3<\/sub>O<sub>9<\/sub> were obtained by reduction of <i>α<\/i>-Ln<sub>2<\/sub>Mo<sub>3<\/sub>O<sub>12<\/sub>(Ln=La,Pr,Nd, Sm,Gd,Dy) as well as Ce<sub>2<\/sub>Mo<sub>3<\/sub>O<sub>12.25<\/sub> in hydrogen at 500~650℃ for 60 hours. The compounds are of single phase and crystallize in tetragonal structure with parameters <i>α<\/i>=0.5260nm~0.5131nm and <i>c<\/i>=1.18211nm~1.1122nm. There are two broad absorption bands in the IR spectra of the Ln<sub>2<\/sub>Mo<sub>3<\/sub>O<sub>9<\/sub>. All of the compounds are <i>n<\/i>-type semiconductors with <i>ρ<\/i><sub>r.t.<\/sub> =92.13Ωcm~7.51Ωcm. Their electrical properties at 10~350℃ and magnetic properties at 100~250K were measured.","articleNo":"19950224","authorCnList":["史发年","  任玉芳","  孟建"],"authorEnList":["Shi Fanian","  Ren Yufang","  Meng Jian"],"authorList":["史发年","  任玉芳","  孟建"],"authors":"史发年,  任玉芳,  孟建","authorsCn":"史发年,  任玉芳,  孟建","authorsEn":"Shi Fanian,  Ren Yufang,  Meng Jian","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"史发年,  任玉芳,  孟建. Ln<sub>2<\/sub>Mo<sub>3<\/sub>O<sub>9<\/sub>的制备、结构及电磁性质. 应用化学, 1995, 12(2): 95-97.","citationCn":"史发年,  任玉芳,  孟建. Ln<sub>2<\/sub>Mo<sub>3<\/sub>O<sub>9<\/sub>的制备、结构及电磁性质. 应用化学, 1995, 12(2): 95-97.","citationEn":"史发年,  任玉芳,  孟建. Preparation,Structure,Electrical and Magnetic Properties of Ln<sub>2<\/sub>Mo<sub>3<\/sub>O<sub>9<\/sub>. Chinese Journal of Applied Chemistry, 1995, 12(2): 95-97.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"95","highCitedState":"","htmlCount":47,"htmlFile":"","id":"629c98ba-39d8-4151-a41f-ca97f50fc8ef","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"稀土钼酸盐, 结构, 电学性质, 磁学性质","keywordCn":"稀土钼酸盐, 结构, 电学性质, 磁学性质","keywordCnList":["稀土钼酸盐"," 结构"," 电学性质"," 磁学性质"],"keywordEn":"rare earth molybdate, structure, electrical property, magnetic property","keywordEnList":["rare earth molybdate"," structure"," electrical property"," magnetic property"],"keywordList":["稀土钼酸盐"," 结构"," 电学性质"," 磁学性质"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"97","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":1,"pdfSize":222.81,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"Ln<sub>2<\/sub>Mo<sub>3<\/sub>O<sub>9<\/sub>的制备、结构及电磁性质","titleCn":"Ln<sub>2<\/sub>Mo<sub>3<\/sub>O<sub>9<\/sub>的制备、结构及电磁性质","titleEn":"Preparation,Structure,Electrical and Magnetic Properties of Ln<sub>2<\/sub>Mo<sub>3<\/sub>O<sub>9<\/sub>","viewCount":466,"volume":"12","year":1995},{"abstractInfo":"聚己内酯(PCL)作为生物降解材料,无毒、无副作用，但其结晶度不高,不易降解,药物渗透性差。","abstractInfoCn":"聚己内酯(PCL)作为生物降解材料,无毒、无副作用，但其结晶度不高,不易降解,药物渗透性差。","abstractInfoEn":"The crystallization of polycaprolactone (PCL),polyethylene glycol (PEG) and their block copolymers have been studied using DSC technique. The results showed that the composition as well as the molecular weight of PCL and PEG affected the crystallinity of the block copolymers. The crystallinity of the copolymer showed a maximum value on standing. Some of the kinetic parameters on isothermo-crystallization have been calculated.","articleNo":"19950225","authorCnList":["高家武","  段跃新","  王身国","  邱波"],"authorEnList":["Gao Jiawu","  Duan Yuexin","  Wang Shenguo","  Qiu Bo"],"authorList":["高家武","  段跃新","  王身国","  邱波"],"authors":"高家武,  段跃新,  王身国,  邱波","authorsCn":"高家武,  段跃新,  王身国,  邱波","authorsEn":"Gao Jiawu,  Duan Yuexin,  Wang Shenguo,  Qiu Bo","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"高家武,  段跃新,  王身国,  邱波. 聚己内酯,聚乙二醇及其嵌段物的结晶行为. 应用化学, 1995, 12(2): 98-100.","citationCn":"高家武,  段跃新,  王身国,  邱波. 聚己内酯,聚乙二醇及其嵌段物的结晶行为. 应用化学, 1995, 12(2): 98-100.","citationEn":"高家武,  段跃新,  王身国,  邱波. Crystallization of Polycaprolactone, Polyethylene Glycol and Their Block Copolymers. Chinese Journal of Applied Chemistry, 1995, 12(2): 98-100.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"98","highCitedState":"","htmlCount":199,"htmlFile":"","id":"16cf6157-fb5f-4711-8d4a-e972c646af34","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"聚己内酯, 聚乙二醇, 嵌段共聚物, 结晶度, 结晶动力学","keywordCn":"聚己内酯, 聚乙二醇, 嵌段共聚物, 结晶度, 结晶动力学","keywordCnList":["聚己内酯"," 聚乙二醇"," 嵌段共聚物"," 结晶度"," 结晶动力学"],"keywordEn":"polycaprolactone, polyethylene glycol, block copolymer, crystallization","keywordEnList":["polycaprolactone"," polyethylene glycol"," block copolymer"," crystallization"],"keywordList":["聚己内酯"," 聚乙二醇"," 嵌段共聚物"," 结晶度"," 结晶动力学"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"100","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":4,"pdfSize":196.11,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"聚己内酯,聚乙二醇及其嵌段物的结晶行为","titleCn":"聚己内酯,聚乙二醇及其嵌段物的结晶行为","titleEn":"Crystallization of Polycaprolactone, Polyethylene Glycol and Their Block Copolymers","viewCount":921,"volume":"12","year":1995},{"abstractInfo":"含氧二茂铁衍生物的选择性还原在二茂铁衍生物制备上是一个很重要的反应。","abstractInfoCn":"含氧二茂铁衍生物的选择性还原在二茂铁衍生物制备上是一个很重要的反应。","abstractInfoEn":"NaBH<sub>3<\/sub>CN-ZnCl<sub>2<\/sub> was applied for the selective reduction deoxygenation of hydroxyl and carbonyl groups in ferrocene derivatives under mild condition without affecting on the carboxy groups. The molar ratio of B/Fe and Zn/Fe,as well as the solvents showed impor-tant influences on the deoxygenation. The possible intermediates were suggested.","articleNo":"19950226","authorCnList":["林欣欣","  W E Lindsell"],"authorEnList":["Lin Xinxin","  W E Lindsell"],"authorList":["林欣欣","  W E Lindsell"],"authors":"林欣欣,  W E Lindsell","authorsCn":"林欣欣,  W E Lindsell","authorsEn":"Lin Xinxin,  W E Lindsell","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"林欣欣,  W E Lindsell. NaBH<sub>3<\/sub>CN-ZnCl<sub>2<\/sub>体系对含氧二茂铁衍生物的选择性还原. 应用化学, 1995, 12(2): 101-103.","citationCn":"林欣欣,  W E Lindsell. NaBH<sub>3<\/sub>CN-ZnCl<sub>2<\/sub>体系对含氧二茂铁衍生物的选择性还原. 应用化学, 1995, 12(2): 101-103.","citationEn":"林欣欣,  W E Lindsell. Selective Reduction of Oxygen-Containing Ferrocene Derivatives with NaBH<sub>3<\/sub>Cn-ZnCl<sub>2<\/sub>. Chinese Journal of Applied Chemistry, 1995, 12(2): 101-103.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"101","highCitedState":"","htmlCount":72,"htmlFile":"","id":"c1847c61-3a12-4723-a826-ce8329088972","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"氰基硼氢化钠, 二氯化锌, 二茂铁衍生物, 选择性还原","keywordCn":"氰基硼氢化钠, 二氯化锌, 二茂铁衍生物, 选择性还原","keywordCnList":["氰基硼氢化钠"," 二氯化锌"," 二茂铁衍生物"," 选择性还原"],"keywordEn":"sodium cyanoborohydrate, zink chloride, ferrocene derivative, selective reduction","keywordEnList":["sodium cyanoborohydrate"," zink chloride"," ferrocene derivative"," selective reduction"],"keywordList":["氰基硼氢化钠"," 二氯化锌"," 二茂铁衍生物"," 选择性还原"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"103","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":200.49,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"NaBH<sub>3<\/sub>CN-ZnCl<sub>2<\/sub>体系对含氧二茂铁衍生物的选择性还原","titleCn":"NaBH<sub>3<\/sub>CN-ZnCl<sub>2<\/sub>体系对含氧二茂铁衍生物的选择性还原","titleEn":"Selective Reduction of Oxygen-Containing Ferrocene Derivatives with NaBH<sub>3<\/sub>Cn-ZnCl<sub>2<\/sub>","viewCount":778,"volume":"12","year":1995},{"abstractInfo":"热塑聚酰胺树脂是由植物油聚合脂肪酸与乙二胺制得的分子量3000~9000的线型缩聚物。","abstractInfoCn":"热塑聚酰胺树脂是由植物油聚合脂肪酸与乙二胺制得的分子量3000~9000的线型缩聚物。","abstractInfoEn":"The alcohol-soluble polyamide resins have been obtained by copolymerization of a mixture comprising polymeric fatty acid,ricinoleic acid and sebacic acid with ethylenediamine and 1,3-diamino-2-hydroxypropane. In an appropriate proportion of ricinoleic acid to 1,3-di-amino-2-hydroxypropane the polymerized product exhibits an improved low temperature sol-ubility in lower molecular aliphatic alcohols and higher softening point.","articleNo":"19950227","authorCnList":["邢存章","  徐新国","  董铭章"],"authorEnList":["Xing Cunzhang","  Xu Xinguo","  Dong Mingzhang"],"authorList":["邢存章","  徐新国","  董铭章"],"authors":"邢存章,  徐新国,  董铭章","authorsCn":"邢存章,  徐新国,  董铭章","authorsEn":"Xing Cunzhang,  Xu Xinguo,  Dong Mingzhang","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"邢存章,  徐新国,  董铭章. 醇溶性聚酰胺树脂的制备. 应用化学, 1995, 12(2): 104-106.","citationCn":"邢存章,  徐新国,  董铭章. 醇溶性聚酰胺树脂的制备. 应用化学, 1995, 12(2): 104-106.","citationEn":"邢存章,  徐新国,  董铭章. Pteparation of Alcohol-Soluble Polyamide Resins. Chinese Journal of Applied Chemistry, 1995, 12(2): 104-106.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"104","highCitedState":"","htmlCount":47,"htmlFile":"","id":"7b77d1e2-57bf-4d7a-8221-16b0243ad41a","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"醇溶聚酰胺, 羟基丙二肢, 聚合脂肪酸, 二聚酸, 制备","keywordCn":"醇溶聚酰胺, 羟基丙二肢, 聚合脂肪酸, 二聚酸, 制备","keywordCnList":["醇溶聚酰胺"," 羟基丙二肢"," 聚合脂肪酸"," 二聚酸"," 制备"],"keywordEn":"alcohol-soluble polyamide, diaminohydroxypropane, polymeric fatty acid, ricino-leic acid, preparation","keywordEnList":["alcohol-soluble polyamide"," diaminohydroxypropane"," polymeric fatty acid"," ricino-leic acid"," preparation"],"keywordList":["醇溶聚酰胺"," 羟基丙二肢"," 聚合脂肪酸"," 二聚酸"," 制备"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"106","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":208.75,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"醇溶性聚酰胺树脂的制备","titleCn":"醇溶性聚酰胺树脂的制备","titleEn":"Pteparation of Alcohol-Soluble Polyamide Resins","viewCount":549,"volume":"12","year":1995},{"abstractInfo":"茶叶中富含-类多羟基的酚性化合物—茶多酚(Tea-Polyphenols,简称TP)是-种新型的天然抗氧化剂<sup>[1]<\/sup>,且具有抗癌、抗衰老、抗辐射、清除人体自由基、降血糖血脂等一系列重要的药理功能<sup>[2,3]<\/sup>,在油脂、食品、医药、日化等领域具有广阔的应用前景.","abstractInfoCn":"茶叶中富含-类多羟基的酚性化合物—茶多酚(Tea-Polyphenols,简称TP)是-种新型的天然抗氧化剂<sup>[1]<\/sup>,且具有抗癌、抗衰老、抗辐射、清除人体自由基、降血糖血脂等一系列重要的药理功能<sup>[2,3]<\/sup>,在油脂、食品、医药、日化等领域具有广阔的应用前景.","abstractInfoEn":"The conditions of extraction of tea-polyphenols (TP) from tea dusts by precipita-tion method using metal ions Ca<sup>2+<\/sup>,Mg<sup>2+<\/sup>,Ba<sup>2+<\/sup>,Fe<sup>3+<\/sup>,Zn<sup>2+<\/sup> and Al<sup>3+<\/sup> as precipitating agents have been investigated. The influences of pH value,temperture,time,type and content of basic solutions used to regulate the pH value on the extraction rate of TP were examined. It is shown that the extraction rate of TP could reach 10.5% and the content of the effective in-gredients of TP could reach 99.5% by the proposed method.","articleNo":"19950228","authorCnList":["葛宜掌","  金红"],"authorEnList":["Ge Yizhang","  Jin Hong"],"authorList":["葛宜掌","  金红"],"authors":"葛宜掌,  金红","authorsCn":"葛宜掌,  金红","authorsEn":"Ge Yizhang,  Jin Hong","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"葛宜掌,  金红. 茶多酚的离子沉淀提取法. 应用化学, 1995, 12(2): 107-109.","citationCn":"葛宜掌,  金红. 茶多酚的离子沉淀提取法. 应用化学, 1995, 12(2): 107-109.","citationEn":"葛宜掌,  金红. Extraction of Tea-Polyphenols by Precipitation Method. Chinese Journal of Applied Chemistry, 1995, 12(2): 107-109.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"107","highCitedState":"","htmlCount":122,"htmlFile":"","id":"f3549545-8569-453e-ab6e-3a2d548bde7b","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"茶多酚, 金属离子, 提取, 沉淀法","keywordCn":"茶多酚, 金属离子, 提取, 沉淀法","keywordCnList":["茶多酚"," 金属离子"," 提取"," 沉淀法"],"keywordEn":"tea-polyphenol, metal ion, extraction, precipitation method","keywordEnList":["tea-polyphenol"," metal ion"," extraction"," precipitation method"],"keywordList":["茶多酚"," 金属离子"," 提取"," 沉淀法"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"109","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":238.5,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"茶多酚的离子沉淀提取法","titleCn":"茶多酚的离子沉淀提取法","titleEn":"Extraction of Tea-Polyphenols by Precipitation Method","viewCount":724,"volume":"12","year":1995},{"abstractInfo":"用硫脲浸出法提取金、银具有速度快、毒性小,再生净化工序简单等优点<sup>[1]<\/sup>.","abstractInfoCn":"用硫脲浸出法提取金、银具有速度快、毒性小,再生净化工序简单等优点<sup>[1]<\/sup>.","abstractInfoEn":"The adsorption of gold-thiourea complex ions by activated carbon in solution has been studied. The adsorption rate curves and isothems were obtained and the effects of pH values of the solution and foreign ions were examined. The microwave radiation technique was used to desorb the gold complexes from the activated carbon. It is found to be more ef-fective as compared with other desorption methods.","articleNo":"19950229","authorCnList":["杨春芬","  王光灿"],"authorEnList":["Yang Chunfen","  Wang Guangcan"],"authorList":["杨春芬","  王光灿"],"authors":"杨春芬,  王光灿","authorsCn":"杨春芬,  王光灿","authorsEn":"Yang Chunfen,  Wang Guangcan","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"杨春芬,  王光灿. 金离子的活性炭吸附及微波解吸. 应用化学, 1995, 12(2): 110-112.","citationCn":"杨春芬,  王光灿. 金离子的活性炭吸附及微波解吸. 应用化学, 1995, 12(2): 110-112.","citationEn":"杨春芬,  王光灿. Adsorption of Gold by Activated Carbon and Its Desorption with Microwave Technique. Chinese Journal of Applied Chemistry, 1995, 12(2): 110-112.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"110","highCitedState":"","htmlCount":75,"htmlFile":"","id":"61682e41-06b0-467d-a156-b8f3b9763115","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"金, 硫脲, 吸附, 微波解吸","keywordCn":"金, 硫脲, 吸附, 微波解吸","keywordCnList":["金"," 硫脲"," 吸附"," 微波解吸"],"keywordEn":"gold, thiourea, adsorption, microwave desorption","keywordEnList":["gold"," thiourea"," adsorption"," microwave desorption"],"keywordList":["金"," 硫脲"," 吸附"," 微波解吸"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"112","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":4,"pdfSize":192.3,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"金离子的活性炭吸附及微波解吸","titleCn":"金离子的活性炭吸附及微波解吸","titleEn":"Adsorption of Gold by Activated Carbon and Its Desorption with Microwave Technique","viewCount":555,"volume":"12","year":1995},{"abstractInfo":"铂催化硅氢加成的机理<sup>[1,2]<\/sup>、副反应<sup>[3,4]<\/sup>、聚合物性能<sup>[3,5]<\/sup>等均有报道,献用粘度、扭变模量表示反应进行的程度<sup>[6]<\/sup>,并没涉及含氢硅氧烷的结构对硅氢加成反应速度的影响.","abstractInfoCn":"铂催化硅氢加成的机理<sup>[1,2]<\/sup>、副反应<sup>[3,4]<\/sup>、聚合物性能<sup>[3,5]<\/sup>等均有报道,献用粘度、扭变模量表示反应进行的程度<sup>[6]<\/sup>,并没涉及含氢硅氧烷的结构对硅氢加成反应速度的影响.","abstractInfoEn":"A series of hydrosiloxanes were prepared as model compounds for hydrosilylation study of 1,3-divinyl-1,1,3,3-tetramethyl-disiloxane in relation to their vinyl contents. The results show that the rate of hydrosilylation depends on the structure of the hydrosiloxane.","articleNo":"19950230","authorCnList":["师彤","  谢择民","  王清正"],"authorEnList":["Shi Tong","  Xie Zemin","  Wang Qingzheng"],"authorList":["师彤","  谢择民","  王清正"],"authors":"师彤,  谢择民,  王清正","authorsCn":"师彤,  谢择民,  王清正","authorsEn":"Shi Tong,  Xie Zemin,  Wang Qingzheng","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"师彤,  谢择民,  王清正. 含氢硅氧烷的硅氢加成反应. 应用化学, 1995, 12(2): 113-114.","citationCn":"师彤,  谢择民,  王清正. 含氢硅氧烷的硅氢加成反应. 应用化学, 1995, 12(2): 113-114.","citationEn":"师彤,  谢择民,  王清正. Hydrosilylation of Hydrosiloxanes with a Disiloxane. Chinese Journal of Applied Chemistry, 1995, 12(2): 113-114.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"113","highCitedState":"","htmlCount":129,"htmlFile":"","id":"da3d87e1-bfbe-4671-9afe-f1247bd9d890","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"含氢硅氧烷, 二乙烯基四甲基二硅氧烷, 硅氢加成反应, <sup>1<\/sup>H NMR","keywordCn":"含氢硅氧烷, 二乙烯基四甲基二硅氧烷, 硅氢加成反应, <sup>1<\/sup>H NMR","keywordCnList":["含氢硅氧烷"," 二乙烯基四甲基二硅氧烷"," 硅氢加成反应"," <sup>1<\/sup>H NMR"],"keywordEn":"hydrosiloxane, divinyl-tetramethyl-disiloxanc, hydrosilylation, NMR","keywordEnList":["hydrosiloxane"," divinyl-tetramethyl-disiloxanc"," hydrosilylation"," NMR"],"keywordList":["含氢硅氧烷"," 二乙烯基四甲基二硅氧烷"," 硅氢加成反应"," <sup>1<\/sup>H NMR"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"114","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":2,"pdfSize":160.28,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"含氢硅氧烷的硅氢加成反应","titleCn":"含氢硅氧烷的硅氢加成反应","titleEn":"Hydrosilylation of Hydrosiloxanes with a Disiloxane","viewCount":707,"volume":"12","year":1995},{"abstractInfo":"聚醚砜(PES)是-种性能优异的特种工程塑料,它具有强度高、刚性大、耐热等特点.","abstractInfoCn":"聚醚砜(PES)是-种性能优异的特种工程塑料,它具有强度高、刚性大、耐热等特点.","abstractInfoEn":"The blends of polyethersulfone (PES) with polycarbonate (PC) have been pre-pared by melt mixing in a brabender. Their mechanical property and transition behavior have been characterized by tensile test, DSC and TBA. The improvement of mechanical property of PES by blending has been discussed in terms of the compatibility.","articleNo":"19950231","authorCnList":["姜振华","  马荣堂","  寇喜春","  安立佳"],"authorEnList":["Jiang Zhenhua","  Ma Rongtang","  Kou Xichun","  An Lijia"],"authorList":["姜振华","  马荣堂","  寇喜春","  安立佳"],"authors":"姜振华,  马荣堂,  寇喜春,  安立佳","authorsCn":"姜振华,  马荣堂,  寇喜春,  安立佳","authorsEn":"Jiang Zhenhua,  Ma Rongtang,  Kou Xichun,  An Lijia","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"姜振华,  马荣堂,  寇喜春,  安立佳. PES/PC共混体系的相容性与力学性能. 应用化学, 1995, 12(2): 115-116.","citationCn":"姜振华,  马荣堂,  寇喜春,  安立佳. PES/PC共混体系的相容性与力学性能. 应用化学, 1995, 12(2): 115-116.","citationEn":"姜振华,  马荣堂,  寇喜春,  安立佳. Mechanical Properties of Polyethersulfone/Polycarbonate Blends. Chinese Journal of Applied Chemistry, 1995, 12(2): 115-116.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"115","highCitedState":"","htmlCount":92,"htmlFile":"","id":"7a0e688d-0342-472e-8130-93e61179e126","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"聚醚砜, 聚碳酸酯, 共混物, 力学性能","keywordCn":"聚醚砜, 聚碳酸酯, 共混物, 力学性能","keywordCnList":["聚醚砜"," 聚碳酸酯"," 共混物"," 力学性能"],"keywordEn":"polyethersulfone, polycarbonate, blend, mechanical property","keywordEnList":["polyethersulfone"," polycarbonate"," blend"," mechanical property"],"keywordList":["聚醚砜"," 聚碳酸酯"," 共混物"," 力学性能"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"116","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":140,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"PES/PC共混体系的相容性与力学性能","titleCn":"PES/PC共混体系的相容性与力学性能","titleEn":"Mechanical Properties of Polyethersulfone/Polycarbonate Blends","viewCount":631,"volume":"12","year":1995},{"abstractInfo":"壳聚糖(CTS)是重金瞩离子的吸附剂<sup>[1,2]<\/sup>,由于壳聚精分子中的-NH<sub>2<\/sub>在pH较低的水溶液易形成NH<sub>3<\/sub><sup>+<\/sup>而使CTS溶于水,造吸附剂的流失,另外CTS在吸附过程中因-NH<sub>2<\/sub>并未全部参予与金属离子的络合而使其吸附能力受到限制<sup>[3]<\/sup>.","abstractInfoCn":"壳聚糖(CTS)是重金瞩离子的吸附剂<sup>[1,2]<\/sup>,由于壳聚精分子中的-NH<sub>2<\/sub>在pH较低的水溶液易形成NH<sub>3<\/sub><sup>+<\/sup>而使CTS溶于水,造吸附剂的流失,另外CTS在吸附过程中因-NH<sub>2<\/sub>并未全部参予与金属离子的络合而使其吸附能力受到限制<sup>[3]<\/sup>.","abstractInfoEn":"Several derivatives of chitosan were prepared and their adsorption to Cu<sup>2-<\/sup> and Ni<sup>2+<\/sup> was studied,their structure was identified by IR.","articleNo":"19950232","authorCnList":["曲荣君","  马千里","  郑秀丽","  孙言志"],"authorEnList":["Qu Rongjun","  Ma Qianli","  Zheng Xiuli","  Sun Yanzhi"],"authorList":["曲荣君","  马千里","  郑秀丽","  孙言志"],"authors":"曲荣君,  马千里,  郑秀丽,  孙言志","authorsCn":"曲荣君,  马千里,  郑秀丽,  孙言志","authorsEn":"Qu Rongjun,  Ma Qianli,  Zheng Xiuli,  Sun Yanzhi","categoryName":"研究论文","categoryNameCn":"研究论文","categoryNameEn":"","citation":"曲荣君,  马千里,  郑秀丽,  孙言志. 壳聚糖衍生物的制备及其吸附性能. 应用化学, 1995, 12(2): 117-118.","citationCn":"曲荣君,  马千里,  郑秀丽,  孙言志. 壳聚糖衍生物的制备及其吸附性能. 应用化学, 1995, 12(2): 117-118.","citationEn":"曲荣君,  马千里,  郑秀丽,  孙言志. Preparation of Chitosan Derivatives and Their Adsorption Behaviour. Chinese Journal of Applied Chemistry, 1995, 12(2): 117-118.","doi":"","figContent":"","figList":[],"firstFig":"","fpage":"117","highCitedState":"","htmlCount":123,"htmlFile":"","id":"b9a09062-cfda-4724-81eb-f54537233646","issnPpub":"1000-0518","issue":"2","journalPublishId":"yyhx","journalReferenceCodeType":0,"journalTitleCn":"应用化学","journalTitleEn":"Chinese Journal of Applied Chemistry","keyword":"壳聚精衍生物, 制备, 吸附","keywordCn":"壳聚精衍生物, 制备, 吸附","keywordCnList":["壳聚精衍生物"," 制备"," 吸附"],"keywordEn":"chitosan derivative, preparation, adsorption","keywordEnList":["chitosan derivative"," preparation"," adsorption"],"keywordList":["壳聚精衍生物"," 制备"," 吸附"],"language":"","latestInfo":"","latestState":"","latestStateEn":"","lpage":"118","oldUrl":"http://yyhx.ciac.jl.cn/article","pdfDownCount":0,"pdfSize":141.73,"pubDate":"","recommendState":"","releaseState":"1","secCount":0,"title":"壳聚糖衍生物的制备及其吸附性能","titleCn":"壳聚糖衍生物的制备及其吸附性能","titleEn":"Preparation of Chitosan Derivatives and Their Adsorption Behaviour","viewCount":806,"volume":"12","year":1995}]}