引用本文:
Zheng Ning LI, Hui Lin CHEN. Cyclopropanation of Diazoacetate with Olefins[J]. Chinese Chemical Letters,
1996, 7(9): 785-787.
Citation: Zheng Ning LI, Hui Lin CHEN. Cyclopropanation of Diazoacetate with Olefins[J]. Chinese Chemical Letters, 1996, 7(9): 785-787.
Citation: Zheng Ning LI, Hui Lin CHEN. Cyclopropanation of Diazoacetate with Olefins[J]. Chinese Chemical Letters, 1996, 7(9): 785-787.
Cyclopropanation of Diazoacetate with Olefins
摘要:
Nine copper compounds are used for catalyzing the cyclopropanation of l-hexene/TME with alkyl diazoacetate. Cu (Salad) 2 shows the highest yield for the reaction of TME at high temperature such as 100℃. The reaction of crude RDA with TME in 73.7% yield under the optimal condition is obtained.
English
Cyclopropanation of Diazoacetate with Olefins
Abstract:
Nine copper compounds are used for catalyzing the cyclopropanation of l-hexene/TME with alkyl diazoacetate. Cu (Salad) 2 shows the highest yield for the reaction of TME at high temperature such as 100℃. The reaction of crude RDA with TME in 73.7% yield under the optimal condition is obtained.
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