OBSERVATION OF ENERGY DISSIPATION PEAK IN POLYSTYRENE MELT ABOVE Tg

Shu-ying Shang Xue-bang Wu Jia-peng Shui Zhen-gang Zhu

Citation:  Shu-ying Shang, Xue-bang Wu, Jia-peng Shui, Zhen-gang Zhu. OBSERVATION OF ENERGY DISSIPATION PEAK IN POLYSTYRENE MELT ABOVE Tg[J]. Chinese Journal of Polymer Science, 2007, 25(6): 629-633. shu

OBSERVATION OF ENERGY DISSIPATION PEAK IN POLYSTYRENE MELT ABOVE Tg

摘要: In this paper two different kinds of dynamic mechanical techniques (inversed torsion pendulum and energy dissipation apparatus) were used to study the dynamic behavior of atactic monodisperse polystyrene above glass transition. The plots of energy dissipation versus temperature were presented for two atactic polystyrene samples. An apparent energy dissipation peak occurred above Tg in each plot measured by the inversed torsion pendulum, and simultaneously the sample was found to flow assuredly at the moment. To exclude the influence of the flow and demonstrate there was a peak indeed above Tg, the energy dissipation apparatus was used, in which the samples were put into a cup. An obvious peak appeared, and it was in agreement with the peak observed by the inversed torsion pendulum. On basis of the results measured by the two kinds of apparatus, a conclusion is drawn that a peak occurrs above Tg, which gives a manifestation for the existence of the liquid-liquid transition.

English


  • 加载中
计量
  • PDF下载量:  0
  • 文章访问数:  0
  • HTML全文浏览量:  0
文章相关
  • 发布日期:  2007-11-20
  • 收稿日期:  2006-11-08
  • 修回日期:  2007-03-08
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章