引用本文:
Xue Yuan HUANG, Rui Xiang LI, Hua CHEN, Xian Jun LI. The Performance of Rhodium Complex-diphosphine Systems in the Hydroformylation of 1-Dodecene[J]. Chinese Chemical Letters,
2003, 14(6): 623-626.
Citation: Xue Yuan HUANG, Rui Xiang LI, Hua CHEN, Xian Jun LI. The Performance of Rhodium Complex-diphosphine Systems in the Hydroformylation of 1-Dodecene[J]. Chinese Chemical Letters, 2003, 14(6): 623-626.
Citation: Xue Yuan HUANG, Rui Xiang LI, Hua CHEN, Xian Jun LI. The Performance of Rhodium Complex-diphosphine Systems in the Hydroformylation of 1-Dodecene[J]. Chinese Chemical Letters, 2003, 14(6): 623-626.
The Performance of Rhodium Complex-diphosphine Systems in the Hydroformylation of 1-Dodecene
摘要:
The catalytic performances of four HRh(CO)(PPh3)3-diphosphine (BISBI, BDPX,BDNA and BINAP) systems in 1-dodecene hydroformylation were investigated and comparedwith HRh(CO)(PPh3)3-PPh3system. The catalyst system HRh(CO)(PPh3)3- BISBI exhibited veryhigh regioselectivity for the formation of linear aldehyde.
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关键词:
- Hydroformylation
- / 1-dodecene
- / diphosphine
- / rhodium complex
English
The Performance of Rhodium Complex-diphosphine Systems in the Hydroformylation of 1-Dodecene
Abstract:
The catalytic performances of four HRh(CO)(PPh3)3-diphosphine (BISBI, BDPX,BDNA and BINAP) systems in 1-dodecene hydroformylation were investigated and comparedwith HRh(CO)(PPh3)3-PPh3system. The catalyst system HRh(CO)(PPh3)3- BISBI exhibited veryhigh regioselectivity for the formation of linear aldehyde.
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Key words:
- Hydroformylation
- / 1-dodecene
- / diphosphine
- / rhodium complex
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