引用本文:
Shu Guo WANG, Jin Lin LI. Thiol-functionalized MCM-48: an Effective Absorbent of Mercury Ions[J]. Chinese Chemical Letters,
2006, 17(2): 221-224.
Citation: Shu Guo WANG, Jin Lin LI. Thiol-functionalized MCM-48: an Effective Absorbent of Mercury Ions[J]. Chinese Chemical Letters, 2006, 17(2): 221-224.
Citation: Shu Guo WANG, Jin Lin LI. Thiol-functionalized MCM-48: an Effective Absorbent of Mercury Ions[J]. Chinese Chemical Letters, 2006, 17(2): 221-224.
Thiol-functionalized MCM-48: an Effective Absorbent of Mercury Ions
摘要:
Mercaptopropyl groups were grafted onto the pore walls of mesoporous molecular sieves MCM-48. The pore structures were characterized by powder X-ray diffraction and N2 adsorption analysis. Elemental analysis confirmed that the material with high organic moiety (2.2 mmol/g) had been obtained. 13C MAS NMR verified the tethered organic groups. The thiol-functionalized MCM-48 showed effective capture of mercury ions, and all of the organic ligands were accessible for the binding of mercury ions.
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关键词:
- Mercaptopropyl
- / MCM-48
- / absorbent
- / mercury ions
English
Thiol-functionalized MCM-48: an Effective Absorbent of Mercury Ions
Abstract:
Mercaptopropyl groups were grafted onto the pore walls of mesoporous molecular sieves MCM-48. The pore structures were characterized by powder X-ray diffraction and N2 adsorption analysis. Elemental analysis confirmed that the material with high organic moiety (2.2 mmol/g) had been obtained. 13C MAS NMR verified the tethered organic groups. The thiol-functionalized MCM-48 showed effective capture of mercury ions, and all of the organic ligands were accessible for the binding of mercury ions.
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Key words:
- Mercaptopropyl
- / MCM-48
- / absorbent
- / mercury ions
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