Thiol-functionalized MCM-48: an Effective Absorbent of Mercury Ions

Shu Guo WANG Jin Lin LI

引用本文: Shu Guo WANG,  Jin Lin LI. Thiol-functionalized MCM-48: an Effective Absorbent of Mercury Ions[J]. Chinese Chemical Letters, 2006, 17(2): 221-224. shu
Citation:  Shu Guo WANG,  Jin Lin LI. Thiol-functionalized MCM-48: an Effective Absorbent of Mercury Ions[J]. Chinese Chemical Letters, 2006, 17(2): 221-224. shu

Thiol-functionalized MCM-48: an Effective Absorbent of Mercury Ions

  • 基金项目:

    This work supported by the Science Foundation of South-Central University of Nationalities (yzz 04001).

摘要: Mercaptopropyl groups were grafted onto the pore walls of mesoporous molecular sieves MCM-48. The pore structures were characterized by powder X-ray diffraction and N2 adsorption analysis. Elemental analysis confirmed that the material with high organic moiety (2.2 mmol/g) had been obtained. 13C MAS NMR verified the tethered organic groups. The thiol-functionalized MCM-48 showed effective capture of mercury ions, and all of the organic ligands were accessible for the binding of mercury ions.

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  • 收稿日期:  2005-04-18
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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