Carbonylation of Allyl Chloride Catalyzed by PdCl2(TPPTS)2 in Two-phase Medium

Heng JIANG Yun XU Shi Jian LIAO Dao Rong YU Hua CHEN Xian Jun LI

引用本文: Heng JIANG,  Yun XU,  Shi Jian LIAO,  Dao Rong YU,  Hua CHEN,  Xian Jun LI. Carbonylation of Allyl Chloride Catalyzed by PdCl2(TPPTS)2 in Two-phase Medium[J]. Chinese Chemical Letters, 1996, 7(9): 847-848. shu
Citation:  Heng JIANG,  Yun XU,  Shi Jian LIAO,  Dao Rong YU,  Hua CHEN,  Xian Jun LI. Carbonylation of Allyl Chloride Catalyzed by PdCl2(TPPTS)2 in Two-phase Medium[J]. Chinese Chemical Letters, 1996, 7(9): 847-848. shu

Carbonylation of Allyl Chloride Catalyzed by PdCl2(TPPTS)2 in Two-phase Medium

  • 基金项目:

    This work was supported by the National Natural Science Foundation of China and the Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences.

摘要: PdCl2 (TPPTS) 2 exhibits very high catalytic activity for carbonylation of allyl chloride in aq. NaOH/toluene two-phase medium under atmospheric pressure. The average turnover frequency (TOFav, mol substrate/mol Pd·min) reaches 31 min-1.

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  • 收稿日期:  1996-04-02
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