Catalytic Dechlorination of Polycyclic Chloroaromatics with Dicyclopentadienyl Yttrium Chloride Ⅱ

John H. Penn Dao Li DENG Chang Tao QIAN

引用本文: John H. Penn,  Dao Li DENG,  Chang Tao QIAN. Catalytic Dechlorination of Polycyclic Chloroaromatics with Dicyclopentadienyl Yttrium Chloride Ⅱ[J]. Chinese Chemical Letters, 1996, 7(9): 845-846. shu
Citation:  John H. Penn,  Dao Li DENG,  Chang Tao QIAN. Catalytic Dechlorination of Polycyclic Chloroaromatics with Dicyclopentadienyl Yttrium Chloride Ⅱ[J]. Chinese Chemical Letters, 1996, 7(9): 845-846. shu

Catalytic Dechlorination of Polycyclic Chloroaromatics with Dicyclopentadienyl Yttrium Chloride Ⅱ

  • 基金项目:

    We thank the National Natural Science Foundation of China and Chinese Academy of Sciences for financial support.

摘要: Catalytic dechlorination of 1-chloronaphthalene (Ⅰ), 2-chloronaph-thalene (Ⅱ), o-chlorobiphenyl (Ⅲ), m-chlorobiphenyl (Ⅳ), p-chlorobiphenyl (Ⅴ) 1-chloroanthracene (Ⅵ) and 2-chloroanthracene (Ⅶ) has been studied with dicyclopentadienyl yttrium/NaH system. The dechlorination products for (Ⅰ), (Ⅱ), (Ⅲ), (Ⅳ) and (Ⅴ) are corresponding aromatics in excellent yields. However for (Ⅵ) and (Ⅶ), the dechlorination products are mixed aromatics.

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  • 收稿日期:  1996-01-09
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