Citation:
QIU Kunyuan, ZHANG Jingyi, HU Yuanjie, FENG Xinde. STUDIES ON THE ORGANIC PEROXIDE-DITERTIARY AMINE INITIATION SYSTEMS*[J]. Chinese Journal of Polymer Science,
1985, 3(1): 76-81.
STUDIES ON THE ORGANIC PEROXIDE-DITERTIARY AMINE INITIATION SYSTEMS*
摘要:
Radical polperization of methyl methacrylate (MMA) initiated with organic peroxide-ditertiary amine binary systems was studied. Benzoyl peroxide (BPO), lauroyl peroxide (LPO), t-butyl hydro-peroxide (TBH), and t-butyl peroxybenzoate (TBPB) were used as organic peroxide components,aromatic ditertiay amine 4, 4′-tetramethyldiaminodiphenylmethane (TMDAPM) an d aliphatic di-tertiary amine tetramethylethylenediamine (TMEDA) were used as amine components. The polymeri-zation rate RP, the overall activation energy of polymerization Ea,the rate equation of MMA polymerization,and the end group of polymer formed were determined.
English
STUDIES ON THE ORGANIC PEROXIDE-DITERTIARY AMINE INITIATION SYSTEMS*
Abstract:
Radical polperization of methyl methacrylate (MMA) initiated with organic peroxide-ditertiary amine binary systems was studied. Benzoyl peroxide (BPO), lauroyl peroxide (LPO), t-butyl hydro-peroxide (TBH), and t-butyl peroxybenzoate (TBPB) were used as organic peroxide components,aromatic ditertiay amine 4, 4′-tetramethyldiaminodiphenylmethane (TMDAPM) an d aliphatic di-tertiary amine tetramethylethylenediamine (TMEDA) were used as amine components. The polymeri-zation rate RP, the overall activation energy of polymerization Ea,the rate equation of MMA polymerization,and the end group of polymer formed were determined.
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