引用本文:
Bing Hao LUO, Hui Ping GUAN, Quan Fu WANG, Chang Ming HU. Synthesis of 2-Fluoroalkylated Tetrahydrofuran Derivatives from Ethyl α-Fluoroalkylacetates[J]. Chinese Chemical Letters,
1997, 8(7): 583-586.
Citation: Bing Hao LUO, Hui Ping GUAN, Quan Fu WANG, Chang Ming HU. Synthesis of 2-Fluoroalkylated Tetrahydrofuran Derivatives from Ethyl α-Fluoroalkylacetates[J]. Chinese Chemical Letters, 1997, 8(7): 583-586.
Citation: Bing Hao LUO, Hui Ping GUAN, Quan Fu WANG, Chang Ming HU. Synthesis of 2-Fluoroalkylated Tetrahydrofuran Derivatives from Ethyl α-Fluoroalkylacetates[J]. Chinese Chemical Letters, 1997, 8(7): 583-586.
Synthesis of 2-Fluoroalkylated Tetrahydrofuran Derivatives from Ethyl α-Fluoroalkylacetates
摘要:
Ethyl α-(2-alkenyl)-α-perfluoroacylacetates (4) are synthesized from the reaction of ethyl α-perfluoroalkylacetates with allylic alcohols in the presence of the mixed base of triethylamine and sodium dicarbonate.lodoenoletherification of the compounds 4 afforded 2-fluoroalkylated tetrahvdrofuran derivatives 5 under the improved conditions.The possible reaction pathways are suggested.
English
Synthesis of 2-Fluoroalkylated Tetrahydrofuran Derivatives from Ethyl α-Fluoroalkylacetates
Abstract:
Ethyl α-(2-alkenyl)-α-perfluoroacylacetates (4) are synthesized from the reaction of ethyl α-perfluoroalkylacetates with allylic alcohols in the presence of the mixed base of triethylamine and sodium dicarbonate.lodoenoletherification of the compounds 4 afforded 2-fluoroalkylated tetrahvdrofuran derivatives 5 under the improved conditions.The possible reaction pathways are suggested.
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