引用本文:
Su Yun Liu, Shigeo Katsumura. An improved synthesis of (-)-7-isopropyl-cis-1-amino-2-indanol the chiral auxiliary for 6π-azaelectrocyclization[J]. Chinese Chemical Letters,
2009, 20(10): 1204-1206.
doi:
10.1016/j.cclet.2009.05.024
Citation: Su Yun Liu, Shigeo Katsumura. An improved synthesis of (-)-7-isopropyl-cis-1-amino-2-indanol the chiral auxiliary for 6π-azaelectrocyclization[J]. Chinese Chemical Letters, 2009, 20(10): 1204-1206. doi: 10.1016/j.cclet.2009.05.024
Citation: Su Yun Liu, Shigeo Katsumura. An improved synthesis of (-)-7-isopropyl-cis-1-amino-2-indanol the chiral auxiliary for 6π-azaelectrocyclization[J]. Chinese Chemical Letters, 2009, 20(10): 1204-1206. doi: 10.1016/j.cclet.2009.05.024
An improved synthesis of (-)-7-isopropyl-cis-1-amino-2-indanol the chiral auxiliary for 6π-azaelectrocyclization
摘要:
(-)-7-Isopropyl-cis-1-amino-2-indanol, a key chiral auxiliary and ligand in the highly stereo-selective asymmetric 6π-azaelectrocyclization,has been prepared previously by two methods.Each however involved using of one extreme condition,i.e.high temperature or high pressure, for the respective reaction.A modified reaction route employed mild condition for synthesis was presented in this report.
English
An improved synthesis of (-)-7-isopropyl-cis-1-amino-2-indanol the chiral auxiliary for 6π-azaelectrocyclization
Abstract:
(-)-7-Isopropyl-cis-1-amino-2-indanol, a key chiral auxiliary and ligand in the highly stereo-selective asymmetric 6π-azaelectrocyclization,has been prepared previously by two methods.Each however involved using of one extreme condition,i.e.high temperature or high pressure, for the respective reaction.A modified reaction route employed mild condition for synthesis was presented in this report.
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Key words:
- Chiral
- / cis-1-Amino-2-indanol
- / Asymmetric dihydroxylation
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