引用本文:
Rong Min WANG, Xiao Dong LI, Yu Feng HE. Preparation of Copolymer of Salen-crown Ether Complexes and its Catalytic Activation for Molecular Oxygen[J]. Chinese Chemical Letters,
2006, 17(2): 265-268.
Citation: Rong Min WANG, Xiao Dong LI, Yu Feng HE. Preparation of Copolymer of Salen-crown Ether Complexes and its Catalytic Activation for Molecular Oxygen[J]. Chinese Chemical Letters, 2006, 17(2): 265-268.
Citation: Rong Min WANG, Xiao Dong LI, Yu Feng HE. Preparation of Copolymer of Salen-crown Ether Complexes and its Catalytic Activation for Molecular Oxygen[J]. Chinese Chemical Letters, 2006, 17(2): 265-268.
Preparation of Copolymer of Salen-crown Ether Complexes and its Catalytic Activation for Molecular Oxygen
摘要:
A new stable salen Schiff base cobalt and crown ether sodium complex (SalCo-NaB18C6) was prepared through copolymerization. This copolymer complex was applied to catalytic oxidation of hydrocarbon compound with molecular oxygen without reductant, which was shown the higher activity and selectivity for ketone, and reused effectively.
English
Preparation of Copolymer of Salen-crown Ether Complexes and its Catalytic Activation for Molecular Oxygen
Abstract:
A new stable salen Schiff base cobalt and crown ether sodium complex (SalCo-NaB18C6) was prepared through copolymerization. This copolymer complex was applied to catalytic oxidation of hydrocarbon compound with molecular oxygen without reductant, which was shown the higher activity and selectivity for ketone, and reused effectively.
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Key words:
- Copolymeric complexes
- / cyclohexene
- / catalysis
- / salen Schiff base
- / crown ether
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