引用本文:
Bao Han XIE, Shi Jie LU, Hong Xiang FU, Lan Yong GAO. Enantioselective Hydrogenation of α,β-Unsaturated Cyclic Ketones by Double Asymmetric Induction Preparation of (R)-Muscone[J]. Chinese Chemical Letters,
1997, 8(6): 477-478.
Citation: Bao Han XIE, Shi Jie LU, Hong Xiang FU, Lan Yong GAO. Enantioselective Hydrogenation of α,β-Unsaturated Cyclic Ketones by Double Asymmetric Induction Preparation of (R)-Muscone[J]. Chinese Chemical Letters, 1997, 8(6): 477-478.
Citation: Bao Han XIE, Shi Jie LU, Hong Xiang FU, Lan Yong GAO. Enantioselective Hydrogenation of α,β-Unsaturated Cyclic Ketones by Double Asymmetric Induction Preparation of (R)-Muscone[J]. Chinese Chemical Letters, 1997, 8(6): 477-478.
Enantioselective Hydrogenation of α,β-Unsaturated Cyclic Ketones by Double Asymmetric Induction Preparation of (R)-Muscone
摘要:
By ketal formation with chiral glycols like methyl or ethyl ester of tartaric acid,hydrogenation of ketals from the corresponding α,β-unsaturated 15-membered cyclic ketone produces (R)-muscone in good chemical and optical yield in the presence of chiral catalysts.
English
Enantioselective Hydrogenation of α,β-Unsaturated Cyclic Ketones by Double Asymmetric Induction Preparation of (R)-Muscone
Abstract:
By ketal formation with chiral glycols like methyl or ethyl ester of tartaric acid,hydrogenation of ketals from the corresponding α,β-unsaturated 15-membered cyclic ketone produces (R)-muscone in good chemical and optical yield in the presence of chiral catalysts.
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