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Preparation of high purity 1,2-diols by catalytic oxidation of linear terminal alkenes with H2O2 in the presence of carboxylic acids under solvent-free conditions

Xu-Wei Wu ,  Bin-Dong Li

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Citation:  Xu-Wei Wu, Bin-Dong Li. Preparation of high purity 1,2-diols by catalytic oxidation of linear terminal alkenes with H2O2 in the presence of carboxylic acids under solvent-free conditions[J]. Chinese Chemical Letters, 2014, 25(3): 459-462. doi: 10.1016/j.cclet.2013.11.049 shu

Preparation of high purity 1,2-diols by catalytic oxidation of linear terminal alkenes with H2O2 in the presence of carboxylic acids under solvent-free conditions

    • 通讯作者: Bin-Dong Li,
摘要: The oxidation of terminal alkenes was smoothly catalyzed by a recyclable and environmentally friendly catalytic system: [(C18H37)2N(CH3)2]3[PW4O16]/H2O2/formic acid. This new catalytic system is not only capable of catalyzing oxidation of terminal alkenes with a phase-transfer character, but also under solvent-free conditions, avoiding the use of chlorinated solvents. Many different kinds of terminal alkenes could be converted to the corresponding 1,2-diols of high purity in high yields. The catalyst could be easily separated and reused after reaction. Both fresh and used [(C18H37)2N(CH3)2]3[PW4O16] catalyst was characterized by Raman and FTIR.

English

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  • 发布日期:  2013-12-03
  • 收稿日期:  2013-09-17
  • 网络出版日期:  2013-11-19
通讯作者: 陈斌, bchen63@163.com
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