Citation:
CHEN Yuanyin, ZHANG Baolian, GONG Shuling, DUAN Heping, LU Xueran. SYNTHESIS AND CATALYTIC HYDROSILYLATION PROPERTY OF POLYSILOXANE-SUPPORTED MERCAPTOSELENAETHER PLATINUM OR RHODIUM COMPLEX[J]. Chinese Journal of Polymer Science,
1998, 16(4): 292-296.
SYNTHESIS AND CATALYTIC HYDROSILYLATION PROPERTY OF POLYSILOXANE-SUPPORTED MERCAPTOSELENAETHER PLATINUM OR RHODIUM COMPLEX
摘要:
Silica-bound mercaptoselenaether-containing silsesquioxane and its plat-inum or rhodium complex were synthesized from γ-(2,3-epithiopropyl) propyltrimethoxysi-lane via ring-opening reaction with bis(2-hydroxyethyl) sclenide, followed by hydrolysisand immobilization on fumed silica, and then reacting with potassium chloroplatinite orrhodium chloride in acetone under nitrogen atmosphere. It was found that two noble metalcomplexes can catalyze the hydrosilylation of olefins with triethoxysilane effectively. The influences of temperature,the amount of complex used,the nature of olefin on catalytic activity were investigated.
English
SYNTHESIS AND CATALYTIC HYDROSILYLATION PROPERTY OF POLYSILOXANE-SUPPORTED MERCAPTOSELENAETHER PLATINUM OR RHODIUM COMPLEX
Abstract:
Silica-bound mercaptoselenaether-containing silsesquioxane and its plat-inum or rhodium complex were synthesized from γ-(2,3-epithiopropyl) propyltrimethoxysi-lane via ring-opening reaction with bis(2-hydroxyethyl) sclenide, followed by hydrolysisand immobilization on fumed silica, and then reacting with potassium chloroplatinite orrhodium chloride in acetone under nitrogen atmosphere. It was found that two noble metalcomplexes can catalyze the hydrosilylation of olefins with triethoxysilane effectively. The influences of temperature,the amount of complex used,the nature of olefin on catalytic activity were investigated.
扫一扫看文章
计量
- PDF下载量: 0
- 文章访问数: 1883
- HTML全文浏览量: 37
下载:
