Synthesis, Structure Characterization and Thermal Analysis of a New Cadmium Zinc Borate in the Pseudo-binary System Cd3B2O6-Zn3B2O6

Citation: JIAO Zhi-Wei, DUAN Cui-Cui, CAO Lei-Ganga, CUI Yan, LIU Feng-Bin, WANG Hai-Jun. Synthesis, Structure Characterization and Thermal Analysis of a New Cadmium Zinc Borate in the Pseudo-binary System Cd₃B₂O₆-Zn₃B₂O₆[J]. Chinese Journal of Structural Chemistry, 2016, 35(11): 1679-1685. doi: 10.14102/j.cnki.0254-5861.2011-1189 shu

Synthesis, Structure Characterization and Thermal Analysis of a New Cadmium Zinc Borate in the Pseudo-binary System Cd₃B₂O₆-Zn₃B₂O₆

1.
a College of Mechanical Engineering and Materials Science, North China University of Technology, Beijing 100144, China;
2.
b Gansu Research Institute of Chemical Industry, Lanzhou 730020, China
基金项目:
This work was supported by the Special Foundation for Young Scientists of Beijing (No. 2014000020124G009) (No. 2014000020124G009)

摘要: Cd-rich portion of the pseudo-binary system Cd₃B₂O₆-Zn₃B₂O₆ was investigated. A new cadmium zinc borate, Cd_2.42Zn_0.58B₂O₆, was synthesized successfully by a traditional solid-state reaction method. The compound crystallizes in the monoclinic space group C2/c with a=17.3048, b=8.4356, c=10.2962 Å, β=93.157°, V=1500.7(2) Å³, D_c=5.683 g/cm³, F(000)=2301, Z=24, R=0.0351 and wR=0.0741. In its structure, BO₃ triangle, CdO₆ and CdO₅ (or ZnO₅) polyhedra are joined together by sharing bridging O atoms to form an intricate three-dimensional framework. A comparison of the structures of Cd_2.42Zn_0.58B₂O₆, α-Cd₃B₂O₆ and β-Cd₃B₂O₆ is presented. The IR spectrum confirms the presence of BO₃ unit. The UV cut-off wavelength of Cd_2.42Zn_0.58B₂O₆ is 313 nm. The differential thermal analysis (DTA) suggests that Cd_2.42Zn_0.58B₂O₆ is an incongruent melting compound.

关键词:

borate
/ crystal structure
/ IR
/ DTA

English

Synthesis, Structure Characterization and Thermal Analysis of a New Cadmium Zinc Borate in the Pseudo-binary System Cd₃B₂O₆-Zn₃B₂O₆

1.
a College of Mechanical Engineering and Materials Science, North China University of Technology, Beijing 100144, China;
2.
b Gansu Research Institute of Chemical Industry, Lanzhou 730020, China
Received Date: 08 March 2016
Fund Project:

Abstract: Cd-rich portion of the pseudo-binary system Cd₃B₂O₆-Zn₃B₂O₆ was investigated. A new cadmium zinc borate, Cd_2.42Zn_0.58B₂O₆, was synthesized successfully by a traditional solid-state reaction method. The compound crystallizes in the monoclinic space group C2/c with a=17.3048, b=8.4356, c=10.2962 Å, β=93.157°, V=1500.7(2) Å³, D_c=5.683 g/cm³, F(000)=2301, Z=24, R=0.0351 and wR=0.0741. In its structure, BO₃ triangle, CdO₆ and CdO₅ (or ZnO₅) polyhedra are joined together by sharing bridging O atoms to form an intricate three-dimensional framework. A comparison of the structures of Cd_2.42Zn_0.58B₂O₆, α-Cd₃B₂O₆ and β-Cd₃B₂O₆ is presented. The IR spectrum confirms the presence of BO₃ unit. The UV cut-off wavelength of Cd_2.42Zn_0.58B₂O₆ is 313 nm. The differential thermal analysis (DTA) suggests that Cd_2.42Zn_0.58B₂O₆ is an incongruent melting compound.

Key words:

borate
/ crystal structure
/ IR
/ DTA

扫一扫看文章

计量

PDF下载量: 1
文章访问数: 3068
HTML全文浏览量: 51

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Structure Characterization and Thermal Analysis of a New Cadmium Zinc Borate in the Pseudo-binary System Cd₃B₂O₆-Zn₃B₂O₆

English

Synthesis, Structure Characterization and Thermal Analysis of a New Cadmium Zinc Borate in the Pseudo-binary System Cd₃B₂O₆-Zn₃B₂O₆

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处