引用本文:
Hui Yu, Tao Gai, Wen Liang Sun, Mei Su Zhang. Radical reduction of Passerini 3CR adducts by SmI2/HMPA[J]. Chinese Chemical Letters,
2011, 22(4): 379-381.
doi:
10.1016/j.cclet.2010.11.013
Citation: Hui Yu, Tao Gai, Wen Liang Sun, Mei Su Zhang. Radical reduction of Passerini 3CR adducts by SmI2/HMPA[J]. Chinese Chemical Letters, 2011, 22(4): 379-381. doi: 10.1016/j.cclet.2010.11.013
Citation: Hui Yu, Tao Gai, Wen Liang Sun, Mei Su Zhang. Radical reduction of Passerini 3CR adducts by SmI2/HMPA[J]. Chinese Chemical Letters, 2011, 22(4): 379-381. doi: 10.1016/j.cclet.2010.11.013
Radical reduction of Passerini 3CR adducts by SmI2/HMPA
摘要:
The Passerini 3-CR adducts of substituted cinnamaldehydes, isocyanides and acetic acid were treated with SmI2/HMPA in dry tetrahydrofuran (THF) at room temperature, and β, γ-unsaturated amides were obtained in moderate yields. The reaction was supposed involving a radical reduction procedure.
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关键词:
- Passerini
- / Isocyanide
- / Modification
- / Amides
- / Samarium diiodide
English
Radical reduction of Passerini 3CR adducts by SmI2/HMPA
Abstract:
The Passerini 3-CR adducts of substituted cinnamaldehydes, isocyanides and acetic acid were treated with SmI2/HMPA in dry tetrahydrofuran (THF) at room temperature, and β, γ-unsaturated amides were obtained in moderate yields. The reaction was supposed involving a radical reduction procedure.
-
Key words:
- Passerini
- / Isocyanide
- / Modification
- / Amides
- / Samarium diiodide
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