引用本文:
Reza Heydari Malek Taher Maghsoodlou, Razieh Nejat Yami. An efficient method for synthesis of organophosphorus compounds in aqueous media[J]. Chinese Chemical Letters,
2009, 20(10): 1175-1178.
doi:
10.1016/j.cclet.2009.05.019
Citation: Reza Heydari Malek Taher Maghsoodlou, Razieh Nejat Yami. An efficient method for synthesis of organophosphorus compounds in aqueous media[J]. Chinese Chemical Letters, 2009, 20(10): 1175-1178. doi: 10.1016/j.cclet.2009.05.019
Citation: Reza Heydari Malek Taher Maghsoodlou, Razieh Nejat Yami. An efficient method for synthesis of organophosphorus compounds in aqueous media[J]. Chinese Chemical Letters, 2009, 20(10): 1175-1178. doi: 10.1016/j.cclet.2009.05.019
An efficient method for synthesis of organophosphorus compounds in aqueous media
摘要:
A convenient and facile one-pot synthesis of stable phosphorus ylides and 1,4-diionic organophosphorus compounds is reported by the reaction of triphenylphosphine, dialkylacetylenedicarboxylates and N-H, C-H or S-H acids in the presence of polyethyleneglycol (PEG), b-cyclodextrin (β-CD), glycerine (Gly) or ethyleneglycol (EG) in water.This methodology is of interest due to the use of water as a solvent, thus minimizing the cost operational hazards, and environmental pollution.
English
An efficient method for synthesis of organophosphorus compounds in aqueous media
Abstract:
A convenient and facile one-pot synthesis of stable phosphorus ylides and 1,4-diionic organophosphorus compounds is reported by the reaction of triphenylphosphine, dialkylacetylenedicarboxylates and N-H, C-H or S-H acids in the presence of polyethyleneglycol (PEG), b-cyclodextrin (β-CD), glycerine (Gly) or ethyleneglycol (EG) in water.This methodology is of interest due to the use of water as a solvent, thus minimizing the cost operational hazards, and environmental pollution.
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