Highly stable supramolecular hydrogels formed from 1,3,5-benzenetricarboxylic acid and hydroxyl pyridines

Li Ming Tang Yu Jiang Wang

引用本文: Li Ming Tang Yu Jiang Wang. Highly stable supramolecular hydrogels formed from 1,3,5-benzenetricarboxylic acid and hydroxyl pyridines[J]. Chinese Chemical Letters, 2009, 20(10): 1259-1262. doi: 10.1016/j.cclet.2009.04.030 shu
Citation:  Li Ming Tang Yu Jiang Wang. Highly stable supramolecular hydrogels formed from 1,3,5-benzenetricarboxylic acid and hydroxyl pyridines[J]. Chinese Chemical Letters, 2009, 20(10): 1259-1262. doi: 10.1016/j.cclet.2009.04.030 shu

Highly stable supramolecular hydrogels formed from 1,3,5-benzenetricarboxylic acid and hydroxyl pyridines

  • 基金项目:

    20874055) is gratefully acknowledged.

    The financial support from the National Natural Science Foundation of China (Nos.20574041

摘要: New supramolecular hydrogels with the maximal sol-gel transition temperature (Tgel) of 95℃ were obtained by using gelators formed from 1,3,5-benzenetricarboxylic acid (BTA) and para-hydroxyl pyridine (PHP) or meta-hydroxyl pyridine (MHP).Thesingle crystal structure of the complex formed from BTA and ortho-hydroxyl pyridine (OHP) indicated that the molecules assembled into superstructure via both hydrogen bonds and π-πstacking interaction.

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  • 收稿日期:  2009-02-23
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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