引用本文:
Ya Dong LU, Yan Hua WANG, Zi Lin JIN. Thermoregulated Organic Biphasic Hydrogenation of 1-OcteneCatalyzed by Ru/PETPP Complex[J]. Chinese Chemical Letters,
2006, 17(2): 255-257.
Citation: Ya Dong LU, Yan Hua WANG, Zi Lin JIN. Thermoregulated Organic Biphasic Hydrogenation of 1-OcteneCatalyzed by Ru/PETPP Complex[J]. Chinese Chemical Letters, 2006, 17(2): 255-257.
Citation: Ya Dong LU, Yan Hua WANG, Zi Lin JIN. Thermoregulated Organic Biphasic Hydrogenation of 1-OcteneCatalyzed by Ru/PETPP Complex[J]. Chinese Chemical Letters, 2006, 17(2): 255-257.
Thermoregulated Organic Biphasic Hydrogenation of 1-OcteneCatalyzed by Ru/PETPP Complex
摘要:
Thermoregulated organic biphasic system composed of triethylene glycol monomethyl ether (TGME) and n-heptane was first applied to the hydrogenation of 1-octene. Under the optimal conditions: P(H2)=5.0MPa, T=80℃, t=3h, 1-octene/Ru=1000(molar ratio), the yield of n-octane reached up to 99.6%. Furthermore, the simply decanted catalyst could be reused for 10 times without apparent loss of catalytic activity.
English
Thermoregulated Organic Biphasic Hydrogenation of 1-OcteneCatalyzed by Ru/PETPP Complex
Abstract:
Thermoregulated organic biphasic system composed of triethylene glycol monomethyl ether (TGME) and n-heptane was first applied to the hydrogenation of 1-octene. Under the optimal conditions: P(H2)=5.0MPa, T=80℃, t=3h, 1-octene/Ru=1000(molar ratio), the yield of n-octane reached up to 99.6%. Furthermore, the simply decanted catalyst could be reused for 10 times without apparent loss of catalytic activity.
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Key words:
- Thermoregulated organic biphasic system
- / hydrogenation
- / 1-octene
- / ruthenium
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