Synthesis of a New Ligand Containing 1, 7-Diaza-12-crown-4 and the Application in Asymmetric Cyclopropanation Reaction

Cheng Yun WANG Zhi Cai SHANG Jiang Hua MEI Qing Sen YU

引用本文: Cheng Yun WANG,  Zhi Cai SHANG,  Jiang Hua MEI,  Qing Sen YU. Synthesis of a New Ligand Containing 1, 7-Diaza-12-crown-4 and the Application in Asymmetric Cyclopropanation Reaction[J]. Chinese Chemical Letters, 2003, 14(6): 579-580. shu
Citation:  Cheng Yun WANG,  Zhi Cai SHANG,  Jiang Hua MEI,  Qing Sen YU. Synthesis of a New Ligand Containing 1, 7-Diaza-12-crown-4 and the Application in Asymmetric Cyclopropanation Reaction[J]. Chinese Chemical Letters, 2003, 14(6): 579-580. shu

Synthesis of a New Ligand Containing 1, 7-Diaza-12-crown-4 and the Application in Asymmetric Cyclopropanation Reaction

摘要: A new chiral multidenate ligand (S, S)-1,7-bis(4-benzyloxazolin-2-yl-methyl)-1,7-diaza- 12-crown-41 has been synthesized and used as ligand in the copper catalyzed asymmetriccyclopropanation of 1, 1-diphenylethylene.

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  • 收稿日期:  2002-05-20
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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