The First Total Synthesis of Five Elegan Type Natural Products

Jing LI Jiong LAN Zuo Sheng LIU Yu Lin LI

引用本文: Jing LI,  Jiong LAN,  Zuo Sheng LIU,  Yu Lin LI. The First Total Synthesis of Five Elegan Type Natural Products[J]. Chinese Chemical Letters, 1997, 8(7): 595-598. shu
Citation:  Jing LI,  Jiong LAN,  Zuo Sheng LIU,  Yu Lin LI. The First Total Synthesis of Five Elegan Type Natural Products[J]. Chinese Chemical Letters, 1997, 8(7): 595-598. shu

The First Total Synthesis of Five Elegan Type Natural Products

  • 基金项目:

    This work was financially supported by the National Natural Science Foundation of China (Grant No. 29672015) and the Special Research Grant for Doctoral Sites in Chinese Universities.

摘要: The first total synthesis of five linear diterpenes:eleganolone (1),eleganolone acetate (2),elegandiol (3),eleganonal (4) and epoxyeleganolone (5),was achieved from (E,E)-farnesol (6) via 4 to 6 steps.The key step was the alkylation reaction of silyl cyanide with allylic iodide.

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  • 收稿日期:  1997-03-17
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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