THE POLYMERIZATION THERMOKINETICS OF PYRROLE IN THE PRESENCE OF IRON TRICHLORID E

ZHANG Tingli HU Rongzu ZHANG Mingnan WANG Yaping LIANG Yanjun WANG Yuan

Citation:  ZHANG Tingli, HU Rongzu, ZHANG Mingnan, WANG Yaping, LIANG Yanjun, WANG Yuan. THE POLYMERIZATION THERMOKINETICS OF PYRROLE IN THE PRESENCE OF IRON TRICHLORID E[J]. Chinese Journal of Polymer Science, 1991, 9(1): 19-23. shu

THE POLYMERIZATION THERMOKINETICS OF PYRROLE IN THE PRESENCE OF IRON TRICHLORID E

摘要: The polymerization thermokinetics of pyrrole in the presence of iron trichloride art studied by using a Calvet microcalorimoter. The apparent activation energy, the pre-exponential constant and reaction order of this reaction in the temperature range of 25.2—37℃ are 34.5 KJ·mol-1, 10-1S2.74 and 1 respectively. The activation free-energies of this reaction at 25.2°, 30°and 37℃ are 91.8, 92.9 and 94.2 KJ·mol-1 respectively.

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  • 发布日期:  1991-03-20
  • 收稿日期:  1989-07-05
通讯作者: 陈斌, bchen63@163.com
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